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41.
Magnus Mahl Dr. Kazutaka Shoyama Ana-Maria Krause Dr. David Schmidt Prof. Dr. Frank Würthner 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(32):13503-13507
We report the direct imidization of naphthalene and perylene dicarboxylic anhydrides/esters with bulky ortho,ortho-diaryl- and ortho,ortho-dialkynylaniline derivatives. This imidization method uses n-butyllithium as a strong base to increase the reactivity of bulky amine derivatives, proceeds under mild reaction conditions, requires only stoichiometric amounts of reactants and gives straightforward access to new sterically crowded rylene dicarboximides. Mechanistic investigations suggest an isoimide as intermediary product, which was converted to the corresponding imide upon addition of an aqueous base. Single-crystal X-ray diffraction analyses reveal dimeric packing motifs for monoimides, while two-side shielded bisimides crystallize in isolated molecules without close π–π-interactions. Spectroscopic investigations disclose the influence of the bulky substituents on the optical properties in the solid state. 相似文献
42.
The tetrahedral bending angle in V-shaped nematogens was claimed to be the optimum for finding a biaxial nematic liquid crystal phase. The benzo[1,2-b:4,3-b’]dithiophene core, recently successfully applied as a tetrahedral bending unit in mesogens with lateral flexible chains, is here embedded in a scaffold with only terminal chains, which conventionally promotes the formation of nematic phases at low temperature. A series of new mesogens has been successfully prepared, realising hockey-stick, hockey-stick dimer and V-shaped molecular topologies. Only the hockey-stick mesogens assemble in uniaxial nematic phases over a broad temperature range. Single crystal structure analysis of a hockey-stick and V-shaped compound reveal remarkable similarities with the benzodithiophene core wrapped by aliphatic chains. A model explaining the absence of nematic mesophases in the family of V-shaped, shape-persistent mesogens with terminal aliphatic chains is presented and results in the proposal of a new design for biaxial nematogens. 相似文献
43.
Frenţiu T Rusu AM Ponta M Anghel SD Cordos EA 《Analytical and bioanalytical chemistry》1996,355(3-4):254-255
A low to medium power radiofrequency capacitively coupled plasma is characterized as spectral source for atomic emission. The signal to background ratio and the limits of detection were determined for 19 elements as a function of the plasma torch geometry and the observation point. 相似文献
44.
Ionel Stavarache Ana-Maria Lepadatu Nicoleta G. Gheorghe Ruxandra M. Costescu George E. Stan Dan Marcov Adrian Slav Gheorghe Iordache Tionica F. Stoica Vladimir Iancu Valentin S. Teodorescu Cristian M. Teodorescu Magdalena Lidia Ciurea 《Journal of nanoparticle research》2011,13(1):221-232
Transmission electron microscopy and X-ray photoelectron spectroscopy analyses are performed to investigate Ge nanoparticles embedded in an amorphous SiO2 matrix. GeSiO thin films are prepared by two methods, sol?Cgel and radio frequency magnetron sputtering. After the deposition, the sol?Cgel films are annealed in either N2 (at 1 atm and 800 °C) or H2 (at 2 atm and 500 °C), and the sputtered films in H2 (at 2 atm and 500 °C), to allow Ge segregation. Amorphous Ge-rich nanoparticles (3?C7 nm size) are observed in sol?Cgel films. Crystalline Ge nanoparticles in the high pressure tetragonal phase (10?C50 nm size) are identified in the sputtered films. The size of the nanoparticles increases with Ge concentration in the volume of the film. At the film surface, the Ge concentration is much larger that in the volume for both sol?Cgel and sputtered films. At the same time, at the film surface, only oxidized Ge is observed. 相似文献
45.
46.
Monica Culea Ana-Maria Salmon 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-4)
Abstract The present paper reports the mass spectra of some compounds of 2-alkylenbenzimidazolylaminomethylphosphonates with the general formula: 相似文献
47.
48.
Ana-Maria Oros-Peusquens Tony Stoecker Katrin Amunts Karl Zilles Nadim Jon Shah 《Magnetic resonance imaging》2010
We present high-resolution in vivo anatomical scans with 3D whole-brain coverage and an isotropic resolution of 0.6 mm, obtained at a clinical field of 1.5 T. The data are acquired in 10 independent scans over two sessions using a 3D magnetization-prepared, gradient echo sequence, modified to output phase images in addition to magnitude images. The independent scans are coregistered to correct for head motion, prior to performing complex averaging. The resolution of the final, averaged image, is found to be equal to the nominal one. 相似文献
49.
The analysis of conductive solid samples by r.f. capacitively coupled plasma at atmospheric pressure
Anghel SD Frentiu T Rusu AM Bese L Cordos EA 《Analytical and bioanalytical chemistry》1996,355(3-4):252-253
A radiofrequency capacitively coupled plasma (rf CCP) with tip-ring electrode geometry has been used for the analysis of Al, Co, Cr, Cu, Mn, Mo, Ni, and V in low and medium alloyed steel. The sample is used as one of the electrodes of the plasma torch. The influence of plasma power, argon flow rate and distance between the electrodes on the analytical signals has been studied. The limits of detection are in the range of 0.001 to 0.048%. The dynamic range is three orders of magnitude. 相似文献
50.
Ana-Maria Voiculescu Serban Georgescu Silviu Nastase Cristian Matei Daniela Berger Cristina Matei Angela Stefan Octavian Toma 《Journal of Sol-Gel Science and Technology》2012,64(3):667-672
Nanopowders of langasite (La3Ga5SiO14) doped with 1 at.% Er3+ and 3 at.% Yb3+ were synthesized for the first time by a modified Pechini route and annealed in air at 700, 750, 800, 900, and 1,000?°C. The langasite powders were characterized by XRD, FTIR and luminescence techniques. Crystallization began at 750?°C and pure langasite phase was obtained for the samples annealed at 800 and 900?°C. Traces of LaGaO3 and Ga2O3 were observed in the sample annealed at 1,000?°C. Bright green and red luminescence was observed for pumping at 973?nm whose intensity increased with annealing temperature due to the removal of the adsorbed impurities and the improvement of crystallinity. 相似文献