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11.
V. D. Anand J. P. Srivastava G. S. Deshmukh 《Fresenius' Journal of Analytical Chemistry》1962,191(5):321-329
Summary The polarographic behaviour of nickel and cobalt in the mixed base electrolytes, urea-pyridine and urea-hydrazine has been studied. The effect of pH, concentration of supporting electrolyte and the presence of various other ions was investigated. Well defined polarograms for both the elements were obtained at pH 6.0 and 5.0 respectively. Attempts were made to utilize these observations in the separation of the two cations. While the difference in E
1/2 of the ions in urea-pyridine was greater than –0.3 volts that in urea-hydrazine was about –0.2 volts or slightly less even under the optimum conditions. In a mixed solution the waves for Co and Ni were therefore well developed and separated in the former base electrolyte. The polarograms in urea-hydrazine were, however, of little analytical use because of the washing away of the Ni wave due to the presence of even small amounts of cobalt.
Zusammenfassung Das polarographische Verhalten von Nickel und Kobalt in Harnstoff-Pyridin- und Harnstoff-Hydrazinlösung wurde untersucht und der Einfluß des pH-Wertes, der Leitsalzkonzentration sowie der Gegenwart verschiedener anderer Ionen festgestellt. Bei pH 6,0 bzw. 5,0 wurden für beide Elemente gut ausgebildete Polarogramme erhalten. Es wurde versucht, die erhaltenen Ergebnisse zur Trennung der beiden Ionen zu benutzen. In Harnstoff-Pyridinlösung beträgt der Unterschied der beiden Halbstufenpotentiale mehr als –0,3 V und man erhält gut ausgebildete und voneinander getrennte Stufen. In Harnstoff-Hydrazinlösung dagegen beträgt der Unterschied nur –0,2 V oder etwas weniger, selbst unter optimaler Bedingungen, und die Ni-Stufe wird schon durch kleine Kobaltmengen beeinträchtigt.相似文献
12.
Processes for the production of xylenes, which occur in an integrated aromatic complex, are discussed. A brief overview of the work carried out at Indian Petrochemicals Corporation Limited for the development of zeolite-based catalytic processes for the production of aromatics is presented. This includes xylene isomerization, transalkylation and disproportionation of C7 and C9 aromatics for maximization of xylenes, selective disproportionation of toluene and selective alkylation of mono-alkylaromatics to p-dialkylbenzene. Achievements in the commercialization of zeolite-based catalysts and processes for isomerization of m-xylene to p- and o-xylene along with dealkylation of ethylbenzene, and for selective ethylation of ethylbenzene to produce p-diethylbenzene are highlighted. 相似文献
13.
Bhatt AI May I Volkovich VA Collison D Helliwell M Polovov IB Lewin RG 《Inorganic chemistry》2005,44(14):4934-4940
The reduction of selected lanthanide cations to the zerovalent state in the room-temperature ionic liquid [Me3N(n)Bu][TFSI] is reported (where TFSI = bistriflimide, [N(SO2CF3)2]-). The lanthanide cations were introduced to the melt as the TFSI hydrate complexes [Ln(TFSI)3(H2O)3] (where Ln = La(III), Sm(III) or Eu(III)). The lanthanum compound [La(TFSI)3(H2O)3] has been crystallographically characterized, revealing the first structurally characterized f-element TFSI complex. The lanthanide in all three complexes was shown to be reducible to the metallic state in [Me3N(n)Bu][TFSI]. For both the Eu and Sm complexes, reduction to the metallic state was achieved via divalent species, and there was an additional observation of the electrodeposition of Eu metal. 相似文献
14.
Vigneshwaran N Bijukumar G Karmakar N Anand S Misra A 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,61(1-2):163-170
This article describes the analysis of autofluorescence of advanced glycation end products of hemoglobin (Hb-AGE). Formed as a result of slow, spontaneous and non-enzymatic glycation reactions, Hb-AGE possesses a characteristic autofluorescence at 308/345 nm (lambda(ex)/lambda(em)). Even in the presence of heme as a quenching molecule, the surface presence of the glycated adduct gave rise to autofluorescence with the quantum yield of 0.19. The specificity of monoclonal antibody developed against common AGE structure with Hb-AGE was demonstrated using reduction in fluorescence polarization value due to increased molecular volume while binding. The formation of fluorescent adduct in hemoglobin in the advanced stage of glycation and the non-fluorescent HbA(1c) will be of major use in distinguishing and to know the past status of diabetes mellitus. While autofluorescence correlated highly with HbA(1c) value under in vivo condition (r = 0.85), it was moderate in the clinical samples (r = 0.55). The results suggest a non-linear relation between glycemia and glycation, indicating the application of Hb-AGE as a measure of susceptibility to glycation rather than glycation itself. 相似文献
15.
B. S. Randhawa Anand Pal Singh R. P. Sharma P. S. Bassi 《Journal of Radioanalytical and Nuclear Chemistry》1988,128(3):165-179
The solid state reactions between ferrous oxalate dihydrate i.e. FeC2O4.2H2O and unsubstituted/ substituted aniline hydrochlorides have been studied. The products [FeCl/oxH/. AN-Cl] have been characterized by elemental analysis, infrared and Mössbauer spectroscopic techniques. The kinetic studies for the reactions have been performed at various temperatures for fixed particle sizes at constant compaction. The following order of reactivity has been observed: unsubstituted > p-substituted > m-substituted o-substituted. 相似文献
16.
Anand R Puri SC Verma N Handa G Khajuria RK Gupta VK Suri OP Qazi GN 《Journal of chromatographic science》2003,41(8):444-446
The present work describes isolation of bioactive lipophilic constituent [namely, hyperforin from St. John's wort (Hypericum perforatum L.)], of approximately 98% purity by semipreparative high-performance liquid chromatography (LC). The extraction, isolation, and analysis of the collected compound is performed without the use of antioxidants and inert gas atmospheres at all the stages. Hyperforin, separated isocratically on a 12microm semiprep column, is obtained in high purity, lyophilized after the removal of the organic phase, and preserved at a low temperature. The purity of the collected marker compound is estimated by the use of LC-mass spectrometry and spectroscopic techniques. 相似文献
17.
Venkatraman S Anand VG Pushpan SK Sankar J Chandrashekar TK 《Chemical communications (Cambridge, England)》2002,(5):462-463
Successful syntheses of two new aromatic core modified oxybenziporphyrins by a simple '3 + 1' methodology and the first aromatic core modified oxybenziporphyrin palladium complex are reported. 相似文献
18.
Anand VG Venkatraman S Rath H Chandrashekar TK Teng W Ruhlandt-Senge K 《Chemistry (Weinheim an der Bergstrasse, Germany)》2003,9(10):2282-2290
Modified octaphyrins with 34pi electrons have been synthesized and characterized following a simple synthetic methodology. An acid-catalyzed alpha,alpha coupling of tetrapyrranes containing furan, thiophene and selenophene rings resulted in the formation of the respective octaphyrins in relatively good yield. Solution studies by (1)H NMR and 2D NMR methods and single crystal Xray structural characterization reveal an almost flat structure with two heterocyclic rings inverted. Specifically, in 14 two selenophene rings (one on each biselenophene unit) are inverted while in 15 two furan rings (one on each bifuran unit) are inverted when the meso substituent are mesityl groups. On changing the mesityl substituent to m-xylyl group as in 19, the location of ring inversion shifts to pyrrole rings (one on each bipyrrole unit) indicating the dependence of structure on the meso substituents. UV/Vis studies, both in freebase and protonated forms reveal typical porphyrinic character and the aromatic nature of the octaphyrins. The Deltadelta values evaluated by (1)H NMR spectroscopy also support their aromatic nature. The protonated forms of octaphyrins bind TFA anion in a 1:2 ratio. The TFA anions are located one above and below the plane of the octaphyrin macrocycle and they are held by weak electrostatic NH-O interactions similar to that observed for protonated rubyrins. However, in the present case, there is an additional non-electrostatic CH-O interaction involving beta-CH of the inverted heterocyclic ring and the carbonyl oxygen of the TFA. Furthermore, inter molecular interactions between the Cbond;H of the meso-mesityl group and the fluorine of CF(3) group of bound TFA leads to the formation of one-dimensional supramolecular arrays with interplanar distance of 13 A between two octaphyrins. 相似文献
19.
Raquel Simancas Anand Chokkalingam Shanmugam P. Elangovan Zhendong Liu Tsuneji Sano Kenta Iyoki Toru Wakihara Tatsuya Okubo 《Chemical science》2021,12(22):7677
Zeolites have been successfully employed in many catalytic reactions of industrial relevance. The severe conditions required in some processes, where high temperatures are frequently combined with the presence of steam, highlight the need of considering the evolution of the catalyst structure during the reaction. This review attempts to summarize the recently developed strategies to improve the hydrothermal framework stability of zeolites.This review attempts to summarize the recently developed strategies to improve the hydrothermal framework stability of zeolites. 相似文献
20.
Anand Pal Singh P. Ramos Cabrer E. Alvarez-Parrilla F. Meijide J. Vázquez Tato 《Journal of inclusion phenomena and macrocyclic chemistry》1999,35(1-2):335-348
In order to study its guest binding and the inclusion phenomena, 6-deoxy-6-(aminoethyl)amino--cyclodextrin (CDN) was synthesised and its binding properties examined. The complexation phenomena of sodium cholate (NaC) and sodium deoxycholate (NaDC) with CDN has been monitored by the NMR method using 13C chemical shift data. The method of continuous variation Job's method has been used to determine the stoichiometry of these supramolecular complexes. The Job's plot confirms the 1 : 1 supramolecular complex for NaC: CDN and the 1 : 2 supramolecular complex for NaDC: CDN. The interaction of NaC and NaDC with CDN has been obtained through two-dimensional Rotational Nuclear Overhauser Effect Spectroscopy (ROESY) NMR. Equilibrium constants were also obtained from 13C chemical shift data (C-1, C-3 & C-4) at different pH values (7, 9, & 11). 相似文献