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41.
Borrowing hydrogen from alcohols, storing it on a catalyst and subsequent transfer of the hydrogen from the catalyst to an in situ generated imine is the hallmark of a transition metal mediated catalytic N-alkylation of amines. However, such a borrowing hydrogen mechanism with a transition metal free catalytic system which stores hydrogen molecules in the catalyst backbone is yet to be established. Herein, we demonstrate that a phenalenyl ligand can imitate the role of transition metals in storing and transferring hydrogen molecules leading to borrowing hydrogen mediated alkylation of anilines by alcohols including a wide range of substrate scope. A close inspection of the mechanistic pathway by characterizing several intermediates through various spectroscopic techniques, deuterium labelling experiments, and DFT study concluded that the phenalenyl radical based backbone sequentially adds H+, H˙ and an electron through a dearomatization process which are subsequently used as reducing equivalents to the C–N double bond in a catalytic fashion.An efficient method is developed for harvesting hydrogen, its storage and catalytic transfer by an odd alternant hydrocarbon. The strategy is reminiscent of transition metals in borrowing hydrogen mediated processes. 相似文献
42.
S. K. Srivastava 《International Journal of Theoretical Physics》1995,34(1):109-125
Expressions for the time dependence of the fundamental constants are derived through dimensional reduction and one-loop quantum corrections to scalar fields. Moreover, singularity-free solutions of Einstein's field equations are obtained. Using these solutions, we discuss the time dependence of fundamental constants. It is interesting to see that the fine structure constant asymptotically approaches to 1/137,G
eff (effective four-dimensional constant) approachesG
N (Newtonian gravitational constant), and eff vanishes. Graphical representations of these results are also given for a special case. 相似文献
43.
The total and differential cross sections for the electron and positron impact excitation of hydrogen from its initially excited metastable 22S state to 32S and 32P states are reported. A distorted-wave approximation theory is used for the calculation. The angular correlation parameters, Ly and alignment angle are also reported for 22S-32P excitation. For comparison, similar first Born results are also obtained. Interesting features are noted on comparing our distorted wave results with the first Born results as well as with the other available results forn
2S andn
2P (n=2,3) excitations from the ground 12S state of hydrogen. 相似文献
44.
45.
G. S. Srivastava 《分析论及其应用》1996,12(4):96-104
The regular solutions of generalized axisymmetric potential equation
, a>−1/2 are called generalized axisymmetric potentials. In this paper, the characterizations of lower order and lower type
of entire GASP in terms of their approximation error {En} have been obtained. 相似文献
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