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971.
972.
We introduce a notion of relative efficiency for axiom systems. Given an axiom system Aβ for a theory T consistent with S12, we show that the problem of deciding whether an axiom system Aα for the same theory is more efficient than Aβ is II2-hard. Several possibilities of speed-up of proofs are examined in relation to pairs of axiom systems Aα, Aβ, with Aα ? Aβ, both in the case of Aα, Aβ having the same language, and in the case of the language of Aα extending that of Aβ: in the latter case, letting Prα, Prβ denote the theories axiomatized by Aα, Aβ, respectively, and assuming Prα to be a conservative extension of Prβ, we show that if Aα — Aβ contains no nonlogical axioms, then Aα can only be a linear speed-up of Aβ; otherwise, given any recursive function g and any Aβ, there exists a finite extension Aα of Aβ such that Aα is a speed-up of Aβ with respect to g. Mathematics Subject Classification: 03F20, 03F30. 相似文献
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976.
Catalytic Asymmetric Reactions of 4‐Substituted Indoles with Nitroethene: A Direct Entry to Ergot Alkaloid Structures 下载免费PDF全文
Simone Romanini Emilio Galletti Dr. Lorenzo Caruana Prof. Andrea Mazzanti Prof. Fahmi Himo Dr. Stefano Santoro Prof. Mariafrancesca Fochi Prof. Luca Bernardi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(49):17578-17582
A domino Friedel–Crafts/nitro‐Michael reaction between 4‐substituted indoles and nitroethene is presented. The reaction is catalyzed by BINOL‐derived phosphoric acid catalysts, and delivers the corresponding 3,4‐ring‐fused indoles with very good results in terms of yields and diastereo‐ and enantioselectivities. The tricyclic benzo[cd]indole products bear a nitro group at the right position to serve as precursors of ergot alkaloids, as demonstrated by the formal synthesis of 6,7‐secoagroclavine from one of the adducts. DFT calculations suggest that the outcome of the reaction stems from the preferential evolution of a key nitronic acid intermediate through a nucleophilic addition pathway, rather than to the expected “quenching” through protonation. 相似文献
977.
Andrea Cristofari 《Optimization Letters》2017,11(8):1527-1546
A data filtering method for cluster analysis is proposed, based on minimizing a least squares function with a weighted \(\ell _0\)-norm penalty. To overcome the discontinuity of the objective function, smooth non-convex functions are employed to approximate the \(\ell _0\)-norm. The convergence of the global minimum points of the approximating problems towards global minimum points of the original problem is stated. The proposed method also exploits a suitable technique to choose the penalty parameter. Numerical results on synthetic and real data sets are finally provided, showing how some existing clustering methods can take advantages from the proposed filtering strategy. 相似文献
978.
Mehiddin Al-Baali Andrea Caliciotti Giovanni Fasano Massimo Roma 《Mathematical Methods of Operations Research》2017,86(3):501-522
In this paper we propose the use of damped techniques within Nonlinear Conjugate Gradient (NCG) methods. Damped techniques were introduced by Powell and recently reproposed by Al-Baali and till now, only applied in the framework of quasi-Newton methods. We extend their use to NCG methods in large scale unconstrained optimization, aiming at possibly improving the efficiency and the robustness of the latter methods, especially when solving difficult problems. We consider both unpreconditioned and Preconditioned NCG. In the latter case, we embed damped techniques within a class of preconditioners based on quasi-Newton updates. Our purpose is to possibly provide efficient preconditioners which approximate, in some sense, the inverse of the Hessian matrix, while still preserving information provided by the secant equation or some of its modifications. The results of an extensive numerical experience highlights that the proposed approach is quite promising. 相似文献
979.
Andrea Dorila Cárcamo Bahamonde Josep Maria Fortuny Aymemí Joan Vicenç Gómez i Urgellés 《International Journal of Mathematical Education in Science & Technology》2017,48(3):338-352
In this article we present a didactic proposal for teaching linear algebra based on two compatible theoretical models: emergent models and mathematical modelling. This proposal begins with a problematic situation related to the creation and use of secure passwords, which leads students toward the construction of the concepts of spanning set and span. The objective is to evaluate this didactic proposal by determining the level of match between the hypothetical learning trajectory (HLT) designed in this study with the actual learning trajectory in the second experimental cycle of an investigation design-based research more extensive. The results show a high level of match between the trajectories in more than half of the conjectures, which gives evidence that the HLT has supported, in many cases, the achievement of the learning objective, and that additionally mathematical modelling contributes to the construction of these linear algebra concepts. 相似文献
980.
A subset {g 1,..., g d } of a finite group G invariably generates \(\left\{ {g_1^{{x_1}}, \ldots ,g_d^{{x_d}}} \right\}\) generates G for every choice of x i ∈ G. The Chebotarev invariant C(G) of G is the expected value of the random variable n that is minimal subject to the requirement that n randomly chosen elements of G invariably generate G. The first author recently showed that \(C\left( G \right) \leqslant \beta \sqrt {\left| G \right|} \) for some absolute constant β. In this paper we show that, when G is soluble, then β is at most 5/3. We also show that this is best possible. Furthermore, we show that, in general, for each ε > 0 there exists a constant c ε such that \(C\left( G \right) \leqslant \left( {1 + \in } \right)\sqrt {\left| G \right|} + {c_ \in }\). 相似文献