全文获取类型
收费全文 | 5695篇 |
免费 | 285篇 |
国内免费 | 8篇 |
专业分类
化学 | 4050篇 |
晶体学 | 45篇 |
力学 | 100篇 |
数学 | 873篇 |
物理学 | 920篇 |
出版年
2023年 | 46篇 |
2022年 | 97篇 |
2021年 | 121篇 |
2020年 | 150篇 |
2019年 | 124篇 |
2018年 | 166篇 |
2017年 | 126篇 |
2016年 | 245篇 |
2015年 | 213篇 |
2014年 | 231篇 |
2013年 | 414篇 |
2012年 | 452篇 |
2011年 | 468篇 |
2010年 | 267篇 |
2009年 | 239篇 |
2008年 | 373篇 |
2007年 | 330篇 |
2006年 | 294篇 |
2005年 | 265篇 |
2004年 | 215篇 |
2003年 | 168篇 |
2002年 | 178篇 |
2001年 | 92篇 |
2000年 | 75篇 |
1999年 | 62篇 |
1998年 | 53篇 |
1997年 | 38篇 |
1996年 | 63篇 |
1995年 | 34篇 |
1994年 | 46篇 |
1993年 | 34篇 |
1992年 | 37篇 |
1991年 | 24篇 |
1990年 | 24篇 |
1989年 | 16篇 |
1988年 | 7篇 |
1987年 | 12篇 |
1986年 | 14篇 |
1985年 | 22篇 |
1984年 | 14篇 |
1983年 | 11篇 |
1982年 | 11篇 |
1981年 | 13篇 |
1980年 | 10篇 |
1979年 | 8篇 |
1977年 | 6篇 |
1976年 | 6篇 |
1975年 | 10篇 |
1973年 | 8篇 |
1969年 | 6篇 |
排序方式: 共有5988条查询结果,搜索用时 12 毫秒
11.
Vanessa R. Machado Louis P. Sandjo Giovanni L. Pinheiro Milene H. Moraes Mario Steindel Moacir G. Pizzolatti 《Natural product research》2018,32(3):275-281
The natural product lupeol 1 was isolated from aerial parts of Vernonia scorpioides with satisfactory yield, which made it viable to be used as starting material in semisynthetic approach. Ten lupeol derivatives 2–11 were prepared by classical procedures. Including, five new esters derivatives 7–11, which were obtained by structural modifications in the isopropylidene fragment. All semisynthetic compounds and lupeol 1–11 were confirmed by 1H NMR, 13C NMR and HRMS. Their antiprotozoal activity was evaluated in vitro against L. amazonensis and T. cruzi. Derivative 6 showed the best antitrypanosomal activity (IC50 = 12.48 μg/mL) and the lowest cytotoxic derivative (CC50 = 161.50 μg/mL). The mechanism of action of the most active derivatives (4, 6 and 11) is not dependent from the enzyme trypanothione reductase. 相似文献
12.
Biosorption of Chromium(III) by Biomass of Seaweed Sargassum sp. in a Fixed-Bed Column 总被引:2,自引:0,他引:2
Eneida Sala Cossich Edson Antonio da Silva Célia Regina Granhen Tavares Lúcio Cardozo Filho Teresa Massako Kakuta Ravagnani 《Adsorption》2004,10(2):129-138
This work aimed at modeling chromium biosorption using the biomass of seaweed Sargassum sp. in a fixed-bed column. The mathematical model used was obtained from the mass balance of the component in the liquid phase and in the biosorbent material. The effects of both axial dispersion in the column and the resistance to mass transfer in the solid were considered for the solution of the partial differential equations of the model, using the Galerkin method on finite elements. To represent the equilibrium data of the batch system the Langmuir isotherm were used. The chromium ion adsorption capacity of the seaweed Sargassum sp., at a temperature of 30°C and pH 3.5, was 2.61 mmol/g. The model performance was evaluated from experimental data obtained at 30°C for flow rates of 2, 6 and 8 mL/min. The parameters of the model, mass transfer and axial dispersion coefficients, were adjusted from these experimental data. The model proved adequate to describe chromium biosorption dynamics in fixed-bed columns. 相似文献
13.
It is a well-known feature of odd space-time dimensions d that there exist two inequivalent fundamental representations A and B of the Dirac gamma matrices. Moreover, the parity transformation swaps the fermion fields living in A and B. As a consequence, a parity-invariant Lagrangian can only be constructed by incorporating both the representations. Based upon these ideas and contrary to long-held belief, we show that in addition to a discrete exchange symmetry for the massless case, we can also define chiral symmetry provided the Lagrangian contains fields corresponding to both the inequivalent representations. We also study the transformation properties of the corresponding chiral currents under parity and charge-conjugation operations. We work explicitly in 2 + 1 dimensions and later show how some of these ideas generalize to an arbitrary number of odd dimensions. 相似文献
14.
J. Pisút N. Pisútová B. Tomásik 《The European Physical Journal C - Particles and Fields》2003,29(1):79-85
We present a few estimates of energy densities reached in heavy-ion collisions at the CERN SPS. The estimates are based on
data and models of proton-nucleus and nucleus-nucleus interactions. In all of these estimates the maximum energy density in
central Pb+Pb interactions is larger than the critical energy density GeV/fm3 following from lattice gauge theory computations. In estimates which we consider as realistic the maximum energy density
is about . In this way our analysis gives some support to claims that deconfined matter has been produced at the CERN SPS. Any definite
statement requires a deeper understanding of formation times of partons and hadrons in nuclear collisions. We also compare
our results with implicit energy estimates contained in earlier models of anomalous suppression in nuclear collisions.
Received: 3 February 2003 / Revised version: 5 March 2003 / Published online: 5 May 2003 相似文献
15.
Let Um be an m×m Haar unitary matrix and U[m,n] be its n×n truncation. In this paper the large deviation is proven for the empirical eigenvalue density of U[m,n] as m/n→λ and n→∞. The rate function and the limit distribution are given explicitly. U[m,n] is the random matrix model of quq, where u is a Haar unitary in a finite von Neumann algebra, q is a certain projection and they are free. The limit distribution coincides with the Brown measure of the operator quq. 相似文献
16.
Július Korbaš 《Acta Mathematica Hungarica》2004,105(1-2):129-137
We prove new results about the vector field problem on the real flag manifolds O(n)/O(1) x O(1) x O(n - 2). For some infinite families of these manifolds, we completely solve the vector field problem. 相似文献
17.
Jesús M. Velásquez Bermúdez 《Annals of Operations Research》2002,117(1-4):21-31
This document presents theoretical considerations about the solution of dynamic optimization problems integrating the Benders Theory, the Dynamic Programming approach and the concepts of Control Theory. The so called Generalized Dual Dynamic Programming Theory (GDDP) can be considered as an extension of two previous approaches known as Dual Dynamic Programming (DDP): The first is the work developed by Pereira and Pinto [3–5], which was revised by Velásquez and others [8,9]. The second is the work developed by Read and others [2,6,7]. 相似文献
18.
Carmelo Nú¯nez 《Annali di Matematica Pura ed Applicata》1992,161(1):43-56
Summary Let K be a compact Hausdorff space and let E be a Banach space. We denote by C(K, E) the Banach space of all E-valued continuous functions defined on K, endowed with the supremum norm. We study in this paper Banach-Saks operators defined on C(K, E) spaces. We characterize these operators for a large class of compacts K (the scattered ones), or for a large class of Banach spaces E (the superreflexive ones). We also show by some examples that our theorems can not be extended directly.Partially supported by C.A.I.C.Y.T. grant 0338-84. The author wishes to thank Professor F.Bombal for his encouragement. 相似文献
19.
Generators of some Ramanujan formulas 总被引:2,自引:0,他引:2
Jesús Guillera 《The Ramanujan Journal》2006,11(1):41-48
In this paper we prove some Ramanujan type formulas for 1/π but without using the theory of modular forms. Instead we use
the WZ—method created by H. Wilf and D. Zeilberger and find some hypergeometric functions in two variables which are second
components of WZ—pairs than can be certified using Zeilberger's EKHAD package. These certificates have an additional property
which allows us to get generalized Ramanujan's type series which are routinely proven by computer. We call these second hypergeometric
components of the WZ—pairs generators. Finding generators seems a hard task but using a kind of experimental research (explained
below), we have succeeded in finding some of them. Unfortunately we have not found yet generators for the most impressive
Ramanujan's formulas. We also prove some interesting binomial sums for the constant 1/π2. Finally we rewrite many of the obtained series using pochhammer symbols and study the rate of convergence.
2000 Mathematics Subject Classification Primary—33C20 相似文献
20.
Alexander Semenov Aurélia Charlot Rachel Auzély-Velty Marguerite Rinaudo 《Rheologica Acta》2007,46(5):541-568
Dynamics of associating polymer solutions above the reversible gelation point are studied. Each macromolecule consists of
a soluble backbone (B) and a small fraction of specific strongly interacting groups (A or C stickers) attached to B. A mixture
of B–A and B–C associating polymers with 1:1 stoichiometric ratio is considered. As a result of AC association, the polymers
reversibly gelate above the overlap concentration. It is shown that (1) the network strands are linear complexes (double chains)
of B–A and B–C; (2) “diffusion” of the network junction points is characterized by an apparent activation energy, which can
be significantly higher than the energy of one AC bond; (3) most importantly, the randomness of sticker distribution along
the chain can significantly slow down the network relaxation leading to a markedly non-Maxwellian viscoelastic behavior. The
theory elucidates the most essential features of rheological behavior of polysaccharide associating systems (with A = adamantyl
moiety, C = β-cyclodextrin, B = either chitosan or hyaluronan) including similar behavior of G
′ and G
″ in a wide frequency range, strong temperature dependence of the characteristic frequency ω
x
, and an extremely strong effect of added free stickers (fC) on the dynamics.
This paper was presented at Annual European Rheology Conference (AERC) held in Hersonisos, Crete, Greece, April 27–29, 2006. 相似文献