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81.
Formation of cyclic Amidiniumiodides and -polyiodides from 1,3,5-Trimethyl-hexahydro-1,3,5-triazine and Iodine The reaction of 1,3,5-trimethyl-hexahydro-1,3,5-triazine (CH3NCH2)3 with iodine in the molar ratio (CH3NCH2)3:I2 = 2:1 gives the new compound 1,3,5-trimethyl-tetrahydro-1,3,5-triazinium-iodide C6H14N3I. This iodide adds one mole I2 and forms 1,3,5-trimethyl-tetrahydro-1,3,5-triazinium-triiodide C6H14N3I3. The crystal structure analysis shows a cation, in which two methyl groups and five ring atoms are planar arranged. The third methyl group stands axial to the ring. 1,3,5-Trimethyl-tetrahydro-1,3,5-triazinium-pentaiodide is formed by adding a further mole I2. 相似文献
82.
83.
The process of drying a paint made of a dispersion of a polymer in a solvent is experimentally and theoretically studied at various constant temperatures. The diffusion of the solvent through the paint and evaporation from the surface is considered, as well as the subsequent shrinkage. From measurements made at the beginning and at the end of the drying operation on the kinetics of drying, the diffusivity is found to largely depend on the solvent concentration. An exponential relationship of the diffusivity versus the concentration is thus found and successfully tested for the whole process of drying, the diffusivity increasing with the solvent concentration. 相似文献
84.
D. B. Ion 《Nuclear Physics A》1981,360(2):400-410
Experimental data on the pion-nucleus total cross sections are analysed in terms of the dual diffractive resonance (DDR) mechanism. The DDR predictions are found to agree well with the actual experimental data in the region corresponding to the Δ(1236) resonance in elementary πN scattering. 相似文献
85.
86.
Barbero G Freire FC Scalerandi M Alexe-Ionescu AL 《The journal of physical chemistry. B》2006,110(36):17889-17897
We analyze the influence of the adsorption of ions at the interfaces on the transient phenomena occurring in an electrolytic cell submitted to a steplike external voltage. In the limit of small amplitude of the applied voltage, where the equation of the problem can be linearized, we obtain an analytical solution for the bulk and surface densities of ions and for the electrical potential. We also obtain, in this limit, the relaxation time for the transient phenomena. 相似文献
87.
Anca Daniela M?cinic 《Journal of Pure and Applied Algebra》2010,214(10):1818-1826
We analyze k-stage formality and relate resonance with this type of formality properties. For instance, we show that, for a finitely generated nilpotent group that is k-stage formal, the resonance varieties are trivial up to degree k. We also show that the cohomology ring, truncated up to degree k+1, of a finitely generated nilpotent, k-stage formal group is generated in degree 1; this criterion is necessary and sufficient for a finitely generated, 2-step nilpotent group to be k-stage formal. We compute resonance varieties for Heisenberg-type groups and deduce the degree of partial formality for this class of groups. 相似文献
88.
Summary : Phosphorus-nitrogen intumescent product (R2000) was filled into polypropylene (PP) as a flame retardant. The neat PP and flame-retarded PP blends were studied for their structural and mechanical properties after verification of the flame retardancy character of blends. In this paper, the influence of incorporation of different amount (5%, 10%, 15%, 20%, and 25%) of R2000 was studied. The flame retardancy is evaluated by limiting oxygen index (LOI) value, which is enhanced from 17.5 for pure PP to 22.7 for the blend comprising 15% intumescent product, phosphorus-nitrogen based (R2000). The thermal degradation behaviour of the PP/R2000 blends was investigated using thermogravimetric analysis (TGA) under nitrogen (N2) and oxygen (O2) atmospheres. The influence of the R2000 on the PP crystallization was examined by X-ray diffraction (XRD) and differential scanning calorimetry (DSC). Further, the mechanical properties of the materials were studied by dynamic mechanical analysis (DMA). The incorporation of the flame retardant had no effect on the crystallization of the neat polymer and the mechanical properties of the materials remained unaffected. 相似文献
89.
The first examples of furan substituted with an SF5 group are reported. 3-pentafluorosulfanylfurans were prepared from their respective 2-pentafluorosulfanyl-5-cyano-7-oxabicyclo[2.2.1]hept-2-ene precursors via retro-Diels-Alder reactions. Also, a tandem cycloaddition/retrocycloaddition reaction between 4-phenyloxazole and 1-pentafluorosulfanylhex-1-yne was used to prepare 3-pentafluorosulfanyl-4-butylfuran. [reaction: see text]. 相似文献
90.
Angelina T. Georgieva Vijay Pappu Vijay Krishna Pando G. Georgiev Ion Ghiviriga Paul Indeglia Xin Xu Z. Hugh Fan Ben Koopman Panos M. Pardalos Brij Moudgil 《Journal of nanoparticle research》2013,15(7):1-18
Characterization of C60 polyhydroxyfullerenes (PHF) prepared in alkaline media, preparation facilitated by phase-transfer catalyst, presents challenges in determining the chemical structure resulting from the possibility of multiple isomers or analogs with greater or fewer hydroxyl groups from a single reaction mixture. This paper presents the utilization of analytical methods employed in tandem, especially X-ray photoelectron spectroscopy, nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy for semi-quantitative analysis on the number of hydroxyl groups present in PHF. Capillary Electrophoresis was used for purity estimation of the material. Multiple spectra and electropherograms were analyzed using a new simultaneous curve fitting method. The most accurate estimate of hydroxyl groups for C60 polyhydroxy fullerenes obtained is between 16 and 18 allylic hydroxyl groups by combining analytical methods’ results with 5 % accuracy. High precision (reproducibility) of the experiments is observed. Purity of 98 % is estimated by capillary electrophoresis. The size of PHF nanoparticles or aggregates has been determined by atomic force microscopy to be 7.4–14.2 nm. According to the elemental analysis the average probable empirical formula for the most pure PHF at pH 7.1 is C60O17H12Na5(NaHCO3)3(H2O)13 and the average formula weight is 1,605.9 g/mol. This is the first thorough characterization of PHF in terms of purity. 相似文献