Structural and magnetic characteristics of Co1−xNix/2Srx/2Fe2O4 nanoparticles

Co_1−xNi_x/2Sr_x/2Fe₂O₄ (x=0–0.5 in steps of 0.1) ferrite nanoparticles have been synthesized at room temperature, without calcination, using a reverse micelle process. The site preference was determined by Mössbauer spectroscopy at 300 K. The hyperfine parameters were obtained, for the whole series of solid solutions. For the X≤0.20 samples, the spectra were fitted with two discrete sextets and for the X>0.20 samples, a magnetic hyperfine field distribution and a doublet were also imposed in the fit procedure. Hysteresis loops were measured using a superconducting quantum interference device magnetometer at 2 K and 300 K. The results indicate that the relative decrease in saturation magnetization of nanoparticles compared to the submicron particles could be attributed to a surface spin termination and disorder. Magnetic dynamics of the nanoparticles was studied by the measurement of ac magnetic susceptibility versus temperature at different frequencies and it is found that the results are well described by the Vogel–Fulcher model.     

Quantum interference induced by initial system–environment correlations

We investigate the quantum interference induced by a relative phase in the correlated initial state of a system which consists in a two-level atom interacting with a damped mode of the radiation field. We show that the initial relative phase has significant effects on both the evolution of the atomic excited-state population and the information flow between the atom and the reservoir, as quantified by the trace distance. Furthermore, by considering two two-level atoms interacting with a common damped mode of the radiation field, we highlight how initial relative phases can affect the subsequent entanglement dynamics.     

Simultaneous near field imaging of electric and magnetic field in photonic crystal nanocavities

The insertion of a metal-coated tip on the surface of a photonic crystal microcavity is used for simultaneous near field imaging of electric and magnetic fields in photonic crystal nanocavities, via the radiative emission of embedded semiconductor quantum dots (QD). The photoluminescence intensity map directly gives the electric field distribution, to which the electric dipole of the QD is coupled. The magnetic field generates, via Faraday's law, a circular current in the apex of the metallized probe that can be schematized as a ring. The resulting magnetic perturbation of the photonic modes induces a blue shift, which can be used to map the magnetic field, within a single near-field scan.     

On the Landau-Teller approximation for energy exchanges with fast degrees of freedom

We revisit the Landau-Teller heuristic approach to adiabatic invariants and, following Rapp, use it to investigate the energy exchanges between the different degrees of freedom, in simple Hamiltonian systems describing the collision of fast rotating or vibrating molecules with a fixed wall. We critically compare the theoretical results with particularly accurate numerical computations (quite small energy exchanges, namely of one part over 10³⁰, are measured).     

Engineered pixels using active plasmonic holograms with liquid crystals

Digital holography requires arrays of small reconfigurable elements to achieve complex reconstruction of the hologram with common systems based on pixels utilizing liquid crystal on silicon (LCoS) technology. The backplane of a typical pixel element is potentially underutilized and thus relatively large physical areas exist in which information can be stored and exploited to give additional functionality to pixel elements. Polarisation and wavelength dependent optical properties can be achieved in small areas using the plasmonic effects of optical antennae. The integration of LCs with optical antennae‐based plasmonic holograms allows active modulation of the far field pattern. The work here demonstrates the concept that conventional LCoS pixel elements can be greatly enhanced with the integration of plasmonic holograms, composed of optical antennae patterned on the surface, giving rise to new levels of modulation capability for holographic pixel elements. Using LCs, polarisation dependent effects in plasmonic holograms can be switched. ‘Engineered pixels', with sub‐wavelength multiplexing over both polarisation and wavelength, can increase the channel capacity of a typical LC display device. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim)     

Dirac Operators on Quantum Projective Spaces

We construct a family of self-adjoint operators D _N , ${N\in{\mathbb Z}}We construct a family of self-adjoint operators D _N , N ? \mathbb Z{N\in{\mathbb Z}} , which have compact resolvent and bounded commutators with the coordinate algebra of the quantum projective space \mathbb CP^l_q{{\mathbb C}{\rm P}^{\ell}_q} , for any ℓ ≥ 2 and 0 < q < 1. They provide 0⁺-dimensional equivariant even spectral triples. If ℓ is odd and N=\frac12(l+1){N=\frac{1}{2}(\ell+1)} , the spectral triple is real with KO-dimension 2ℓ mod 8.     

Suspended bridge-like silica 2×2 beam splitter on silicon

We report a successful experimental realization of a 2×2 suspended silica splitter integrated on a silicon substrate. The silica splitter was photo-lithographically patterned, etched, and reflowed to form the suspended and rounded silica waveguide channels. The silica splitter showed a flat splitting ratio and excess loss over a wide wavelength range from 1520 to 1630 nm with a low crosstalk. Additionally, as a result of the very low nonlinear coefficients of silica, the splitting ratio is independent of input power.     

Sextic centrifugal distortion constants: interplay of density functional and basis set for accurate yet feasible computations

Quantum-chemical calculations assist the analysis of laboratory spectra, and often provide the only means to determine spectroscopic data that cannot be accessed experimentally. Accurate predictions of vibrational and rotational spectroscopic parameters are required for applications in the field of high-resolution molecular spectroscopy. While the accuracy issue of the quantum-chemical calculation of vibrational properties and of equilibrium structures has been addressed in the literature, the same is not true for centrifugal distortion constants that however play an essential role for the interpretation of remote sensing data. In this work, the performance of several model chemistries, rooted mainly in density functional theory, in computing sextic centrifugal distortion constants is assessed employing a benchmark set of molecules of both atmospheric and astrochemical relevance. The Jensen’s (aug-)pcs-n basis sets, different flavours of Dunning’s triple-ζ basis sets and the SNSD basis set, are employed in conjunction with different functionals, and their predictions are benchmarked against experimental and theoretical data at the coupled cluster level of theory. This study also demonstrates the reliability of the calculation of sextic centrifugal distortion constants within the Gaussian16 rev. B.01 program package. Reliable predictions of the sextic centrifugal distortion constants for the gauche- and trans-conformers of ethyl-mercaptan are also presented.     

Noise Reduction in Spur Gear Systems

This article lists some tips for reducing gear case noise. With this aim, a static analysis was carried out in order to describe how stresses resulting from meshing gears affect the acoustic emissions. Different parameters were taken into account, such as the friction, material, and lubrication, in order to validate ideas from the literature and to make several comparisons. Furthermore, a coupled Eulerian–Lagrangian (CEL) analysis was performed, which was an innovative way of evaluating the sound pressure level of the aforementioned gears. Different parameters were considered again, such as the friction, lubrication, material, and rotational speed, in order to make different research comparisons. The analytical results agreed with those in the literature, both for the static analysis and CEL analysis—for example, it was shown that changing the material from steel to ductile iron improved the gear noise, while increasing the rotational speed or the friction increased the acoustic emissions. Regarding the CEL analysis, air was considered a perfect gas, but its viscosity or another state equation could have also been taken into account. Therefore, the above allowed us to state that research into these scientific fields will bring about reliable results.     

Metamaterials and plasmonics: From nanoparticles to nanoantenna arrays,metasurfaces, and metamaterials

The rise of plasmonic metamaterials in recent years has unveiled the possibility of revolutionizing the entire field of optics and photonics, challenging well-established technological limitations and paving the way to innovations at an unprecedented level To capitalize the disruptive potential of this rising field of science and technology, it is important to be able to combine the richness of optical phenomena enabled by nanoplasmonics in order to realize metamaterial components, devices, and systems of increasing complexity. Here, we review a few recent research directions in the field of plasmonic metamaterials, which may foster further advancements in this research area. We will discuss the anomalous scattering features enabled by plasmonic nanoparticles and nanoclusters, and show how they may represent the fundamental building blocks of complex nanophotonic architectures. Building on these concepts, advanced components can be designed and operated, such as optical nanoantennas and nanoantenna arrays, which, in turn, may be at the basis of metasurface devices and complex systems. Following this path, from basic phenomena to advanced functionalities, the field of plasmonic metamaterials offers the promise of an important scientific and technological impact, with applications spanning from medical diagnostics to clean energy and information processing.