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901.
Betânia H. Lunelli Rafael R. Andrade Daniel I. P. Atala Maria Regina Wolf Maciel Francisco Maugeri Filho Rubens Maciel Filho 《Applied biochemistry and biotechnology》2010,161(1-8):227-237
Lactic acid is an important product arising from the anaerobic fermentation of sugars. It is used in the pharmaceutical, cosmetic, chemical, and food industries as well as for biodegradable polymer and green solvent production. In this work, several bacterial strains were isolated from industrial ethanol fermentation, and the most efficient strain for lactic acid production was selected. The fermentation was conducted in a batch system under anaerobic conditions for 50 h at a temperature of 34 °C, a pH value of 5.0, and an initial sucrose concentration of 12 g/L using diluted sugarcane molasses. Throughout the process, pulses of molasses were added in order to avoid the cell growth inhibition due to high sugar concentration as well as increased lactic acid concentrations. At the end of the fermentation, about 90% of sucrose was consumed to produce lactic acid and cells. A kinetic model has been developed to simulate the batch lactic acid fermentation results. The data obtained from the fermentation were used for determining the kinetic parameters of the model. The developed model for lactic acid production, growth cell, and sugar consumption simulates the experimental data well. 相似文献
902.
The influence of sulfur versus selenium coordination to molybdenum on the oxo transfer reaction mechanisms of functional models for oxidoreductases has been studied. The solution structure of the dimeric molybdenum compound with tridentate bis-anionic ligands containing a thioether function (−O(CH2)3S(CH2)3O−) has been determined using EXAFS spectroscopy to be able to compare a feature of its solution structure to that of its selenoether analogue. A significant difference is found for the solution structures of the two compounds. The thioether group remains coordinated in solution, whereas the selenoether does not. The influence of this difference on the catalytic oxo transfer has been investigated in detail by following the catalytic transition of PPh3 to OPPh3 with DMSO as oxygen donor with variation of both substrate concentrations. 相似文献
903.
G. Pérez-Caballero J. M. Andrade S. Muniategui D. Prada 《Analytical and bioanalytical chemistry》2009,395(7):2335-2347
The capability of single-reflection near-IR (NIR) spectroscopy to differentiate, characterize and monitor the fate of a set
of hydrocarbons spilled in the marine environment was compared with that of multiple-reflection horizontal attenuated total
reflection mid-IR (ATR-MIR) spectroscopy. Multivariate pattern recognition techniques [principal component analysis (PCA),
multivariate polynomial regression, cluster analysis and potential curves] were applied to unravel the major trends of the
weathering processes of four generic types of crude oils and two heavy fuel oils spilled under controlled conditions for almost
4 months. A chemical interpretation of the NIR spectra related the weathering processes and the PCA loadings, which had not
already been done in the literature. Weathering for both light and heavy products was characterized by a contrast among the
linear aliphatic structures (more volatile and easy to degrade) and the branched and aromatic structures (more recalcitrant).
Potential curves were applied to model each product and determine objectively whether unknown samples could be classified
correctly. Polynomial regression on the PCA scores was employed to evaluate the time elapsed from the oil spillage to its
sampling; this represents a new approach to assess the age of a hydrocarbon lump. In general, NIR spectroscopy yielded good
results when light crude oils were studied, whereas ATR-MIR spectroscopy led to satisfactory results for both light and heavy
products. 相似文献
904.
We study the oil displacement and production behavior in an isothermal thin layered reservoir model subjected to water flooding. We use the CMG’s (Computer Modelling Group ) numerical simulators to solve mass balance equations. The influences of the viscosity ratio (m≡μoil/μwater) and the inter-well (injector-producer) distance r on the oil production rate C(t) and the breakthrough time tbr are investigated. Two types of reservoir configuration are used, namely one with random porosities and another with a percolation cluster structure. We observe that the breakthrough time follows a power-law of m and r, tbr∝rαmβ, with α=1.8 and β=−0.25 for the random porosity type, and α=1.0 and β=−0.2 for the percolation cluster type. Moreover, our results indicate that the oil production rate is a power law of time. In the percolation cluster type of reservoir, we observe that P(t)∝tγ, with γ=−1.81, where P(t) is the time derivative of C(t). The curves related to different values of m and r may be collapsed suggesting a universal behavior for the oil production rate. 相似文献
905.
Sand-moving winds blowing from a constant direction in an area of high sand availability form transverse dunes, which have a fixed profile in the direction orthogonal to the wind. Here we show, by means of a linear stability analysis, that transverse dunes are intrinsically unstable. Any perturbation in the cross-wind profile of a transverse dune amplifies in the course of dune migration due to the combined effect of two main factors, namely: the lateral transport through avalanches along the dune’s slip-face, and the scaling of dune migration velocity with the inverse of the dune height. Our calculations provide a quantitative explanation for recent observations from experiments and numerical simulations, which showed that transverse dunes moving on the bedrock (or “transverse sand ridges”) cannot exist in a stable form and decay into a chain of crescent-shaped barchans. 相似文献
906.
907.
Celeste de Jesus Pereira Franco Oberdan Oliveira Ferreira Jorddy Neves Cruz Everton Luiz Pompeu Varela ngelo Antnio Barbosa de Moraes Lidiane Diniz do Nascimento Mrcia Moraes Cascaes Antnio Pedro da Silva Souza Filho Rafael Rodrigues Lima Sandro Percrio Mozaniel Santana de Oliveira Eloisa Helena de Aguiar Andrade 《Molecules (Basel, Switzerland)》2022,27(15)
The essential oil (EO) of Calycolpus goetheanus (Myrtaceae) specimens (A, B, and C) were obtained through hydrodistillation. The analysis of the chemical composition of the EOs was by gas chromatography coupled with mass spectrometry CG-MS, and gas chromatography coupled with a flame ionization detector CG-FID. The phytotoxic activity of those EOs was evaluated against two weed species from common pasture areas in the Amazon region: Mimosa pudica L. and Senna obtusifolia (L.) The antioxidant capacity of the EOs was determined by (DPPH•) and (ABTS•+). Using molecular docking, we evaluated the interaction mode of the major EO compounds with the molecular binding protein 4-hydroxyphenylpyruvate dioxygenase (HPPD). The EO of specimen A was characterized by β-eudesmol (22.83%), (E)-caryophyllene (14.61%), and γ-eudesmol (13.87%), while compounds 1,8-cineole (8.64%), (E)-caryophyllene (5.86%), δ-cadinene (5.78%), and palustrol (4.97%) characterize the chemical profile of specimen B’s EOs, and specimen C had α-cadinol (9.03%), δ-cadinene (8.01%), and (E)-caryophyllene (6.74%) as the majority. The phytotoxic potential of the EOs was observed in the receptor species M. pudica with percentages of inhibition of 30%, and 33.33% for specimens B and C, respectively. The EOs’ antioxidant in DPPH• was 0.79 ± 0.08 and 0.83 ± 0.02 mM for specimens A and B, respectively. In the TEAC, was 0.07 ± 0.02 mM for specimen A and 0.12 ± 0.06 mM for specimen B. In the results of the in silico study, we observed that the van der Waals and hydrophobic interactions of the alkyl and pi-alkyl types were the main interactions responsible for the formation of the receptor–ligand complex. 相似文献
908.