Resonances and the Weinberg-Tomozawa 56-baryon-35-meson interaction

Vector meson degrees of freedom are incorporated into the Weinberg-Tomozawa (WT) meson-baryon chiral Lagrangian by using a scheme which relies on spin-flavor SU(6) symmetry. The corresponding Bethe-Salpeter approximation successfully reproduces previous SU(3)-flavor WT results for the lowest-lying s-wave negative-parity baryon resonances, and it also provides some information on the dynamics of the heavier ones. Moreover, it also predicts the existence of an isoscalar spin-parity ^- K^*N bound state (strangeness +1) with a mass around 1.7-1.8GeV, unstable through K^* decay. Neglecting d-wave KN decays, this state turns out to be quite narrow ( Γ≤15MeV) and it might provide clear signals in reactions like γp→ˉ⁰ pK ⁺ π ^- by looking at the three-body pK ⁺ π ^- invariant mass.     

On the cascade approach to the quantum multiscattering problem

The multiscattering problem is studied in the matrix density formalism. We study how to isolate the quasi-classical degrees of freedom in order to connect them with a cascade approach. The different problems that arise, as well as their possible solutions, are discussed and exemplified with a pion-nucleus model. Received: 24 May 2002 / Accepted: 25 July 2002 / Published online: 17 January 2003 RID="a" ID="a"e-mail: salcedo@ugr.es Communicated by A. Sch?fer     

Theoretical treatment of relaxation oscillations in quasi-three-level systems

The study of the temporal and spectral behavior of relaxation oscillations in quasi-three-level systems allows the direct measurement of the absolute value and spectral profile of laser-transition absorption and emission cross sections, simultaneously and independently, not requiring the usual assumption of Boltzman distributions for the intermanifold sublevels.On leave from the General Physics Institute, Russian Academy of Sciences, Moscow, Russia     

Angular dependence of the transverse and vortex modesin magnetic nanotubes

The angular dependence of the transverse and vortex modes in a magnetic nanotube is investigated as a function of the tube geometry, by means of analytical calculations and numerical simulations. A critical radius defining the transition between vortex and transverse reversal modes is determined, leading to low or high coercivity modes just by varying the direction of the external field, in a fixed nanotube.     

Ni(eta 3-CH2C(CH3)CH2)(SbPh3)3][BAr'4]: an extremely active cationic allyl nickel-stibine catalyst for the oligomerization of styrene

The pseudotetrahedral, formally 5-coordinate complex [Ni(eta 3-CH2C(CH3)CH2)(SbPh3)3][BAr'4] (Ar' = 3,5-C6H3(CF3)2) as well as the 4-coordinate derivative [Ni(eta 3-CH2C(CH3)CH2)(AsPh3)2][BAr'4] act as extremely efficient catalysts for the oligomerization of styrene.     

Nonaqueous capillary electrophoresis method for the analysis of gleevec and its main metabolite in human urine

The viability of nonaqueous capillary electrophoresis (NACE) was investigated for determination of gleevec and its main metabolite in human urine using a fused-silica capillary. Baseline separation of the studied solutes was obtained using a nonaqueous solution composed of 12 mM ammonium acetate and 87.6 mM acetic acid in methanol-acetonitrile (ACN) (80:20, v:v) providing analysis time shorter than 3 min. Different aspects including stability of the solutions, linearity, accuracy and precision were studied in order to validate the method in the urine matrix. Detection limits of 24 microg L(-1) for gleevec and its metabolite were obtained. A robustness test of the method was carried out using the Plackett-Burman fractional factorial model with a matrix of 15 experiments. The developed method is simple, rapid and sensitive and has been used to determine gleveec and its metabolite at clinically relevant levels in human urine. Before NACE determination, a solid-phase extraction (SPE) procedure with a C18 cartridge was necessary. Real determination of these analytes in two patient urines were done.     

Development and validation method for determination of Paroxetine and its metabolites by nonaqueous capillary electrophoresis in human urine. Experimental design for evaluating the ruggedness of the method

A simple, rapid, and sensitive procedure using nonaqueous capillary electrophoresis (NACE) to measure Paroxetine (one of the mostly used antidepressants for mental diseases treatment) and three metabolites has been developed and validated. Optimum separation of paroxetine and metabolites was obtained on a 57 cm x 75 microm capillary using a nonaqueous buffer system of 9:1 methanol-acetonitrile containing 25 mM ammonium acetate and 1% acetic acid, with temperature and voltage of 25 degrees C and 15 kV, respectively, and hydrodynamic injection. Fluoxetine was used as an internal standard. Good results were obtained for different aspects including stability of the solutions, linearity, accuracy, and precision. Detection limits between 9.3 and 23.1 microg.L(-1) were obtained for paroxetine and its metabolites. A ruggedness test of the method was carried out using the Plackett-Burman fractional factorial model with a matrix of 15 experiments. This method has been used to determine paroxetine and its main metabolite B at clinically relevant levels in human urine. Prior to NACE determination, the samples were purified and enriched by means of an extraction-preconcentration step with a preconditioned C18 cartridge and eluting the compounds with methanol.