Application of a nanostructured supramolecular solvent for the microextraction of diphenylamine and its mono‐nitrated derivatives from unburned single‐base propellants

A supramolecular solvent made up of nano‐sized inverted hexagonal aggregates of 1‐octanol is proposed for the microextraction of diphenylamine and its mono‐nitrated derivatives in unburned single‐base propellants. The procedure included the extraction of sub‐gram quantities (30 mg) of homogenized propellant with 1.5 mL of the supramolecular solvent. Several conditions affecting extraction efficiency, for example the concentrations of the major components of the supramolecular solvent (tetrahydrofuran and alkanol), alkanol type, solvent pH, and extraction time, were investigated and optimized. The main forces for the microextraction of analytes in the nanostructured supramolecular solvent include both dispersion and hydrogen bond interactions. This mixed‐mode mechanism resulted in high extraction efficiencies reaching low method detection limits (0.005–0.012 mg/g) without the need for extract evaporation. Under the optimum conditions, recoveries in samples ranged between about 82.6 and 98.7%. Compared to the reference method, the proposed method is simple and rapid, delivering accurate and precise results, and can be applied for routine determination of diphenylamine and its derivatives in propellants. The precision of the method, expressed as relative standard deviation, was about 4.3–10.9%.     

Ordered Semigroups Characterized by Their Intuitionistic Fuzzy Generalized Bi-ideals

In this paper, we define intuitionistic fuzzy generalized bi-ideals in ordered semigroups and characterize regular and left weakly regular ordered semigroups in terms of intuitionistic fuzzy generalized bi-ideals.     

Numerical and experimental direct shear tests for coarse-grained soils

The presence of particles larger than the permissible dimensions of conventional laboratory specimens causes difficulty in the determination of shear strength of coarse-grained soils. In this research, the influence of particle size on shear strength of coarse-grained soils was investigated by resorting to experimental tests in different scale and numerical simulations based on discrete element method (DEM). Experimental tests on such soil specimens were based on using the techniques designated as "parallel" and "scalping" to prepare gradation of samples in view of the limitation of laboratory specimen size. As a second approach, the direct shear test was numerically simulated on assemblies of elliptical particles. The behaviors of samples under experimental and numerical tests are presented and compared, indicating that the modification of sample gradation has a significant influence on the mechanical properties of coarse-grained soils. It is noted that the shear strengths of samples produced by the scalping method are higher than samples by the parallel method. The scalping method for preparing specimens for direct shear test is therefore recommended. The micromechanical behavior of assemblies under direct shear test is also discussed and the effects of stress level on sample behavior are investigated.     

Travelling wave and similarity solutions to nonlinear evolution type equations through inverse variational and symmetry methods

Shallow water equations are usually modelled by nonlinear KdV type equations of which various generalisations now exist. For example there are vector versions of the modified KdV equation and shallow water equations with nonlinear internal waves. We discuss the reduction and solutions of these and other large classes of such type of equations using inverse variational and symmetry methods.     

On the analytic solution of nonlinear flow problem involving Oldroyd 8-constant fluid

The problem dealing with the steady flow of an Oldroyd 8-constant fluid over a suddenly moved plate is considered. The fluid is electrically conducting and a uniform magnetic field is applied in the transverse direction. An analytical solution of the nonlinear boundary value problem is obtained using homotopy analysis method (HAM). The behavior of the material constants and the magnetic field is seen on the velocity distribution. It is noted that the boundary layer thickness decreases by increasing the magnetic parameter.     

Wall properties and heat transfer analysis of the peristaltic motion in a power‐law fluid

A mathematical analysis has been carried out to investigate the effect of elasticity of the flexible walls on the peristaltic flow of a power‐law fluid. The heat transfer analysis is further examined. Expressions of stream function, velocity, and temperature distributions are presented in closed form under long wavelength and low Reynolds number approximations. The effects of the various parameters entering into the mathematical analysis are sketched and discussed. Copyright © 2012 John Wiley & Sons, Ltd.     

Effects of Hall current and heat transfer on rotating flow of a second grade fluid through a porous medium

The effects of Hall current and heat transfer on the rotating flow of a second grade fluid past a porous plate with variable suction are examined. The medium considered is porous and suction and external flow velocities vary periodically. The plate is assumed to be at a higher temperature than the fluid. The influences of the Hall parameter and porosity of the medium have been seen and discussed on the velocity and temperature profiles. Moreover, these influences have also been seen on the drag and lateral stress. Finally, the obtained solutions are also compared with the previous studies in the literature and found quite agreement.     

Improvement of colour strength and colourfastness properties of gamma irradiated cotton using reactive black-5

The dyeing behaviour of gamma irradiated cotton fabric using Reactive Black-5 dye powder has been investigated. The mercerized, bleached and plain weaved cotton fabric was irradiated to different absorbed doses of 100, 200, 300, 400, 500 and 600 Gy using Co-60 gamma irradiator. Dyeing was performed using irradiated and un-irradiated cotton with dye solutions. The dyeing parameters such as temperature of dyeing, time of dyeing and pH of dyeing solutions were optimised. The colour strength values of dyed fabrics were evaluated by comparing irradiated and un-irradiated cotton in CIE Lab system using Spectra flash SF650. Methods suggested by International Standard Organisation (ISO) were employed to study the effect of gamma irradiation on the colourfastness properties of dyed fabric. It is found that gamma irradiated cotton dyed with Reactive Black-5 has not only improved the colour strength but also enhanced the rating of fastness properties.