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排序方式: 共有1138条查询结果,搜索用时 15 毫秒
1.
2.
Felipe J. Gonzlez Juan M. Aceves Ren Miranda Ignacio Gonzlez 《Journal of Electroanalytical Chemistry》1991,310(1-2)
An electrochemical study using transient techniques of a quinone-type natural product, perezone, has been performed in acetonitrile and in the presence of benzoic acid. Using linear sweep voltametry and single potential step chronoamperometry, it was possible to establish that the reduction mechanism of perezone involves a monoelectronic charge-transfer step, followed by a protonation step and homogeneous charge transfer due to disproportionation of the protonated intermediate. The mechanism for the homogeneous charge-transfer step was found to be of the type DISP1 (disproportionation order one) from the results of double potential step chronoamperometry experiments. The occurrence of the DISP1 mechanism was provoked by the mildly acidic medium used in this study. 相似文献
3.
Andreia PeixotoMariette M. Pereira M.Graça P.M.S. NevesArtur M.S. Silva José A.S. Cavaleiro 《Tetrahedron letters》2003,44(30):5593-5595
Formyl derivatives of protoporphyrin-IX dimethyl ester metal complexes were obtained via hydroformylation reactions, catalysed by rhodium-triphenylphosphine complexes. The regioselectivity of the reaction is remarkably dependent on the metal centre of the porphyrin, yielding 100% of the branched aldehyde with zinc(II) complexes and 75% with the nickel(II). The NMR characterisation of the new compounds was carried out after their derivatisation into acetals. 相似文献
4.
P. Miranda Jr. J. Zukerman-Schpector J. R. Matos M. F. Máduar E. M. Aricó M. Linardi L. B. Zinner G. Vicentini 《Journal of Thermal Analysis and Calorimetry》2004,75(2):577-582
The complexes [Ln(pic)3(DTSO)3] (Ln=La, Lu and Y; pic=picrate; DTSO=1,3-dithiane-1-oxide) were synthesized and characterized. Indirect structural determination by far infrared
spectroscopy is presented. Results from thermal decomposition of these complexes by TG/DTG and DSC techniques are reported.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
5.
Pérez-Prieto J Galian RE Miranda MA Catalina F Martín-Vargas N López-Ortiz F 《Organic letters》2004,6(4):561-564
[reaction: see text] Several benzo[d]-1,2-oxaphosphole 2-oxides were examined as potential precursors of stabilized C-centered radicals. The transient absorption spectra obtained after laser flash photolysis in the presence of di-tert-butyl peroxide showed the features of benzylic radicals with formation and decay kinetics not significantly influenced by the presence of oxygen. In the case of compounds with two possible diastereomeric forms, the C-H bond of the trans-isomers [corrected] is more reactive toward hydrogen abstraction. 相似文献
6.
Luis C. Mendes Andrea D. Tedesco Mauro S. Miranda Marcia R. Benzi Beatriz S. Chagas 《Polymer Testing》2005,24(8):963-968
In this third work, we evaluated the degree of conversion (DC) versus depth of dental filling composite named Prodigy Condensable™ using infrared spectroscopy. Confirming previous results, there was a gradual reduction of DC with increasing depth but the composite exhibited extreme values of DC, an upper value (45.9%) on the surface and a lower one (6.1%) at a depth of 5 mm. The composite presented the worst performance among materials studied. The composite formulation was 80% of inorganic fillers and BisfenolA/dimethacrylate (BisGMA) (18%)/triethyleneglycoldimethacrylate (TEGDMA) (2.0%) as monomers. As stated before, type/ratio/viscosity of monomers and type, amount, size and size distribution of fillers all together had an important role in the cure reaction contributing to the final performance of the composite. 相似文献
7.
Photocyclization of 2-chloroacetyl-1,2,3,4,5,6-hexahydro-1, 5-methanoazocino[4,3-b]indole () takes place at the indole 4-position to give a 1 ,2 ,3 ,4 , 5 ,6-hexahydro-2 ,11-ethano-1 ,5-methanoazocino [4 , 3-6] indole system. Consequently, the method appears to be unsuitable for constructing the pyrrolidine ring of pentacyclic Strychnos indole alkaloids. 相似文献
8.
Lhiaubet-Vallet V Sarabia Z Boscá F Miranda MA 《Journal of the American Chemical Society》2004,126(31):9538-9539
A remarkable stereodifferentiation has been observed in the interaction between the excited triplet state of carprofen (CP) and human serum albumin (HSA). Time-resolved measurements using laser flash photolysis reveal the presence of two components with different lifetimes in triplet decay. This is explained by complexation of CP to the two possible HSA binding sites. The shorter-lived components are ascribed to the CP/HSA complexes in site I, where stereodifferentiation is more important (tauR/tauS ca. 4). This is correlated with formation of a dehalogenated photoproduct upon steady-state photolysis. 相似文献
9.
I. M. Miranda Salvado F. M. A. Margaça J. Teixeira 《Journal of Sol-Gel Science and Technology》1994,2(1-3):289-294
Silica-titania gels, prepared in acidic conditions, with contents of TiO2 up to 6 mol%, have been studied by small angle neutron scattering (SANS) as wet gel with increasing aging times. In all samples, small primary particles have been found with a diameter of about 3 nm. At the gel point, cylindrical clusters, ca. 10 nm long, were observed as well. These grow with aging time, becoming branched. The cluster-cluster diffusion limited aggregation model is found to be consistent with the SANS results. The growth process is independent of the TiO2 content. It is mainly influenced by the ratio of the aging time to the gelation time. 相似文献
10.
We have investigated the transitions between disordered phases in supercooled liquid silicon using computer simulations. The thermodynamic properties were directly obtained from the free energy, which was computed using the recently proposed reversible scaling method. The calculated free energies of the crystalline and liquid phases of silicon at zero pressure, obtained using the environment dependent interatomic potential, are in excellent agreement with the available experimental data. The results show that, at zero pressure, a weak first-order liquid-liquid transition occurs at 1135 K and a continuous liquid-amorphous transition takes place at 843 K. These results are consistent with the existence of a second critical point for the liquid-liquid transition at a negative pressure. 相似文献