Die Sicherheit der Ergebnisse im Falle von linearen physikalisch-chemischen Titrationskurven. Das Vertrauensintervall des ?quivalenzpunktes

Ohne Zusammenfassung

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The reliability of results in case of linear physio-chemical titration curves. The interval of confidence of the equivalence point

     

Berechnung des Gehaltes an Einzelkomponenten und deren Vertrauensintervalle im Falle der indirekten Analyse

Ohne Zusammenfassung

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Calculation of the content of individual components and their confidence intervals in indirect analysis

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Diese Arbeit kann im Zusammenhang mit unseren vorangehenden Beiträgen [1–3] über das Vertrauensintervall von Analysenergebnissen gesehen werden     

Role of the adsorption phenomenon on the ionic equilibrium distribution and on the transient effects in electrolytic cells

We analyze the influence of the adsorption of ions at the interfaces on the transient phenomena occurring in an electrolytic cell submitted to a steplike external voltage. In the limit of small amplitude of the applied voltage, where the equation of the problem can be linearized, we obtain an analytical solution for the bulk and surface densities of ions and for the electrical potential. We also obtain, in this limit, the relaxation time for the transient phenomena.     

A Fractional Schrödinger Equation and Its Solution

This paper presents a fractional Schrödinger equation and its solution. The fractional Schrödinger equation may be obtained using a fractional variational principle and a fractional Klein-Gordon equation; both methods are considered here. We extend the variational formulations for fractional discrete systems to fractional field systems defined in terms of Caputo derivatives to obtain the fractional Euler-Lagrange equations of motion. We present the Lagrangian for the fractional Schrödinger equation of order α. We also use a fractional Klein-Gordon equation to obtain the fractional Schrödinger equation which is the same as that obtained using the fractional variational principle. As an example, we consider the eigensolutions of a particle in an infinite potential well. The solutions are obtained in terms of the sines of the Mittag-Leffler function.     

Stability analysis for a nonlinear coupled system of fractional hybrid delay differential equations

The main objective of this research work is to establish existence results as well as to study qualitative aspects of the proposed coupled system of fractional hybrid delay differential equations (FHDDEs). Using the hybrid fixed point theory, we establish appropriate results for the existence of at least one solution to our problem. The powerful tools of functional analysis and dynamical systems are applied to derive different kinds of stability analysis. These include Ulam-Hyers (UH), generalized Ulam-Hyers (GUH), Ulam-Hyers-Rassias (UHR), and generalized Ulam-Hyers-Rassias (GUHR). In order to provide the authenticity of the our results, an illustrative example is given to wind up the present research work.     

On a backward problem for fractional diffusion equation with Riemann-Liouville derivative

In the present paper, we study the initial inverse problem (backward problem) for a two-dimensional fractional differential equation with Riemann-Liouville derivative. Our model is considered in the random noise of the given data. We show that our problem is not well-posed in the sense of Hadamard. A truncated method is used to construct an approximate function for the solution (called the regularized solution). Furthermore, the error estimate of the regularized solution in L² and H^τ norms is considered and illustrated by numerical example.     

Inverse problems for quasi-variational inequalities

In this short note, our aim is to investigate the inverse problem of parameter identification in quasi-variational inequalities. We develop an abstract nonsmooth regularization approach that subsumes the total variation regularization and permits the identification of discontinuous parameters. We study the inverse problem in an optimization setting using the output-least squares formulation. We prove the existence of a global minimizer and give convergence results for the considered optimization problem. We also discretize the identification problem for quasi-variational inequalities and provide the convergence analysis for the discrete problem. We give an application to the gradient obstacle problem.     

Cohomology rings and formality properties of nilpotent groups

We analyze k-stage formality and relate resonance with this type of formality properties. For instance, we show that, for a finitely generated nilpotent group that is k-stage formal, the resonance varieties are trivial up to degree k. We also show that the cohomology ring, truncated up to degree k+1, of a finitely generated nilpotent, k-stage formal group is generated in degree 1; this criterion is necessary and sufficient for a finitely generated, 2-step nilpotent group to be k-stage formal. We compute resonance varieties for Heisenberg-type groups and deduce the degree of partial formality for this class of groups.     

Koszul incidence algebras, affine semigroups, and Stanley-Reisner ideals

We prove a theorem unifying three results from combinatorial homological and commutative algebra, characterizing the Koszul property for incidence algebras of posets and affine semigroup rings, and characterizing linear resolutions of squarefree monomial ideals. The characterization in the graded setting is via the Cohen-Macaulay property of certain posets or simplicial complexes, and in the more general nongraded setting, via the sequential Cohen-Macaulay property.     

Multiple and sign‐changing solutions for the multivalued p ‐Laplacian equation

We consider a class of elliptic inclusions under Dirichlet boundary conditions involving multifunctions of Clarke's generalized gradient. Under conditions given in terms of the first eigenvalue as well as the Fu?ik spectrum of the p ‐Laplacian we prove the existence of a positive, a negative and a sign‐changing solution. Our approach is based on variational methods for nonsmooth functionals (nonsmooth critical point theory, second deformation lemma), and comparison principles for multivalued elliptic problems. In particular, the existence of extremal constant‐sign solutions plays a key role in the proof of sign‐changing solutions (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)