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81.
Staby A Sand MB Hansen RG Jacobsen JH Andersen LA Gerstenberg M Bruus UK Jensen IH 《Journal of chromatography. A》2004,1034(1-2):85-97
A comparative study was performed on strong cation-exchangers to investigate the pH dependence, efficiency, binding strength, particle size distribution, static and dynamic capacity, and SEM pictures of chromatographic resins. The resins tested included: SP Sepharose XL, Poros 50 HS, Toyopearl SP 550c, SP Sepharose BB, Source 30S, TSKGel SP-5PW-HR20, and Toyopearl SP 650c. Testing was performed with four different proteins: anti-FVII Mab (IgG), aprotinin, lysozyme, and myoglobin. Dependence of pH on retention was generally very low for proteins with high pI. An unexpected binding at pH 7.5 of anti-FVII Mab with pI < 7.5 was observed on several resins. Efficiency results show the expected trend of higher dependence of the plate height with increasing flow rate of soft resins compared to resins for medium and high-pressure operation. Determination of particle size distribution by two independent methods, Coulter counting and SEM, was in very good agreement. The mono-dispersed nature of Source 30S was confirmed. Binding to cation-exchange resins as a function of ionic strength varies depending on the specific protein. Generally, binding and elution at high salt concentration may be performed with Toyopearl SP 550c and Poros 50 HS, while binding and elution at low salt concentration may be performed with Toyopearl SP 650c. A very high binding capacity was obtained with SP Sepharose XL. Comparison of static capacity and dynamic capacity at 10% break-through shows in general approximately 50-80% utilisation of the total available capacity during chromatographic operation. A general good agreement was obtained between this study and data obtained by others. The results of this study may be used for selection of resins for testing in process development. The validity of experiments and results with model proteins were tested using human insulin precursor in pure state and in real feed-stock on Toyopearl SP 550c, SP Sepharose BB, and Toyopearl SP 650c. Results showed good agreement with experiments with model proteins. 相似文献
82.
83.
T.V. Andersen J. Thogersen S.R. Keiding J.J. Larsen 《Applied physics. B, Lasers and optics》2003,76(6):639-644
We demonstrate intracavity frequency doubling of a standard femtosecond Ti:sapphire oscillator. The cavity is extended with
a pair of focusing mirrors and a 0.5-mm-thick BBO crystal. We achieve a repetition rate of 50 MHz and simultaneously generate
22 mW of 55-fs pulses at 810 nm and 200 mW of 73-fs pulses at 405 nm, which corresponds to 4 nJ per pulse. We create a total
of 330-mW, 405-nm light when pumping the Ti:sapphire crystal with 5.7 W from an Ar-ion laser, corresponding to a conversion
efficiency of 5.7%. No saturation is found, which implies that higher outputs can be achieved with higher pump rates. Preliminary
results from the use of blue pulses as pump in an optical parametric amplifier seeded by pulses from a photonic crystal fiber
are presented.
Received: 27 January 2003 / Revised version: 27 March 2003 / Published online: 12 May 2003
RID="*"
ID="*"Corresponding author. Fax: +45-861/96199, E-mail: tva@chem.au.dk 相似文献
84.
The reaction of aryl alkynes with dilute methylene chloride solutions of quaternary ammonium bromide and 20% trifluoroacetic acid produces primarily the syn Markovnikov adducts of hydrogen bromide. At moderate concentrations of the bromide, the principal product is the Markovnikov anti adduct. At high concentrations of bromide, the anti-Markovnikov anti addition product predominates. 相似文献
85.
Pretreatment of polystyrene beads with a nonpolar organic solvent is the key for the generation of mechanically robust tablets consisting of neat functionalized polystyrene beads, both alone and in combination with solid reagents or catalysts. The novel dosing methodology provides accurately preweighed tablets in virtually any shape and size and with excellent disintegration properties, speeding up parallel solution and solid phase synthesis. The use of tablets is demonstrated in parallel Mitsunobu and acylation reactions. 相似文献
86.
87.
88.
The $-game 总被引:1,自引:0,他引:1
J. Vitting Andersen D. Sornette 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,31(1):141-145
We propose a payoff function extending Minority Games (MG) that captures the competition between agents to make money. In
contrast with previous MG, the best strategies are not always targeting the minority but are shifting opportunistically between
the minority and the majority. The emergent properties of the price dynamics and of the wealth of agents are strikingly different
from those found in MG. As the memory of agents is increased, we find a phase transition between a self-sustained speculative
phase in which a “stubborn majority” of agents effectively collaborate to arbitrage a market-maker for their mutual benefit
and a phase where the market-maker always arbitrages the agents. A subset of agents exhibit a sustained non-equilibrium risk-return
profile.
Received 5 June 2002 / Received in final form 21 November 2002 Published online 27 January 2003
RID="a"
ID="a"e-mail: sornette@unice.fr
RID="b"
ID="b"CNRS UMR7536
RID="c"
ID="c"CNRS UMR6622 相似文献
89.
Nils Byrial Andersen Gestur Ó lafsson 《Proceedings of the American Mathematical Society》2001,129(1):173-179
We formulate and prove a topological Paley-Wiener theorem for the normalized spherical Laplace transform defined on the rank 1 causal symmetric spaces , for .
90.
Hansen K Andersen JU Hvelplund P Møller SP Pedersen UV Petrunin VV 《Physical review letters》2001,87(12):123401
The exponential law is valid both for decay from a single quantum state into a continuum and for an ensemble maintained in thermal equilibrium. For statistical decay of an ensemble of isolated systems with a broad energy distribution, the exponential decay is replaced by a 1/t distribution. We present confirmation of this decay law by experiments with cluster anions in a small electrostatic storage ring. Deviations from the 1/t law for such an ensemble give important information on the dynamics of the systems. As examples, we present measurements revealing strong radiative cooling of anions of both metal clusters and fullerenes. 相似文献