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91.
Andrea D. Beck David G. Flad Claudia Tonhäuser Gregor Gassner Claus-Dieter Munz 《Flow, Turbulence and Combustion》2016,97(2):475-511
In this work we investigate the interplay of polynomial de-aliasing and sub-grid scale models for large eddy simulations based on discontinuous Galerkin discretizations. It is known that stability is a major concern when simulating underresolved turbulent flows with high order nodal collocation type discretizations. By changing the interpolatory character of the nodal collocation type discretization to a projection based discretization by increasing the number of quadrature points (polynomial de-aliasing), one is able to remove the aliasing induced stability problems. We focus on this effect and on the consequence for large eddy simulations with explicit subgrid scale models. Often, subgrid scale models have to achieve two possibly conflicting tasks in a single simulation: firstly stabilizing the numerics and secondly modeling the physical effect of the missing scales. Within a discontinuous Galerkin approach, it is possible to use either a fast (but potentially aliasing afflicted) nodal collocation discretization or a projection-based (but computationally costly) variant in combination with an explicit subgrid scale model. We use this framework to investigate the effect on the appropriate model parameter of a standard Smagorinsky subgrid scale model and of a Variational Multiscale Smagorinsky formulation. For this we first consider the 3-D viscous Taylor-Green vortex example to investigate the impact on the stability of the method and second the turbulent flow past a circular cylinder to investigate and compare the accuracy of the results. We show that the aliasing instabilities of collocative discretizations severely limit the choice of the model constant, in particular for high order schemes, while for de-aliased DG schemes, the closure model parameters can be chosen independently from the numerical scheme. For the cylinder flow, we also find that for the same model settings, the projection-based results are in better agreement with the reference DNS than those of the collocative scheme. 相似文献
92.
93.
94.
We assess the validity of a single step Godunov scheme for the solution of the magnetohydrodynamics equations in more than one dimension. The scheme is second-order accurate and the temporal discretization is based on the dimensionally unsplit Corner Transport Upwind (CTU) method of Colella. The proposed scheme employs a cell-centered representation of the primary fluid variables (including magnetic field) and conserves mass, momentum, magnetic induction and energy. A variant of the scheme, which breaks momentum and energy conservation, is also considered. Divergence errors are transported out of the domain and damped using the mixed hyperbolic/parabolic divergence cleaning technique by Dedner et al. (2002) [11]. The strength and accuracy of the scheme are verified by a direct comparison with the eight-wave formulation (also employing a cell-centered representation) and with the popular constrained transport method, where magnetic field components retain a staggered collocation inside the computational cell. Results obtained from two- and three-dimensional test problems indicate that the newly proposed scheme is robust, accurate and competitive with recent implementations of the constrained transport method while being considerably easier to implement in existing hydro codes. 相似文献
95.
In the late sixties the Canadian psychologist Laurence J. Peter advanced an apparently paradoxical principle, named since then after him, which can be summarized as follows: ‘Every new member in a hierarchical organization climbs the hierarchy until he/she reaches his/her level of maximum incompetence’. Despite its apparent unreasonableness, such a principle would realistically act in any organization where the mechanism of promotion rewards the best members and where the competence at their new level in the hierarchical structure does not depend on the competence they had at the previous level, usually because the tasks of the levels are very different to each other. Here we show, by means of agent based simulations, that if the latter two features actually hold in a given model of an organization with a hierarchical structure, then not only is the Peter principle unavoidable, but also it yields in turn a significant reduction of the global efficiency of the organization. Within a game theory-like approach, we explore different promotion strategies and we find, counterintuitively, that in order to avoid such an effect the best ways for improving the efficiency of a given organization are either to promote each time an agent at random or to promote randomly the best and the worst members in terms of competence. 相似文献
96.
97.
Michelina Soccio Nadia Lotti Lara Finelli Massimo Gazzano Andrea Munari 《Journal of Polymer Science.Polymer Physics》2010,48(17):1901-1910
Poly(glycolic acid) (PGA) and a series of novel random copolymers of PGA containing 2‐hydroxyisobutyrric acid (PGAPHIB) (HIB unit content from 1.5 to 7.4 mol %) were synthesized and characterized in terms of chemical structure and molecular weight. Afterward, the polyesters were examined by thermogravimetric analysis, differential scanning calorimetry, and X‐ray diffraction techniques. The copolymers, which displayed a better thermal stability than PGA, at room temperature appeared as semicrystalline materials: the main effect of copolymerization was a lowering in the amount of crystallinity and a decrease of the melting temperature with respect to homopolymer PGA. Baur's equation described well the Tm‐composition data. X‐ray diffraction measurements allowed the identification of the PGA crystalline structure in all cases. After melt quenching, semicrystalline samples were obtained with the exception of PGAPHIB7.4 copolymer. The introduction of HIB units decreased the crystallization rate compared with pure PGA. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 1901–1910, 2010 相似文献
98.
Stephanie Kaspar Diana Weier Winfriede Weschke Hans-Peter Mock Andrea Matros 《Analytical and bioanalytical chemistry》2010,398(7-8):2883-2893
Both the nucellar projection (NP) and endosperm transfer cells (ETC) of the developing barley grain (harvested 8 days after flowering) were isolated by laser capture micro-dissection combined with pressure catapulting. Protein extracts were analyzed by nanoUPLC separation combined with ESI-Q-TOF mass spectrometry. The majority of the ~160 proteins identified were involved in translation, protein synthesis, or protein destination. The NP proteome was enriched for stress defense molecules, while proteins involved in assimilate transport and the mobilization of nutrients were common to both the NP and the ETC. The combined qualitative and quantitative protein profiling allowed for the identification of several proteins showing tissue specificity in their expression, which underlines the distinct biological functions of these two tissues within the developing barley grain. 相似文献
99.
Michele Iannone Anna Pia Dima Francesca Sciarra Francesco Botrè Andrea M. Isidori 《Biomedical chromatography : BMC》2022,36(5):e5344
We present a liquid chromatography tandem mass spectrometry method for the simultaneous analysis of 16 endogenous steroids (androgens, estrogens, glucocorticoids and progestogens) in human serum. Samples (250 μl of matrix) were extracted with t-butylmethyl ether prior to LC–MS/MS analysis. The chromatographic separation was achieved on a reversed-phase column using a methanol–water gradient. The HPLC was coupled to a triple quadrupole mass spectrometer equipped with an electrospray ionization source with acquisition in multiple reaction monitoring mode. The method was validated using surrogate matrices and human serum samples. The specificity of the method was confirmed for all of the considered steroids; linearity was also assessed (R2 > 0.99, lack-of-fit test) in the ranges of concentrations investigated. The lower limits of quantification were in the range 10–400 pg/ml depending on the target steroid. Accuracy was in the range 85–115% for all target steroids except for the lower limit of quantitation levels where it was 80–120%. The extraction recovery was always >65%. No significant matrix effects were observed. To test the reliability of the method, the analysis of serum samples collected from 10 healthy subjects (5 M/5F) was performed. The present method can be used to identify the trajectories of deviation from the concentration normality ranges applied to disorders of the gonadal and adrenal axes. 相似文献
100.
负热膨胀(NTE)是一种反常的物理现象, 已在合金和框架结构化合物等材料中被观察到, 但NTE材料的种类仍然有限. 本文合成了一种单轴NTE材料Zn(NCN), 该材料在c轴方向及在100~475 K下的热膨胀系数为-3.35×10?6 K?1, 而a轴和b轴方向则呈低热膨胀性, 体积具有低的热膨胀系数[6.13×10?6 K?1(100~475 K)]. 通过同步辐射X射线衍射、 扩展X射线吸收精细结构和拉曼光谱等方法, 研究了Zn(NCN)的NTE机理. 结果表明, Zn—N键具有明显的横向振动, 一些低频振动模Grüneisen参数为负值. 直接的实验证据表明, N=C=N的横向振动以及准刚性ZnN4四面体的耦合旋转和扭摆导致了c轴方向的NTE. 相似文献