1-Fluorosilatrane synthesis from SiF4 complexes and its properties

A new method of 1-fluorosilatrane synthesis on the basis of silicon tetrafluoride complexes obtained from SiO₂ is offered. Chemical properties of 1-fluorosilatrane in reactions of nucleophilic substitution are investigated. It is shown that fluorine can be substituted by O-nucleophiles (lithium methoxide, isopropoxide and phenoxide) and C-nucleophile (lithium phenylacetylenide).     

p-Adic valued quantization

This review covers an important domain of p-adic mathematical physics — quantum mechanics with p-adic valued wave functions. We start with basic mathematical constructions of this quantum model: Hilbert spaces over quadratic extensions of the field of p-adic numbers ? _p , operators — symmetric, unitary, isometric, one-parameter groups of unitary isometric operators, the p-adic version of Schrödinger’s quantization, representation of canonical commutation relations in Heisenberg andWeyl forms, spectral properties of the operator of p-adic coordinate.We also present postulates of p-adic valued quantization. Here observables as well as probabilities take values in ? _p . A physical interpretation of p-adic quantities is provided through approximation by rational numbers.     

How Far can the Anisotropy Deviate from Uniaxiality in a Dy-Based Single-Molecule Magnet? Dinuclear Dy(III) Complex Study

The Dy^III ions in the dimer [Dy₂(H₂tea)₂(O₂CPh)₄]·2H₂O (1) (H₃tea = triethanolamine) have the 9-coordinate monocapped square-antiprismatic ligand field environment. Compound 1 shows slow relaxation of magnetization which is observable only with applied magnetic fields. This is consistent with the idea that low-symmetry ligand fields allow for the quantum tunneling of magnetization. This is reflected by the fact that there are no observable maxima in the out-of-phase ac susceptibility above 1.8 K. The {g}-tensor of the Dy^III ions {g _x = 11, g _y = 8.2, g _z = 1} further underlying the reduced uniaxiality in this system was determined in electron paramagnetic resonance (X- and Q-band) studies of 1 at temperatures down to 4 K.     

The Hermitian Laplace Operator on Nearly Kähler Manifolds

The moduli space ${\mathcal {NK}}The moduli space NK{\mathcal {NK}} of infinitesimal deformations of a nearly K?hler structure on a compact 6-dimensional manifold is described by a certain eigenspace of the Laplace operator acting on co-closed primitive (1, 1) forms (cf. Moroianu et al. in Pacific J Math 235:57–72, 2008). Using the Hermitian Laplace operator and some representation theory, we compute the space NK{\mathcal {NK}} on all 6-dimensional homogeneous nearly K?hler manifolds. It turns out that the nearly K?hler structure is rigid except for the flag manifold F(1, 2) = SU₃/T ², which carries an 8-dimensional moduli space of infinitesimal nearly K?hler deformations, modeled on the Lie algebra \mathfraksu₃{\mathfrak{su}_3} of the isometry group.     

Single-shot two-dimensional spectrometer

A two-dimensional optical spectrometer is demonstrated using simple optical components. This spectrometer is based on ultrafast two-dimensional (2D) frequency-dispersed pump-probe spectroscopy and can be used for single-shot correlation spectroscopy. To demonstrate functionality of this device, we measure the 2D correlation spectrum of atomic rubidium.     

Measurement of the polarization correlation parameter C nn in the pp elastic scattering with an unpolarized proton target and an unpolarized 1-GeV proton beam

The polarization correlation parameter C _nn in the elastic proton-proton scattering was for the first time measured with a high statistical accuracy at 1 GeV using an unpolarized proton beam incident on an unpolarized proton target. Both outgoing protons from the reaction were detected in coincidence by means of a two-arm focusing magnetic spectrometer installed at nonsymmetric angles corresponding to the center-of-mass scattering angle Θ_cm = 62.25°. The correlation parameter C _nn , as well as polarizations P ₁ and P ₂ of the secondary protons, were measured by means of multiwire proportional chamber polarimeters placed at the focal planes of each spectrometer arm. The obtained data are compared with the predictions of the phase-shift analysis. The connection with the experiment on C _nn and polarization measurements in the (p, 2p) reaction on ⁴He and other light nuclei in similar kinematics is discussed     

Pictorial Representation for Antisymmetric Eigenfunctions of <Emphasis Type="Italic">PS</Emphasis>–3 Integral Equations

Eigenvalue problem for Poincare-Steklov-3 integral equation is reduced to the solution of three transcendential equations for three unknown numbers, moduli of pants. The complete list of antisymmetric eigenfunctions of integral equation in terms of Kleinian membranes is given.     

Double-differential cross sections and kerma coefficients for light-charged particles produced by 96 MeV neutrons on carbon

Double-differential cross sections of inclusive light-ion (p, d, t, ³He and α) production in carbon induced by 96 MeV neutrons have been measured at eight laboratory angles from 20° to 160° in steps of 20°. Experimental techniques, as well as procedures for data taking and data reduction, are presented. Deduced energy-differential and production cross sections are herewith reported. Experimental cross sections are compared with theoretical reaction model calculations and experimental data in the literature. The measured production cross sections for protons, deuterons, tritons, ³He, and α particles support the trends suggested by data at lower energies. Deduced partial kerma coefficients for carbon are also shown.     

Optical Characterization of Zinc Pyrithione

Zinc pyrithione is ubiquitous in commercial products particularly antidandruff shampoos. For the efficacy of zinc pyrithione therapeutic cleansers to be assessed accurately, the distribution of particles on the scalp needs to be visualized. Currently, no technique is available which provides the chemical specificity and sensitivity required. Here, we report application of fluorescence‐lifetime imaging microscopy (FLIM) for high‐contrast mapping of zinc pyrithione distribution on the scalp. Characterization of the zinc pyrithione emission by using both one‐photon excitation at five specific wavelengths and two‐photon excitation in the range of 740–820 nm revealed its FLIM fingerprint—a characteristic short average time‐weighted emission lifetime of Τ_ZnPT = 250 ps. Bandpass‐filtering FLIM signals at Τ_ZnPT enabled an efficient discrimination between the zinc pyrithione and major endogenous skin species in comparison with that of the conventional reflectance confocal microscopy. Our findings provide means for in vivo high‐sensitivity assaying and high‐contrast imaging of zinc pyrithione in biological systems.