排序方式: 共有167条查询结果,搜索用时 812 毫秒
71.
Hongjing Sun Michele M. Kim Yi Hong Ong Andreea Dimoft Sunil Singhal Theresa M. Busch Keith A. Cengel Timothy C. Zhu 《Photochemistry and photobiology》2023,99(2):814-825
Photodynamic therapy (PDT) has been used to treat malignant pleural mesothelioma. Current practice involves delivering light to a prescribed light fluence with a point source, monitored by eight isotropic detectors inside the pleural cavity. An infrared (IR) navigation system was used to track the location of the point source throughout the treatment. The recorded data were used to reconstruct the pleural cavity and calculate the light fluence to the whole cavity. An automatic algorithm was developed recently to calculate the detector positions based on recorded data within an hour. This algorithm was applied to patient case studies and the calculated results were compared to the measured positions, with an average difference of 2.5 cm. Calculated light fluence at calculated positions were compared to measured values. The differences between the calculated and measured light fluence were within 14% for all cases, with a fixed scattering constant and a dual correction method. Fluence-surface histogram (FSH) was calculated for photofrin-mediated PDT to be able to cover 80% of pleural surface area to 50 J cm−2(83.3% of 60 J cm−2). The study demonstrates that it will be possible to eliminate the manual measurement of the detector positions, reducing the patient's time under anesthesia. 相似文献
72.
Research on Chemical Intermediates - A series of mono- and di-cationic pyridinium salts with one or two promesogenic cyanobiphenyl groups and different counterions, bromide, dodecylsulfate or... 相似文献
73.
Journal of Russian Laser Research - Using the axiomatic formalism based on completely positive quantum dynamical semigroups, we describe the dynamics of quantum coherence of an open system... 相似文献
74.
Cristina-Ramona Metzner Ungureanu Mariana-Atena Poiana Ileana Cocan Andreea Ioana Lupitu Ersilia Alexa Diana Moigradean 《Molecules (Basel, Switzerland)》2020,25(23)
This research was conducted in order to establish the effectiveness of two freeze-dried extracts obtained from blueberry processing byproducts resulting from juice manufacturing compared to butylated hydroxytoluene (BHT) in delaying the lipid oxidation of sunflower oil subjected to high-temperature convective heating at 180 °C up to 12 h under simulated frying conditions. The fruits were harvested from spontaneous flora of two regions of Romania, Arieseni (Alba County) and Paltinis (Sibiu County) and the blueberry byproducts extracts (BBE) were noted according to the origin place as ABBE and PBBE. The progress of lipid thermo-oxidation was investigated in terms of peroxide value (PV), p-anisidine value (p-AV), the response of TBA-malondialdehyde interactions assessed by thiobarbituric acid (TBA) method, the total oxidation (TOTOX) value and inhibition of oil oxidation (IO). The recorded data highlighted that BBE exhibit a high inhibitory response on lipid thermo-oxidation. The inhibitory effect was concentration-dependent, thus, the degree of lipid oxidation was in reverse related to the BBE dose. The exposure of the oil samples supplemented with 800 ppm BBE (ABBE, PBBE) to a high-temperature heating for 12 h led to a significant decrease of the assessed indices compared to additives-free sunflower oil sample as follows: PV (46%; 45%), p-AV (21%; 17%), TOTOX (27%; 24%), TBA value (25%; 11%). Regarding the impact of the origin on the potential of BBE to inhibit the lipid oxidative degradation, it was noted that ABBE derived from blueberries grown in a region with a milder climate with moderate precipitations and higher temperatures showed a stronger inhibitory effect on lipid thermo-oxidation than PBBE. A moderate level of 500 ppm BBE inhibited the lipid oxidation similar to 200 ppm BHT. The reported results reveal that BBE represent efficient natural antioxidants that could be successfully applied to improve the thermo-oxidative stability of sunflower oil used in various high-temperature food applications. 相似文献
75.
Iris Koch Markus Langner Dennis Holzinger Maximilian Merkel Meike Reginka Rico Huhnstock Andreea Tomiţa Claudia Jauregui Caballero Andreas Greiner Arno Ehresmann 《Particle & Particle Systems Characterization》2021,38(12):2100072
The possibility to arrange and embed magnetic micro- and nanoparticles in thin polymer film systems using flat magnetically patterned substrate templates is investigated. In contrast to self-organized particle rows forming by applying a homogeneous magnetic field, particles adapt to the magnetic field landscape of the substrate's magnetic pattern prior to polymer crosslinking. Crosslinking then fixes the particle positions in the polymer. The process is tested for composites of hydrophobic polydimethylsiloxane (PDMS) and maghemite nanoparticles as well as for hydrophilic polyvinyl alcohol (PVOH) and hydrophilic functionalized, superparamagnetic core–shell microspheres. The substrate template is an exchange bias layer system magnetically patterned into parallel-stripe domains with in-plane magnetizations and head-to-head/tail-to-tail remanent magnetization orientation in adjacent magnetic domains. A high occupancy percentage of magnetic beads on a domain wall as well as anisotropic actuation of the composite is achieved. 相似文献
76.
Andreea Pasc Patrick Gizzi Stéphane Parant Christine Gérardin 《Tetrahedron letters》2009,50(45):6183-8238
The synthesis of novel histidine-based surfactants and their self-assembling properties into anisotropic microscopic and macroscopic spaces are reported. Below pH 8, surfactant molecules self-assemble into micelles whereas hydrogelation occurs above pH 8 even at very low concentrations (0.3%w/v). Structure, size, and morphology of the fiber-like lamellar aggregates were determined by SAXS and WAXS measurements, polarized optical microscopy, transmission and scanning electron microscopy, and linear and circular dichroism. 相似文献
77.
Andreea Calin Manfred Wilhelm Corneliu Balan 《ournal of non Newtonian Fluid Mechanics》2010,165(23-24):1564-1577
The paper introduces a novel procedure to determine the non-linear parameter of the Giesekus model, in relation to the characterization of the non-linear oscillatory shear regime of viscoelastic polymer solutions based on polyacrylamide. Instead of using the shear-thinning viscosity as the representative non-linear effect, the third harmonic in the Fourier spectrum of the shear stress response signal is considered for computing the mobility factor. The fluid is subjected to large amplitude oscillatory shear (LAOS) and its response is recorded. Deviations of this signal from the sinusoidal form are specific to each material and gives both qualitative and quantitative measures of the non-linearity. By fitting the material response with the corresponding numerical solutions of the n-modes Giesekus constitutive relation, one can extract the values of the non-linear αi-parameters that describe the fluid rheology. It is demonstrated that this procedure, which can be successfully applied to semi-concentrated polymer solutions, provides better results than the classical viscosity-fit method. 相似文献
78.
Herein we report the synthesis of a chiral imidazolium salt derived from trans-L-hydroxyproline and its applications as a catalyst for the asymmetric aldol reaction. By performing the aldol reaction in [Bmim]NTf(2) as a solvent, we report excellent isolated yields of the aldol product (up to 99%), as well as modest to excellent selectivities (dr superior to 99:1. ee up to 89%). Mechanistic insights and the origins of the selectivity of the aldol reaction are discussed on the basis of the results obtained with two catalytic imidazolium salts having different H-bonding potential. 相似文献
79.
A method for the cross-coupling of alkyl electrophiles with various potassium aryl- and heteroaryltrifluoroborates has been developed. Nearly stoichiometric amounts of organoboron species could be employed to cross-couple a large variety of challenging heteroaryl nucleophiles. Several functional groups were tolerated on both the electrophilic and the nucleophilic partners. Chemoselective reactivity of C(sp(3))-Br bonds in the presence of C(sp(2))-Br bonds was achieved. 相似文献
80.
The authors of this paper aim to highlight issues related to the organology and the integration of the hardware component in the mechanical structure of a tracked mini robot, called Robo Geniu, part of the unmanned ground vehicles category having the ability to act autonomously and enabling its endowment with means of observation, listening, tapping, relaying and jamming. This paper reveals, in detail, the composing parts of the hardware component, as well as the way they are assembled in the mechanical structure of the mini robot under study. (© 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献