全文获取类型
收费全文 | 378篇 |
免费 | 10篇 |
国内免费 | 1篇 |
专业分类
化学 | 276篇 |
晶体学 | 7篇 |
力学 | 6篇 |
数学 | 46篇 |
物理学 | 54篇 |
出版年
2024年 | 1篇 |
2023年 | 4篇 |
2022年 | 16篇 |
2021年 | 11篇 |
2020年 | 13篇 |
2019年 | 11篇 |
2018年 | 12篇 |
2017年 | 14篇 |
2016年 | 16篇 |
2015年 | 15篇 |
2014年 | 14篇 |
2013年 | 25篇 |
2012年 | 18篇 |
2011年 | 30篇 |
2010年 | 17篇 |
2009年 | 11篇 |
2008年 | 18篇 |
2007年 | 21篇 |
2006年 | 27篇 |
2005年 | 14篇 |
2004年 | 14篇 |
2003年 | 8篇 |
2002年 | 12篇 |
2001年 | 9篇 |
2000年 | 6篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 6篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1986年 | 1篇 |
1985年 | 2篇 |
排序方式: 共有389条查询结果,搜索用时 15 毫秒
1.
P. V. Bharatam Amita D. Kaur P. Senthil Kumar 《International journal of quantum chemistry》2006,106(5):1237-1249
The potential energy surface (PES) of thionylimide has been searched using ab initio MO and density functional calculations. The electronic structures of the isomers of HNSO have been studied using the HF/6‐31+G*, MP2(full)/6‐31+G*, and B3LYP/6‐31+G* levels. Final energies of these molecules have been calculated at the high‐accuracy G2 and CBS‐Q levels. The probable pathways of isomerization of thionylimide to its isomers (e.g., thiocyanic acid, HONS, nitrosothiols) have been explored by studying the three‐ or four‐membered transition states. This study identified total eight possible isomers ( 1–8 ) of HNSO, of which four ( 1–4 ) have already been realized experimentally. Of the remaining four ( 5–8 ), at least two ( 5, 7 ) can be generated experimentally. © 2005 Wiley Periodicals, Inc. Int J Quantum Chem, 2006 相似文献
2.
Thangavelu Saravanan Rajendran Selvakumar Mukesh Doble Anju Chadha 《Tetrahedron: Asymmetry》2012,23(18-19):1360-1368
The stereochemical preference of the biocatalyst, Candida parapsilosis ATCC 7330, was investigated with respect to the E/Z configuration in the deracemization and the asymmetric reduction of aryl secondary alcohols and prochiral ketones, respectively. The biocatalyst preferred the E-isomers over Z-isomers as substrates as evidenced from the experimental results of >99% ee and up to 86% isolated yield for E-secondary alcohols. The synthesis of enantiomerically pure E-4-phenylbut-3-ene-1,2-diol (ee >99%, isolated yield 86%) by whole cell mediated deracemization is reported here for the first time. The geometric preference of the enzymes was confirmed by using the cell free extract of this biocatalyst. Mechanistic insights using in silico studies showed that the E-isomers when located in the active site are favourably placed with respect to the catalytic triad (Ser-Tyr-Lys) for hydride transfer from NADPH. 相似文献
3.
Gurusamy Arumugam Jagmohan Tyagi 《Mathematical Methods in the Applied Sciences》2020,43(10):6576-6597
We establish the existence of nonnegative weak solutions to nonlinear reaction–diffusion system with cross-diffusion and nonstandard growth conditions subject to the homogeneous Neumann boundary conditions. We assume that the diffusion operators satisfy certain monotonicity condition and nonstandard growth conditions and prove that the existence of weak solutions using Galerkin's approximation technique. 相似文献
4.
Perumal Vivekanandhan Ayyakkannu Usha-Raja-Nanthini Gurusamy Valli 《Natural product research》2020,34(18):2626-2629
AbstractIn this study Eucalyptus globulus essential oil was tested on major mosquito species and toxicity was compared with temephos. Mortality was calculated after 24?h and 48?h post treatment. In 24?h treatment essential oil show strong larvicidal activity with LC50 and LC90 values were 30.198ppm, 103.389ppm for Anopheles stephensi, 13.578ppm, 106.755ppm for Aedes aegypti; and, 7.469ppm, 32.454ppm for Culex quinquefasciatus and 48?h post treatment LC50 and LC90 values were, 12.576, 49.380ppm for Anopheles stephensi, 7.926, 34.470ppm for Aedes aegypti and 4.408, 21.048ppm for Culex quinquefasciatus. Chemical composition of essential oil using GC-MS and FT-IR analysis shows the presence of 1,8-cineol, (71.7%); α-pinene, (9.14%) as a major compounds. Our findings suggest that essential oil from Eucalyptus globulus leaves can be used for control of mosquito larvae. 相似文献
5.
The nonlinear optical properties of a magneto-exciton in a strained Ga0.2In0.sAs/GaAs quantum dot 下载免费PDF全文
The magnetic field-dependent heavy hole excitonic states in a strained Gao.2Ino.sAs/GaAs quantum dot are investi- gated by taking into account the anisotropy, non-parabolicity of the conduction band, and the geometrical confinement. The strained quantum dot is considered as a parabolic dot of InAs embedded in a GaAs barrier material. The dependence of the effective excitonic g-factor as a function of dot radius and the magnetic field strength is numerically measured. The interband optical transition energy as a function of geometrical confinement is computed in the presence of a mag- netic field. The magnetic field-dependent oscillator strength of interband transition under the geometrical confinement is studied. The exchange enhancements as a function of dot radius are observed for various magnetic field strengths in a strained Gao.2Ino.sAs/GaAs quantum dot. Heavy hole excitonic absorption spectra, the changes in refractive index, and the third-order susceptibility of third-order harmonic generation are investigated in the Gao.2Ino.8As/GaAs quantum dot. The result shows that the effect of magnetic field strength is more strongly dependent on the nonlinear optical property in a low-dimensional semiconductor system. 相似文献
6.
Krishnan Thiyagarajan Thangavelu Kesavamurthy Gattu Bharathkumar 《Applied magnetic resonance》2014,45(3):255-268
Magnetic resonance imaging (MRI) technique is widely used to capture the images of the liquid items inside the human body. The radio-frequency (RF) coil is one of the important modules present inside an MRI system, which plays a major role in image quality. In this work, a microstrip-based high-pass RF birdcage coil is proposed for 1.5 T MRI. The cylindrical-shaped birdcage coil consists of 12 microstrip radiating elements and tuning capacitors to achieve a resonance at 63.85 MHz. The coil is made up of 10 mm polytetrafluoroethylene substrate coated by a conducting transmission line of desired length and width. A finite difference time domain simulation is carried out to analyze the return loss (S11), magnetic field homogeneity and Specific Absorption Rate (SAR) parameters of the RF coil. The SAR values of the proposed microstrip-based 1.5 T birdcage coil was compared with 3 T RF birdcage coil. The simulation results indicate the proposed birdcage coil structure gives optimal values of S11, magnetic field homogeneity and SAR. 相似文献
7.
In spatial dimensions d>or=2, Kondo lattice models of conduction and local moment electrons can exhibit a fractionalized, nonmagnetic state (FL(*)) with a Fermi surface of sharp electronlike quasiparticles, enclosing a volume quantized by (rho(a)-1)(mod 2), with rho(a) the mean number of all electrons per unit cell of the ground state. Such states have fractionalized excitations linked to the deconfined phase of a gauge theory. Confinement leads to a conventional Fermi liquid state, with a Fermi volume quantized by rho(a)(mod 2), and an intermediate superconducting state for the Z2 gauge case. The FL(*) state permits a second order metamagnetic transition in an applied magnetic field. 相似文献
8.
Optically transparent semiorganic nonlinear optical bulk single crystal of l-ornithine monohydrochloride (LOMHCL) of dimension 11×3×2 mm3 has been grown from its aqueous solution by slow solvent evaporation technique. The grown crystal was characterized by powder X-ray diffraction to confirm the crystal structure. Investigation has been carried out to assign the vibrational frequencies of the grown crystals by Fourier transform infrared spectroscopy technique. Thermal behavior of the grown crystals was studied by thermogravimetric analysis. The second harmonic generation (SHG) efficiency of LOMHCL was determined by Kurtz and Perry powder technique. The optical absorption study confirms the suitability of the crystal for device applications. The mechanical properties of the grown crystals have been studied using Vickers microhardness tester. Dielectric and photoconductivity studies are also carried out for the grown samples. 相似文献
9.
Krishnan R. Anandha Pounraj P. Govindaraj R. Pandian Muthu Senthil Ramasamy P. 《Research on Chemical Intermediates》2022,48(5):1877-1906
Research on Chemical Intermediates - Triphenylamine and methoxy substituted triphenylamine-based dyes are examined by density-functional theory and time-dependent density-functional theory. The... 相似文献
10.
Nanocatalyst-based assay using DNA-conjugated Au nanoparticles for electrochemical DNA detection 总被引:1,自引:0,他引:1
Selvaraju T Das J Jo K Kwon K Huh CH Kim TK Yang H 《Langmuir : the ACS journal of surfaces and colloids》2008,24(17):9883-9888
Compared to enzymes, Au nanocatalysts show better long-term stability and are more easily prepared. Au nanoparticles (AuNPs) are used as catalytic labels to achieve ultrasensitive DNA detection via fast catalytic reactions. In addition, magnetic beads (MBs) are employed to permit low nonspecific binding of DNA-conjugated AuNPs and to minimize the electrocatalytic current of AuNPs as well as to take advantage of easy magnetic separation. In a sandwich-type electrochemical sensor, capture-probe-conjugated MBs and an indium-tin oxide electrode modified with a partially ferrocene-modified dendrimer act as the target-binding surface and the signal-generating surface, respectively. A thiolated detection-probe-conjugated AuNP exhibits a high level of unblocked active sites and permits the easy access of p-nitrophenol and NaBH 4 to these sites. Electroactive p-aminophenol is generated at these sites and is then electrooxidized to p-quinoneimine at the electrode. The p-aminophenol redox cycling by NaBH 4 offers large signal amplification. The nonspecific binding of detection-probe-conjugated AuNPs is lowered by washing DNA-linked MB-AuNP assemblies with a formamide-containing solution, and the electrocatalytic oxidation of NaBH 4 by AuNPs is minimized because long-range electron transfer between the electrode and the AuNPs bound to MBs is not feasible. The high signal amplification and low background current enable the detection of 1 fM target DNA. 相似文献