全文获取类型
收费全文 | 9729篇 |
免费 | 552篇 |
国内免费 | 42篇 |
专业分类
化学 | 7259篇 |
晶体学 | 32篇 |
力学 | 159篇 |
数学 | 1502篇 |
物理学 | 1371篇 |
出版年
2023年 | 75篇 |
2022年 | 95篇 |
2021年 | 154篇 |
2020年 | 229篇 |
2019年 | 199篇 |
2018年 | 146篇 |
2017年 | 120篇 |
2016年 | 415篇 |
2015年 | 378篇 |
2014年 | 401篇 |
2013年 | 476篇 |
2012年 | 661篇 |
2011年 | 704篇 |
2010年 | 503篇 |
2009年 | 410篇 |
2008年 | 652篇 |
2007年 | 576篇 |
2006年 | 541篇 |
2005年 | 554篇 |
2004年 | 472篇 |
2003年 | 338篇 |
2002年 | 311篇 |
2001年 | 156篇 |
2000年 | 129篇 |
1999年 | 149篇 |
1998年 | 115篇 |
1997年 | 158篇 |
1996年 | 109篇 |
1995年 | 109篇 |
1994年 | 105篇 |
1993年 | 92篇 |
1992年 | 88篇 |
1991年 | 58篇 |
1990年 | 42篇 |
1989年 | 68篇 |
1988年 | 54篇 |
1987年 | 31篇 |
1986年 | 31篇 |
1985年 | 45篇 |
1984年 | 36篇 |
1983年 | 22篇 |
1982年 | 45篇 |
1981年 | 30篇 |
1980年 | 25篇 |
1979年 | 23篇 |
1978年 | 20篇 |
1977年 | 18篇 |
1975年 | 22篇 |
1973年 | 16篇 |
1968年 | 14篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
921.
922.
Andreas Mautner Xiaohua Qin Harald Wutzel Samuel C. Ligon Barbara Kapeller Doris Moser Guenter Russmueller Juergen Stampfl Robert Liska 《Journal of polymer science. Part A, Polymer chemistry》2013,51(1):203-212
Monomers for radical photopolymerization based on vinyl esters (VEs) have recently been identified as suitable alternatives to (meth)acrylates on account of their low irritancy and cytotoxicity. The drawback of most VEs with abstractable hydrogens is their relatively low reactivity compared with (meth)acrylates. Within this article, we proved by photo‐differential scanning calorimetry measurements and real‐time Fourier transform infrared spectroscopy that the thiol‐ene concept is able to improve the photoreactivity of these VEs to a large extent to a level between those of acrylates and methacrylates. Other VEs have now a reactivity of at least the level of similar acrylates. Mechanical properties as determined by Dynamic Mechanical Analysis and Charpy impact tests showed significant toughening of these materials. Furthermore, we were able to confirm low toxicity of all components by osteoblast cell culture experiments. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
923.
Feichtinger Gustav Andreas J. Novak 《Mathematical and Computer Modelling of Dynamical Systems: Methods, Tools and Applications in Engineering and Related Sciences》2013,19(3):197-211
In this paper we present a simple time-continuous behavioural model of habit formation. Addictive behaviour is damped by a threshold which adapts itself to the habit. This adaptive behaviour of the threshold may lead to periodic fluctuations of the consumption rate, the habit and the threshold. It turns out that both a low adjustment rate of the threshold as well as a steep consumption function favour oscillatory patterns. 相似文献
924.
Peter Medley Andreas Bollhöfer Paul Martin 《Journal of Radioanalytical and Nuclear Chemistry》2013,296(2):1155-1162
Low-level measurements of 210Po using alpha spectrometry with a 209Po tracer have been conducted at the Environmental Research Institute of the Supervising Scientist (eriss) for many years, on samples with a range of activity concentrations spanning several orders of magnitude. These samples originated from a wide range of research and monitoring projects, and included a wide variety of traditional foods consumed by the indigenous population in Australia’s Northern Territory. Assessment of instrument blank and analyte blank data from these measurements collected over a period of 8 years was conducted. Instrumental blank data for 210Po and 209Po generally followed a normal distribution, whereas analyte blank data for 210Po followed a lognormal distribution. Instrumental blank data for 209Po indicated an increasing trend, indicative of a low level of polonium volatilisation from prepared sources. Lower limits of detection, including the critical limit, detection limit and quantification limit have been calculated. The critical limit ranges from 12 to 37 counts per day. Detection and quantification limits range from 0.18 to 0.33 mBq and 2.3 to 3.6 mBq for a 4-day count, with an assumed mean chemical recovery of 53 %. These limits are relatively high for alpha spectrometric techniques due to the high variability of the analyte blank signal and non-normal distribution for 210Po. Native plant species have relatively low activity concentrations of 210Po in their edible fruits and the amount of sample that should be used for analysis to ensure 90 % of fruit samples analysed reach the specified quantification limit was 11 g. 相似文献
925.
Thomas Kania Boris Schilder Thilo Kissel Peter Stephan Steffen Hardt Andreas Dreizler 《Flow, Turbulence and Combustion》2013,90(4):741-761
New developments in portable electrical and mechanical devices have created demand for increasing amounts of energy and thus new ways of supplying energy. The high energy density of hydrocarbon fuels are a possible way to solve this issue. This paper deals with the development of an adapted thermodynamic concept for a micro energy converter based on the thermoelectric effect. Developing a PowerMEMS device that does not contain any moving parts is the main design feature. In the proposed concept liquid hydrocarbon fuel, such as methanol, is evaporated in a micro evaporator, mixed with air, and combusted in a micro combustion chamber. The combustion process is assisted by catalytically coated microfibers. Electrical power can be generated by a thermoelectric generator, which is located between the hot combustion zone and the cold micro evaporator. This arrangement leads to large temperature differences between hot and cold junctions, which is necessary for efficient thermoelectric energy conversion and hence power generation. For a more detailed investigation of thermal boundary conditions and interior thermal management, in-situ temperature measurements of the combustor walls are performed using thermographic phosphors. 相似文献
926.
Hong Cai David P‐. Berry Giuseppe Garcea Karen Brown William P. Steward Andreas J. Gescher 《Biomedical chromatography : BMC》2011,25(6):660-663
Anthocyanins possess cancer chemopreventive properties in preclinical models. Their clinical pharmacology is only poorly understood. In this pilot study, anthocyanins and their metabolites were analysed in the urine of two patients with colorectal liver metastases. They received a single dose of 1.88 g standardized bilberry extract (mirtoselect) via either nasogastric or nasojejunal tube intra‐operatively during liver resection. HPLC‐MS/MS and HPLC‐UV analysis showed there were more anthocyanins and metabolites in the urine of the patient who received mirtoselect via the stomach than via the jejunum. This result is consistent with information obtained in rodents which suggests the stomach is the predominant site for anthocyanin absorption. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
927.
For quasianalytic Denjoy-Carleman differentiable function classes CQ where the weight sequence Q=(Qk) is log-convex, stable under derivations, of moderate growth and also an L-intersection (see (1.6)), we prove the following: The category of CQ-mappings is cartesian closed in the sense that CQ(E,CQ(F,G))≅CQ(E×F,G) for convenient vector spaces. Applications to manifolds of mappings are given: The group of CQ-diffeomorphisms is a regular CQ-Lie group but not better. 相似文献
928.
929.
930.
Dušan Repovš Witold Rosicki Žiga Virk Andreas Zastrow 《Topology and its Applications》2012,159(10-11):2609-2620
This paper shows that a construction, which was introduced by Piotr Minc in connection with a problem that came from Helly type theorems and that allows to replace three PL-arcs with a “sheltered middle path”, can in the case of general (non-PL) paths result in the topologist?s sine curve. 相似文献