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31.
Summary The surface tensions of aqueous solutions ofn-alkylammonium chlorides (methyl to hexyl) have been measured at 25 °C. With methylammonium chloride the surface tension increased with concentration, whereas with ethylammonium chloride and higher homologues, the surface tension decreased with concentration. The results suggest that this transition is attributed to the effect of hydrophobic hydration. For propylammonium chloride and higher homologues, the relation between the surface tension lowering da and the concentrationC in the range of 0–10 dyne/cm, can be expressed by the equation; = AC + BC, whereA andB are constants. The surface tension coefficientB has been found to increase approximately twofold for each additional CH2 group of alkyl chain.
Zusammenfassung Es wurden die Oberflächenspannungen wäßriger Lösungen vonn-Alkylammoniumchloriden (Methyl- bis Hexylammoniumchloride) bei 25 °C gemessen. Für Methylammoniumchlorid nimmt die Oberflächenspannung mit der Konzentration zu, aber bei allen höheren Homologen mit der Konzentration ab. Die Ergebnisse deuten darauf hin, daß dieser Übergang durch die hydrophobe Hydration bedingt wird. Für Propylammonium-chlorid und die höheren Homologen wird die Beziehung zwischen der Erniedrigung der Oberflächenspannung und der KonzentrationC in dem Bereich von 1 bis 10 dyn/cm durch die folgende Gleichung ausgedrückt: = AC + BC (A undB sind Konstanten). Es wurde gefunden, daß B für jede zusätzliche CH2-Gruppe etwa um den Faktor 2 größer wird.
  相似文献   
32.
Summary A new technique is described for the identification of the chloride ion through the formation of chromyl chloride, based on the extraction of the latter with carbon tetrachloride. The identification limit is 2g of chloride. It is possible to carry out the test in the presence of many other anions, including fluoride, which cannot be present when the traditional distillation technique is employed.
Zusammenfassung Vorgeschlagen wird eine neue Technik zum Chloridnachweis durch Bildung von Chromylchlorid. Dieser Nachweis beruht auf der Extraktion des Chromylchlorids mit Tetrachlorkohlenstoff. Die Nachweisgrenze liegt bei 2g Chlorid, wobei die Möglichkeit besteht, den Test auch in Gegenwart von Fluorid durchzuführen, das bei Anwendung der üblichen Destillationsmethoden nicht anwesend sein darf.
  相似文献   
33.
Preparation and physical and chemical properties of 3-ethinyl-2,4-diformyl-pentandial (3 a) and its salts are described.3 a contains 2 malonaldehyde groups. Starting from3 a, 4H-pyranes, 4H-dihydropyridines, dipyrazoles, diisoxazoles, bisdiazepines and vinamidine derivates are obtained.

Mit 1 Abbildung  相似文献   
34.
Tetrahydro-6-hydroxy-trimethyl-1,3-thiazine-2-thione (1) reacts with secondary amines via the dialkylammonium-3-oxoalkyldithiocarbamate3, either via isothiocyanates6 to 4-dialkylaminodihydro-2(1H)-pyridinethiones7 or to dialkylammonium dithiocarbamates (13), depending on the amine used and the reaction conditions. Subsequently, 6-dialkylaminotetrahydro-1,3-thiazine-2-thiones11 or tetrahydro-6-mercapto-1,3-thiazine-2-thione10 are formed. On being heated to reflux,11 reacts to pyridinethione7 and 4-dialkylaminodihydrothiopyranthione19. With secondary amines only13 is formed from tetrahydro-6-hydroxytetramethyl-1,3-thiazine-2-thione20. The reaction of dihydrotrimethyl-1,3-thiazine-2-thione21 with secondary amines leads to N,N-dialkylthioureas16 or dialkylammonium thiocyanates17 and with dialkylformamides 4-dialkylaminodihydropyridinethiones7 are formed. Dihydrotetramethyl-1,3-thiazine-2-thione24 reacts neither with secondary amines nor with dialkylformamides.  相似文献   
35.
The reactions of the bidentate dinitrosoresorcinol (DNR) with copper, cobalt, nickel, iron and zinc salts were investigated. This ligand was found to react with these metal salts in aqueous media where hydrogen ion was confirmed to be liberated except in case of iron. The solid complexes were prepared in alcoholic media. Chemical analyses, magnetic and spectral data were compatible to determine the structure of these complexes and their mode of chelation.

Mit 2 Abbildungen  相似文献   
36.
The electrochemical oxidation of arylmethylene-pyrrolinones, pyrromethenones and pyrromethenes as representative bile pigment partial structure models was investigated by means of a rotating disc platinum electrode using acetonitrile as the solvent. Two different oxidation reactions were found. The first reaction being a reversible one-electron oxidation with compounds of the arylmethylene-pyrrolinone series and pyrromethenones which are unsubstituted in position 5 of the pyrrole ring. A two step reaction (the first one reversible, the second irreversible) on the other hand was found to be typical for pyrromethenones bearing a methyl group in this position.Through protonation the first step is at a higher potential, whereas the second one is lowered and becomes reversible. The resulting oxidation pattern can be interpreted analogous to the oxidation of hydroquinones in aprotic solvents.The geometrical isomers of a pyrromethenone were oxidized at appr. the same potential, but there is a strong dependence of the potential of the first oxidation step on the substitution: a higher degree of alkylation favours oxidation by lowering the oxidation potential.

Mit 1 Abbildung  相似文献   
37.
By reaction of primary carboxamides with “dibromoisocyanuric acid” (DBI) N-monobromoamides can be readily obtained as well as the N,N-dibromoamides described in an earlier paper1. Reactions, some of them new, and properties of these compounds are described and compared with those of the N,N-dibromoamides. Like other compounds bearing the NHBr group2, 3 the N-monobromocarboxamides disproportionate at room temperature according to: 2 RCONHBr ? ? RCONH2+RCONBr2. For CH3CONHBr the equilibrium constant was found to beK=0.02. In aqueous solution they behave as weak acids. The dissociation constants of eight compounds [R=?CH3, ?C2H5, ?CH2Cl, ?CHCl2, ?CCl3, ?CF3, ?C(CH3)3 and ?C6H5] were measured: they differ from those of the corresponding carboxylic acids by about three powers of ten.  相似文献   
38.
The selective chlorination of a m/p-xylene mixture, followed by distillation of the unreacted p-xylene, leaves a residue containing up to 90% of monochlorinated m-xylenes. m-Xylene is recovered from the latter by heterogeneous catalytic hydrogenolysis in the gas-phase. It was found that the hydrogenolysis on certain noble metal catalysts proceeds according to an ionic reaction mechanism at temperatures below a definite temperature range. At temperatures above this range hydrogenolysis follows a radical reaction mechanism.  相似文献   
39.
The stoichiometry and structure of acetophenone benzoylhydrazone and acetophenone salicoylhydrazone chelates with some divalent metal ions are studied by conductometric titration and visible and infra-red absorption spectrophotometry. The results are supported by analysis of the solid complexes. The infra-red study revealed that coordination occurs through C=O and C=N groups. The shift in the C=O and C=N bands is utilised for the determination of bond lengths.  相似文献   
40.
The azido tetrazolo valence isomerism of twenty 9-methyl-s-triazolo[4,3-c]tetrazolo[1,5-a]pyrimidines with different substituents at position 5 has been studied by means of 1H NMR spectroscopy. All the compounds have been found to be tetrazoles in the solid state and in (CD3)2SO solution; in CF3COOH azido and tetrazolo isomers are in equilibrium. From equilibrium constants K and thermodynamic data determined it is concluded that in this series K depends on both electronic effects and steric requirements of the 5-substituents. A linear relation between K and σ was found for 5-arylderivatives because ΔS° keeps approximately constant and the substituent mainly operates on ΔH°.  相似文献   
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