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581.
Maheswari PU Modec B Pevec A Kozlevcar B Massera C Gamez P Reedijk J 《Inorganic chemistry》2006,45(17):6637-6645
The reaction of Zn(NO3)2.6H2O or Cu(NO3)2.3H2O with the star-shaped ligand 2,4,6-tris(di-2-picolylamino)[1,3,5]triazine (dipicatriz) in acetonitrile results in the formation of the mono- or trinuclear coordination compounds [Zn(dipicatriz)(NO3)2] (1), [Zn3(dipicatriz)(NO3)6](CH3CN)3 (2), and [Cu3(dipicatriz)(NO3)2(H2O)6](NO3)4 (3), depending on the metal-to-ligand ratios used during the crystallization process. Their crystal structures exhibit unique supramolecular interactions. Compounds 1 and 2 show anion-pi interactions between coordinated nitrate ions and the s-triazine ring. Compound 3 exhibits remarkable interactions between two noncoordinated nitrate anions and the two faces of the electron-deficient heteroaromatic ring, corroborating earlier theoretical investigations in this area. New theoretical investigations have been carried out on nitrate-pi interactions, taking into account the particular position of the anion toward the aromatic ring observed in the crystal structures. 相似文献
582.
CO(2) samples were collected from air at three sites in Hungary for comparison of polluted and background areas. In order to reduce the uncertainties caused by the varying amount of N(2)O, a gas chromatography (GC)-based vacuum separation was applied. The reliability of the procedure was demonstrated by careful standardization and comparison with global network data. The stable isotope data show complex diurnal and seasonal variations that can be explained by fractionations during photosynthesis and respiration. The isotopic characteristics of pollution-derived (anthropogenic) and biogenic CO(2) appear to be indistinguishable at the study sites. However, the sites at unpolluted areas reveal a seasonal variation in the carbon isotope composition of biogenic CO(2) that may be related to changes in soil biogenic activities. The atmospheric background CO(2) shows constant delta(13)C in the region. Finally, the study demonstrates the need for careful standardization of sampling in order to make the data obtained from different sampling systems comparable. 相似文献
583.
The infrared spectra of OCS-(H2)(n) clusters in cold (0.15 K) superfluid 4He droplets coated with 3He exhibit resolved rotational bands for each n up to n=8 para-H2 (pH(2)) or ortho-D2 (oD(2)) molecules. An analysis of the different Q-branch intensities based on the different spin symmetries of pH(2) and oD(2) indicates the formation of symmetric 5- or 6-membered rings around the linear carbonyl sulfide (OCS) chromophore. The rings of distinguishable oD(2) are found to undergo axial rotations, whereas for 6 pH(2) molecules the symmetry-allowed rotational levels lie too high to be excited at the 0.15 K droplet temperatures. 相似文献
584.
585.
Motivated by the operation of myogenic (self-oscillatory) insect flight muscle, we study a model consisting of a large number of identical oscillatory contractile elements joined in a chain, whose end is attached to a damped mass-spring oscillator. When the inertial load is small, the serial coupling favors an antisynchronous state in which the extension of one oscillator is compensated by the contraction of another, in order to preserve the total length. However, a sufficiently massive load can synchronize the oscillators and can even induce oscillation in situations where isolated elements would be stable. The system has a complex phase diagram displaying quiescent, synchronous and antisynchronous phases, as well as an unusual asynchronous phase in which the total length of the chain oscillates at a different frequency from the individual active elements. 相似文献
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588.
G. E. Malashkevich E. N. Poddeneznyi I. M. Mel’nichenko V. B. Prokopenko D. V. Dem’yanenko 《Physics of the Solid State》1998,40(3):427-431
Silica gel films dyed with rhodamine 6G in the sol stage are prepared and investigated. It is shown that the host matrix of
the film loosens structurally as a result of intensification of the formation of dye molecular associates, lowering of the
luminescence photon yield, and enhancement of the luminescence spectral sensitivity of such films to vapors of highly volatile
organic solvents.
Fiz. Tverd. Tela (St. Petersburg) 40, 466–471 (March 1998) 相似文献
589.
We consider properties of sets in an intuitionistic setting corresponding to large cardinals in classical set theory. Adding such ‘large set axioms’ to intuitionistic ZF set theory does not violate well-know metamathematical properties of intuitionistic systems. Moreover, we consider statements in constructive analysis equivalent to the consistency of such ‘large set axioms’. 相似文献
590.
Jurij Svete Andrej Preeren Branko Stanovnik Ljubo Goli
Simona Goli
-Grdadolnik 《Journal of heterocyclic chemistry》1997,34(4):1323-1328
Reaction of rel-(4R,5R)-4-benzoylamino-5-phenyl-3-pyrazolidinone (4) with aromatic aldehydes 5a-f gave the corresponding (1Z)-rel-(4R,5R)-1-arylmethylene-4-benzoylamino-5-phenyl-3-pyrazolidinon-1-azomethinimines 6a-f . 1,3-Dipolar cycloadditions of azomethinimines 6a-f to various dipolarophiles, which were found to proceed regio- and stereo-selectively, afforded the corresponding pyrazolo[1,2-a]-pyrazoles 8a-f, 10 , and 13–16 . Reaction of azomethinimine 6a with hydrogen cyanide gave rel-(5R,6R)-6-benzoylamino-5,6-dihydro-3,5-diphenyl-1-oxo-1H,7H-pyrazolo[1,2-a][1,2,3]triazole (18) as a representative of a new ring system. 相似文献