全文获取类型
收费全文 | 2232篇 |
免费 | 53篇 |
国内免费 | 8篇 |
专业分类
化学 | 1378篇 |
晶体学 | 12篇 |
力学 | 71篇 |
数学 | 273篇 |
物理学 | 559篇 |
出版年
2022年 | 23篇 |
2021年 | 39篇 |
2020年 | 33篇 |
2019年 | 22篇 |
2018年 | 25篇 |
2017年 | 12篇 |
2016年 | 58篇 |
2015年 | 42篇 |
2014年 | 46篇 |
2013年 | 133篇 |
2012年 | 109篇 |
2011年 | 137篇 |
2010年 | 83篇 |
2009年 | 61篇 |
2008年 | 135篇 |
2007年 | 127篇 |
2006年 | 111篇 |
2005年 | 110篇 |
2004年 | 85篇 |
2003年 | 60篇 |
2002年 | 64篇 |
2001年 | 46篇 |
2000年 | 38篇 |
1999年 | 28篇 |
1998年 | 31篇 |
1997年 | 41篇 |
1996年 | 29篇 |
1995年 | 27篇 |
1994年 | 37篇 |
1993年 | 32篇 |
1992年 | 39篇 |
1991年 | 16篇 |
1990年 | 19篇 |
1989年 | 17篇 |
1987年 | 11篇 |
1986年 | 15篇 |
1985年 | 29篇 |
1984年 | 25篇 |
1983年 | 24篇 |
1982年 | 28篇 |
1981年 | 29篇 |
1980年 | 18篇 |
1979年 | 20篇 |
1978年 | 13篇 |
1977年 | 17篇 |
1976年 | 15篇 |
1975年 | 16篇 |
1974年 | 16篇 |
1973年 | 18篇 |
1972年 | 12篇 |
排序方式: 共有2293条查询结果,搜索用时 15 毫秒
11.
L. Cianchi F. Del Giallo F. Pieralli M. Mancini S. Sciortino G. Spina 《Hyperfine Interactions》1991,66(1-4):387-391
Mössbauer parameters of151Eu in Eu1+x Ba2?x Cu3O7+δ have been studied as a function of temperature, forx=0.15 andx=0.25. The areas of the absorption spectra for the two samples are almost equal. This could mean that thef-Mössbauer factor for151Eu at the barium sites is much smaller than that for151Eu at the rare earth sites, i.e. we only observe the spectra of the latter sites. According to this, the fits of the spectra with a single quadrupolar pattern and with two quadrupolar patterns have given equivalent χ2 values. 相似文献
12.
M. A. Macrì C. Del Gratta L. Di Donato S. Di Luzio G. L. Romani S. Della Penna A. Pasquarelli 《Il Nuovo Cimento D》1994,16(5):425-432
Summary A preliminary study is here reported on a new potential marker for biomagnetic measurements. The marker consists of superparamagnetic
polymer microspheres which were detected in the presence of external steady magnetic fields by means of an r.f.-SQUID magnetometer.
The particles were prepared in samples differing in the concentration value and immersed in a homogeneous magnetic field of
variable intensity. A simple model was taken into account for the distribution of the microspheres in the samples, so that
the theoretical values were compared to the marker field values measured by the biomagnetic sensor. The overall sensitivity
of the experimental apparatus and the minimum concentration value of the marker were then estimated. 相似文献
13.
14.
B. Blank J. -J. Gaimard H. Geissel K. -H. Schmidt H. Stelzer K. Sümmerer D. Bazin R. Del Moral J. P. Dufour A. Fleury F. Hubert H. -G. Clerc M. Steiner 《Zeitschrift für Physik A Hadrons and Nuclei》1992,343(4):375-379
Total charge-changing cross sections have been measured for8Li on C and Pb targets, for9Li on C, Al, Cu, Sn and Pb targets, as well as for11Li on C, Sn and Pb targets at about 80 MeV/nucleon. These data are compared to measured total reaction cross sections and Glauber-type calculations using Hartree-Fock density distributions. These comparisons allow to draw conclusions on the proton density distribution of the neutronrich lithium isotopes. The results show that even for the most exotic nucleus11Li the proton distribution is only very weakly influenced by the long tail in the neutron density distribution already established in several experiments. 相似文献
15.
P. N. Burrows V. Del Duca P. Hoyer 《Zeitschrift fur Physik C Particles and Fields》1992,53(1):149-155
In heavy quark jets the quark mass acts as a regulator of collinear singularities, making the quark momentum an infra-red safe variable in perturbative QCD. This allows a direct comparison of measured heavy hadron momentum spectra with perturbative calculations. We exploit the factorisation of heavy quark fragmentation to derive QCD predictions for momentum correlations between heavy hadrons produced ine + e ? annihilations. We study the practical feasibility and model sensitivity of our approach using Monte Carlo simulations. Higher order perturbative corrections and contributions from non-perturbative effects are found to be at the level of 10%. 相似文献
16.
17.
G. Del Piero G. Perego S. Cucinella M. Cesari A. Mazzei 《Journal of organometallic chemistry》1977,136(1):13-18
The crystall and molecular structures of (ClAlN-i-Pr)6 (I), and of (Me0.83H0.17AlN-i-Pr)6(MeAlN-i-Pr)6 have been determined by single crystal three-dimensional X-ray analysis. Block-matrix least-squares refinements led to conventional R factor of 0.039 for I and 0.037 for II. The compounds are isostructural, as the cage molecules consist of a prismatic hexagonal framework, (AlN)6, similar to that observed for the parent hydrogenated analogue (HAlN-i-Pr)6.Some differences in bond distances and angles are discussed, in connection with the different Al-bonded substituents. Crystal data: I, trigonal space group R; a = 17.083(2), c = 9.652(1); Z = 3; Dc 1.46 g cm?3; II, trigonal space group R, a = 17.378(3), c = 9.706(3) »; Z = 3; Dc 1.15 g cm?3. 相似文献
18.
J. L. Gascón M. Rodríguez J. A. Suárez Del Rey 《Journal of Radioanalytical and Nuclear Chemistry》1996,207(1):63-69
The determination of Am and Cm in typical waste streams from nuclear power plants using anion exchange chromatography has some drawbacks like the contamination by Pu and Po. This improved procedure solves these problems, and it has been applied with success to the analysis of Am and Cm in nuclear waste samples: ion exchange resins, ion exchange resins solidified with cement and evaporator concentrates. 相似文献
19.
Gerhard Laus Johannes Schütz Herwig Schottenberger Max Andre Klaus Wurst Mariana Spetea Karl‐Hans Ongania AdrianG. Müller Helmut Schmidhammer 《Helvetica chimica acta》2003,86(10):3274-3280
The two diastereoisomeric ferrocenyl‐substituted orvinols 2 and 3 were prepared. The modified alkaloids are still able to interact with opioid receptors (see Table). The ferrocene moiety allows highly selective and sensitive electrochemical detection. The X‐ray crystal structure of the major isomer 2 was determined. The combination of a metallocene and a morphinan alkaloid holds promise for useful antitumor activity. 相似文献
20.
Michelini Mdel C Russo N Alikhani ME Silvi B 《Journal of computational chemistry》2004,25(13):1647-1655
The Density functional theory has been applied to characterize the structural features of Mo(1,2)-NH(3),-C(2)H(4), and -C(2)H(2) compounds. Coordination modes, geometrical structures, and binding energies have been calculated for several spin multiplets. It has been shown that in contrast to the conserved spin cases (Mo(1,2)-NH(3)), the interaction between Mo (or Mo(2)) and C(2)H(4) (or C(2)H(2)) are the low-spin (Mo-C(2)H(4) and -C(2)H(2)) and high-spin (Mo(2)-C(2)H(4) and -C(2)H(2)) complexes. In the ground state of Mo(1,2)-C(2)H(4) and -C(2)H(2), the metal-center always reacts with the C-C center. The spontaneous formation of the global minima is found to be possible due to the crossing between the potential energy surfaces (ground and excited states with respect to the metallic center). The bonding characterization has been performed using the topological analysis of the Electron Localization Function. It has been shown that the most stable electronic structure for a pi-acceptor ligand correlates with a maximum charge transfer from the metal center to the C-C bond of the unsaturated hydrocarbons, resulting in the formation of two new basins located on the carbon atoms (away from hydrogen atoms) and the reduction of the number of attractors of the C-C basin. The interaction between Mo(1,2) and C(2)H(4) (or C(2)H(2)) should be considered as a chemical reaction, which causes the multiplicity change. Contrarily, there is no charge transfer between Mo(1,2) and NH(3), and the partners are bound by an electrostatic interaction. 相似文献