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91.
Thin film of CaCu3Ti4O12 (CCTO) has been deposited on Nb-doped SrTiO3(100) single crystal using pulsed laser deposition. The dielectric constant and AC conductivity of CCTO film in the metal–insulator–metal
capacitor configuration over a wide temperature (80 to 500 K) and frequency (100 Hz to 1 MHz) range have been measured. The
small dielectric dispersion with frequency observed in the lower temperature region (<300 K) indicates the presence of small
defects in the deposited CCTO thin film. The frequency-dependent AC conductivity at lower temperature indicates the hopping
conduction. The dielectric dispersion data has been analyzed in the light of both conductivity relaxation and Debye type relaxation
with a distribution of relaxation times. Origin of dielectric dispersion is attributed to the distribution of barrier heights
such that some charge carriers are confined between long-range potential wells associated with defects and give rise to dipolar
polarization, while those carriers which do not encounter long-range potential well give rise to DC conductivity. 相似文献
92.
Gowri S. Sherlekar C.M. Srivastava G. Chandra 《Journal of magnetism and magnetic materials》1989,80(2-3):271-275
The temperature of the resistivity maximum, Tm, in the ternary spin glass system Au-Cu-Mn has been analysed in terms of Larsen's theory in order to highlight the contribution from the Kondo effect and the RKKY interaction energy to the resistivity maximum in spin glasses. The competition between these two contributions has been effectively illustrated and a good agreement with theory is obtained for samples with varying magnetic and nonmagnetic atom concentration. A comparison of the dependence of Tm and the RKKY interaction energy on the lattice pressure generated due to addition of Au with reported pressure studies on
Mn alloys shows that there is a close relation between the lattice pressure and the externally applied pressure. 相似文献
93.
C M Srivastava 《Pramana》1989,32(3):251-267
A theory of high temperature superconductivity in YBa2Cu3O7_δ compound has been developed on the basis of the momentum pairing of electrons through the relativistic Darwin interaction.
The transport behaviour of electrons is explained in terms of a mechanism of correlated electron transfer arising from the
electron-phonon coupling. A model Hamiltonian has been developed to describe the superconducting properties of the system.
This gives an energy gap which is higher than the BCS value. Attempts have been made to explain the absence of isotope effect,
the linear dependence of specific heat, the presence of larger temperature-independent paramagnetism in the normal phase and
the softening of some of the optic phonon modes observed in this system. 相似文献
94.
M.K. Kretov I.M. Iskandarova B.V. Potapkin A.V. Scherbinin A.M. Srivastava N.F. Stepanov 《Journal of luminescence》2012,132(8):2143-2150
A sequential, fully first-principle theoretical study of the Mn2+ green emission bands in the Zn2SiO4:Mn2+ phosphor is presented for the first time. A combined approach is developed based on the modern periodic density-functional theory and cluster ab initio wave-function-based electronic structure methods, the linear response theory for lattice phonons, and generating function formalism of vibronic spectra within the displaced multi-mode harmonic oscillator model. We obtain fairly good agreement between the calculated low- and high-temperature emission band positions, widths, zero-phonon lines and phonon wings and the available experimental emission studies, with special emphasis on Mn2+ distribution over two non-equivalent Zn2+ sites in the Zn2SiO4 material. An interpretation for vibronic structure observed in the low-temperature emission spectrum of this phosphor is suggested based on the present first-principle study. 相似文献
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White organic light emitting diodes based on DCM dye sandwiched in 2-methyl-8-hydroxyquinolinolatolithium 总被引:1,自引:0,他引:1
Amit Kumar Ritu Srivastava Sukhwant S. Bawa Kapoor Singh Ishwar Singh 《Journal of luminescence》2010,130(8):1516-1520
Stable white electroluminescence (EL) has been achieved from organic LED, in which an ultrathin 4-(dicyanomethylene)-2-methyl-6-(p-dimethyl-aminostyryl)-4H-pyran (DCM) dye layer has been inserted in between two 2-methyl-8-hydroxyquinolinolatolithium [LiMeq] emitter layer and by optimizing the position of the DCM dye layer from the α-NPD/LiMeq interface. Electroluminescence spectra, current-voltage-luminescence (I-V-L) characteristics of the devices have been studied by changing the position of the dye layer. As the distance of DCM layer from α-NPD/LiMeq interface is increased, the intensity of host emission enhances rapidly. Introduction of thin layer of DCM in emissive layer increases the turn on voltage. The best Commission International de L’ Eclairage (CIE) coordinates i.e. (0.32, 0.33) were obtained with device structure ITO/α-NPD(30 nm) /LiMeq(10 nm)/DCM(1 nm)/LiMeq(25 nm)/BCP(6 nm)/Alq3(28 nm)/LiF(1 nm)/Al(100 nm). The EL spectrum covers the whole visible spectra range 400-700 nm. The color rendering index (CRI) for our best white light (Device 4) is 47.4. The device shows very good color stability in terms of CIE coordinates with voltages. The maximum luminescence 1240 cd/m−2 has been achieved at 19 V. 相似文献