首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   10172篇
  免费   562篇
  国内免费   42篇
化学   7489篇
晶体学   49篇
力学   165篇
数学   1602篇
物理学   1471篇
  2023年   79篇
  2022年   82篇
  2021年   157篇
  2020年   238篇
  2019年   203篇
  2018年   149篇
  2017年   125篇
  2016年   427篇
  2015年   387篇
  2014年   409篇
  2013年   492篇
  2012年   673篇
  2011年   730篇
  2010年   510篇
  2009年   420篇
  2008年   667篇
  2007年   580篇
  2006年   550篇
  2005年   563篇
  2004年   482篇
  2003年   352篇
  2002年   322篇
  2001年   171篇
  2000年   140篇
  1999年   155篇
  1998年   121篇
  1997年   161篇
  1996年   119篇
  1995年   112篇
  1994年   109篇
  1993年   98篇
  1992年   96篇
  1991年   66篇
  1990年   51篇
  1989年   73篇
  1988年   59篇
  1987年   37篇
  1986年   37篇
  1985年   56篇
  1984年   40篇
  1983年   33篇
  1982年   57篇
  1981年   41篇
  1980年   36篇
  1979年   33篇
  1978年   30篇
  1977年   29篇
  1975年   27篇
  1974年   18篇
  1973年   20篇
排序方式: 共有10000条查询结果,搜索用时 163 毫秒
61.
Lufthansa Technical Training GmbH (LTT) performs training courses for Lufthansa Technik AG as well as for several other international airlines. Courses of about 670 different types are offered of which several hundred take place each year. The course scheduling problem faced by LTT is to construct a yearly schedule which maximizes the profit margin incurred while meeting a variety of complex precedence, temporal, and resource-related constraints. A “good” operational schedule should also meet a number of additional subordinate objectives. We formalize the problem and develop a heuristic scheme along with several priority rules, as well as a local search algorithm to determine well-suited weights for weighted composite rules. The operational planning situation of 1996 served as our major test instance; additional test instances were constructed by modifying this data. Several computational experiments were carried out to evaluate the performance of the algorithms. It turned out that the best so-found schedule is substantially better in terms of the profit margin incurred than the solution manually constructed by LTT.  相似文献   
62.
63.
Andreas Vohns 《ZDM》2006,38(6):498-504
“Basic ideas” (or “fundamental ideas” etc.) have been discussed in mathematical curriculum theory for about forty years. This paper will centre on the hypothesis that this concept can only be applied successfully by using it as a category for the analysis of concrete mathematical problems. This hypothesis will be illustrated by means of a sample problem from the Austrian Standards for Mathematics Education (“Bildungsstandards”). In this example, basic ideas are used in a content matter analysis which takes students' solutions to the problem as a starting point for the creation of a potentially substantial learning environment in trigonometry.  相似文献   
64.
65.
66.
Cyclic Oligomers of (R)-3-Hydroxybutanoic Acid: Preparation and Structural Aspects The oligolides containing three to ten (R)-3-hydroxybutanoate (3-HB) units (12-through 40-membered rings 1–8 ) are prepared from the hydroxy acid itself, its methyl ester, its lactone (‘monolide’), or its polymer (poly(3-HB), mol. wt. ca. 106 Dalton) under three sets of conditions: (i) treatment of 3-HB ( 10 ) with 2,6-dichlorobenzoyl chloride/pyridine and macrolactonization under high dilution in toluene with 4-(dimethylamino)pyridine (Fig. 3); (ii) heating a solution (benzene, xylene) of the β-lactone 12 or of the methyl ester 13 from 3-HB with the tetraoxadistanna compound 11 as trans-esterification catalyst (Fig. 4); (iii) heating a mixture of poly(3-HB) and toluene-sulfonic acid in toluene/1,2-dichloroethane for prolonged periods of time at ca. 100° (Fig. 6). In all three cases, mixtures of oligolides are formed with the triolide 1 being the prevailing component (up to 50% yield) at higher temperatures and with longer reaction times (thermodynamic control, Figs. 3–6). Starting from rac-β-lactone rac- 12 , a separable 3:1 to 3:2 mixture of the l,u- and the l,l-triolide diasteroisomers rac- 14 and rac- 1 , respectively, is obtained. An alternative method for the synthesis of the octolide 6 is also described: starting from the appropriate esters 15 and 17 and the benzyl ether 16 of 3-HB, linear dimer, tetramer, and octamer derivatives 18–23 are prepared, and the octamer 23 with free OH and CO2H group is cyclized (→ 6 ) under typical macrolactonization conditions (see Scheme). This ‘exponential fragment coupling protocol’ can be used to make higher linear oligomers as well. The oligolides 1–8 are isolated in pure form by vacuum distillation, chromatography, and crystallization, an important analytical tool for determining the composition of mixtures being 13C-NMR spectroscopy (each oligolide has a unique and characteristic chemical shift of the carbonyl C-atom, with the triolide 1 at lowest, the decolide 8 at highest field). The previously published X-ray crystal structures of triolide 1 , pentolide 3 , and hexolide 4 (two forms), as well as those of the l,u-triolide rac- 14 , of tetrolide ent- 2 , of heptolide 5 , and of two modifications of octolide 6 described herein for the first time are compared with each other (Figs. 7–10 and 12–15, Tables 2 and 5–7) and with recently modelled structures (Tables 3 and 4, Fig. 11). The preferred dihedral angles τ1 to τ4 found along the backbone of the nine oligolide structures (the hexamer and the larger ones all have folded rings!) are mapped and statistically evaluated (Fig. 16, Tables 5–7). Due to the occurrence of two conformational minima of the dihedral angle O? CO? CH2? CH (τ3 = + 151 or ?43°), it is possible to locate two types of building blocks for helices in the structures at hand: a right-handed 31 and a left-handed 21 helix; both have a ca. 6 Å pitch, but very different shapes and dispositions of the carbonyl groups (Fig. 17). The 21 helix thus constructed from the oligolide single-crystal data is essentially superimposable with the helix derived for the crystalline domains of poly(3-HB) from stretched-fiber X-ray diffraction studies. The absence of the unfavorable (E)-type arrangements around the OC? OR bond (‘cis-ester’) from all the structures of (3-HB) oligomers known so far suggests that the model proposed for a poly(3-HB)-containing ion channel (Fig. 2) must be modified.  相似文献   
67.
68.
69.
The method of infrared bounds is extended to a large class of nearest neighbour interactions in classical spin systems. Temperature controlled bounds on fluctuations follow whenever the coupling function is a positive definite kernel. Existence of phase transitions is demonstrated for the RP Nmodel for d3.  相似文献   
70.
Cross ratios constitute an important tool in classical projective geometry. Using the theory of Tutte groups as discussed in [6] it will be shown in this note that the concept of cross ratios extends naturally to combinatorial geometries or matroids. From a thorough study of these cross ratios which, among other observations, includes a new matroid theoretic version and proof of the Pappos theorem, it will be deduced that for any projective space M= n (K) of dimension n2 of M over some skewfield K the inner Tutte group is isomorphic to the commutator factor group K */[K *, K *] of K *K{0}. This shows not only that in case M= n (K) our matroidal cross ratios are nothing but the classical ones. It can also be used to correlate orientations of the matroid M= n (K) with the orderings of K. And it implies that Dieudonné's (non-commutative) determinants which, by Dieudonné's definition, take their values in K */[K *, K *] as well, can be viewed as a special case of a determinant construction which works for just every combinatorial geometry.Research supported by the DFG (Deutsche Forschungsgemeinschaft).  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号