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991.
Rivas AB Gascón JM Lahoz FJ Balana AI Pardey AJ Oro LA Pérez-Torrente JJ 《Inorganic chemistry》2008,47(13):6090-6104
The reaction of gem-dithiol compounds R 2C(SH) 2 (R = Bn (benzyl), (i) Pr; R 2 = -(CH 2) 4-) with dinuclear rhodium or iridium complexes containing basic ligands such as [M(mu-OH)(cod)] 2 and [M(mu-OMe)(cod)] 2, or the mononuclear [M(acac)(cod)] (M = Rh, Ir, cod = 1,5-cyclooctadiene) in the presence of a external base, afforded the dinuclear complexes [M 2(mu-S 2CR 2)(cod) 2] ( 1- 4). The monodeprotonation of 1,1-dimercaptocyclopentane gave the mononuclear complex [Rh(HS 2Cptn)(cod)] ( 5) that is a precursor for the dinuclear compound [Rh 2(mu-S 2Cptn)(cod) 2] ( 6). Carbonylation of the diolefin compounds gave the complexes [Rh 2(mu-S 2CR 2)(CO) 4] ( 7- 9), which reacted with P-donor ligands to stereoselectively produce the trans isomer of the disubstituted complexes [Rh 2(mu-S 2CR 2)(CO) 2(PR' 3) 2] (R' = Ph, Cy (cyclohexyl)) ( 10- 13) and [Rh 2(mu-S 2CBn 2)(CO) 2{P(OR') 3} 2] (R' = Me, Ph) ( 14- 15). The substitution process in [Rh 2(mu-S 2CBn 2)(CO) 4] ( 7) by P(OMe) 3 has been studied by spectroscopic means and the full series of substituted complexes [Rh 2(mu-S 2CBn 2)(CO) 4- n {P(OR) 3} n ] ( n = 1, 4) has been identified in solution. The cis complex [Rh 2(mu-S 2CBn 2)(CO) 2(mu-dppb)] ( 16) was obtained by reaction of 7 with the diphosphine dppb (1,4-bis(diphenylphosphino)butane). The molecular structures of the diolefinic dinuclear complexes [Rh 2(mu-S 2CR 2)(cod) 2] (R = Bn ( 1), (i) Pr ( 2); R 2 = -(CH 2) 4- ( 6)) and that of the cis complex 16 have been studied by X-ray diffraction. 相似文献
992.
Vălean AM Gómez-Ruiz S Lönnecke P Silaghi-Dumitrescu I Silaghi-Dumitrescu L Hey-Hawkins E 《Inorganic chemistry》2008,47(23):11284-11293
The (organo)gallium compounds GaCl{(SC6H4-2-PPh2)-kappa2S,P}2 (1), Ga{(SC6H4-2-PPh2)-kappa2S,P}{(SC6H4-2-PPh2)-kappaS}2 (2), GaMe2{(SC6H4-2-PPh2)-kappa2S,P} (3), GatBu2{(SC6H4-2-PPh2)-kappa2S,P} (4), GatBu{(SC6H4-2-PPh2)-kappa2S,P}{(SC6H4-2-PPh2)-kappaS} (5), [GaMe2{(mu2-SC6H4-2-AsPh2)-kappaS}]2 (6), and GatBu{(SC6H4-2-AsPh2)-kappa2S,As}{(SC6H4-2-AsPh2)-kappaS} (7) were obtained from the reaction of 2-EPh2C6H4SH (E = P (PSH), As (AsSH)) with GaCl3 (1, 2) or GaR3 (R = Me, tBu; 3-7) in different molar ratios and under different reaction conditions. Compound 2 was also obtained from Li(PS) and GaCl3 (3.5:1). While a monomeric structure with a chelating phosphinoarylthiolato ligand is observed in GaMe2{(SC6H4-2-PPh2)-kappa2S,P} (3), a dimeric arsinoarylthiolato-bridged complex [GaMe2{(mu2-SC6H4-2-AsPh2)-kappaS}]2 (6) is obtained with the corresponding AsS- ligand. B3LYP/6-31G(d) calculations show that although the dimer is thermodynamically favored for both ligands, the formation of 3 is due to the combination of higher stability of the chelate compared with the monodentate phosphorus ligand and a higher barrier for the ring opening of the PS- than of the AsS- chelate. 相似文献
993.
Dr. Sarah Desmons Yu Zhou Dr. Dan Zhang Dr. Carlos Jarava-Barrera Dr. Anaïs Coffinet Dr. Antoine Simonneau Dr. Laure Vendier Prof. Dr. Gen Luo Dr. Sébastien Bontemps 《European journal of organic chemistry》2023,26(30):e202300525
The hydroboration of CO2 into bis(boryl)acetal (BBA) compounds is an important transformation, since it enabled to selectively reduce CO2 by 4e- and to subsequently use the BBA compounds as C1 and Cn sources. However, the influence of the nature of the boryl moieties on the reactivity of BBA compounds has not been evaluated so far. In the present study, four BBA compounds – including two new ones – were reacted with 2,6-diisopropylaniline to afford the expected imine. Significant differences in the rate of the reaction from minutes to weeks have been observed depending on the BBA used, showing the importance of the nature of the boryl moieties. Theoretical investigations enabled to propose a mechanism involving the addition of the aniline to the BBA as the rate-determining step and to determine that the steric hindrance of the BBA compounds is the main factor driving the rate of this condensation reaction. 相似文献
994.
Andreia S. Oliveira João C. Silva Mónica V. Loureiro Ana C. Marques Nicholas A. Kotov Rogério Colaço Ana P. Serro 《Macromolecular bioscience》2023,23(2):2200240
Cartilage replacement materials exhibiting a set of demanding properties such as high water content, high mechanical stiffness, low friction, and excellent biocompatibility are quite difficult to achieve. Here, poly(p-phenylene-2,6-benzobisoxazole) (PBO) nanofibers are combined with polyvinyl alcohol (PVA) to form a super-strong structure with a performance that surpasses the vast majority of previously existing hydrogels. PVA–PBO composites with water contents in the 59–76% range exhibit tensile and compressive moduli reaching 20.3 and 4.5 MPa, respectively, and a coefficient of friction below 0.08. Further, they are biocompatible and support the viability of chondrocytes for 1 week, with significant improvements in cell adhesion, proliferation, and differentiation compared to PVA. The new composites can be safely sterilized by steam heat or gamma radiation without compromising their integrity and overall performance. In addition, they show potential to be used as local delivery platforms for anti-inflammatory drugs. These attractive features make PVA–PBO composites highly competitive engineered materials with remarkable potential for use in the design of load-bearing tissues. Complementary work has also revealed that these composites will be interesting alternatives in other industrial fields where high thermal and mechanical resistance are essential requirements, or which can take advantage of the pH responsiveness functionality. 相似文献
995.
Juan F. Ayala-Cabrera María J. Trujillo-Rodríguez Óscar M. Hernández-Torres Ana M. Afonso Juliette Sirieix-Plénet 《International journal of environmental analytical chemistry》2016,96(2):101-118
This work compares the performance of dispersive liquid–liquid method (DLLME) as a prior step for determining copper by flame atomic absorption spectrometry (FAAS), when using the ionic liquid (IL) 1-butyl-3-methylimidazolium hexafluorophosphate (C4MIm-PF6) or the IL-based surfactant 1-hexadecyl-3-butylimidazolium bromide (C16C4Im-Br) as extractant solvents. For the water-insoluble C4MIm-PF6, the most conventional DLLME mode using acetonitrile as dispersive solvent was employed. For the water-soluble C16C4Im-Br, the in situ DLLME mode with lithium bis[(trifluoromethane)sulfonyl]imide (Li-NTf2) as metathesis reagent was employed. In both approaches, some effective parameters such as volumes of extractant and dispersive solvents, concentration of complexing agent, pH of sample solution, salting-out effect and final diluting solvent to ensure compatibility with FAAS, were properly optimised. The optimum conditions for the IL-DLLME method using C4MIm-PF6 were: 100 μL of neat C4MIm-PF6, 1 mL of acetonitrile, 10 mL of water, no control of pH for environmental waters, NaCl content of 23 g L?1, diethyl dithiocarbamate (DDTC) as complexing agent at 10 mg L?1 and final dilution of the micro-droplet with acetonitrile up to 70 µL. The optimum conditions for the in situ IL-DLLME method using C16C4Im-Br were: 0.8 mL of acetonitrile, 10 mL of water containing C16C4Im-Br at 25.2 mmol L?1, final dilution step of the micro-droplet with 200 µL of acetonitrile and remaining conditions as those of C4MIm-PF6. The analytical performance of both methods was similar, being slightly better for the IL-DLLME method using C4MIm-PF6, with limits of detection (LOD) of 3.3 µg L?1 (versus 5.1 µg L?1 when using C16C4Im-Br), precision values as intraday relative standard deviation (RSD in %) lower than 8.8% (being of 10% for the C16C4Im-Br method) and an enrichment factor of 54 (being 27 when using C16C4Im-Br). The DLLME-FAAS method with C4MIm-PF6 was used in the analysis of environmental waters with successful performance, with relative recoveries of 110% and 105%, and interday precision with RSD values of 21% and 7.4% for spiked levels of 60 and 160 µg L?1, respectively. The results obtained when analysing an urban wastewater sample coming from an inter-laboratory exercise was comparable to those obtained for other 93 laboratories. The method was also valid for the determination of Cu2+ in presence of foreign ions commonly found in natural waters. 相似文献
996.
O. Oliveira C. A. Bertulani M. S. Hussein W. de Paula T. Frederico 《Brazilian Journal of Physics》2016,46(6):721-729
We propose a mirror model for ordinary and dark matter that assumes a new SU(3) gauge group of transformations, as a natural extension of the Standard Model (SM). A close study of big bang nucleosynthesis, baryon asymmetries, cosmic microwave background bounds, galaxy dynamics, together with the Standard Model assumptions, help us to set a limit on the mass and width of the new gauge boson. The cross section for the elastic scattering of a dark proton by an ordinary proton is estimated and compare to the WIMP–nucleon experimental upper bounds. It is observed that all experimental bounds for the various cross sections can be accommodated consistently within the gauge model. We also suggest a way for direct detection of the new gauge boson via one example of a SM forbidden process: \(e^{+} + p \rightarrow \mu ^{+} + X\), where X=Λ or Λc. 相似文献
997.
Dr. Ana M. Castilla Dr. Mark A. Miller Prof. Jonathan R. Nitschke Dr. Maarten M. J. Smulders 《Angewandte Chemie (International ed. in English)》2016,55(36):10616-10620
The derivation and application of a statistical mechanical model to quantify stereochemical communication in metal–organic assemblies is reported. The factors affecting the stereochemical communication within and between the metal stereocenters of the assemblies were experimentally studied by optical spectroscopy and analyzed in terms of a free energy penalty per “incorrect” amine enantiomer incorporated, and a free energy of coupling between stereocenters. These intra‐ and inter‐vertex coupling constants are used to track the degree of stereochemical communication across a range of metal–organic assemblies (employing different ligands, peripheral amines, and metals); temperature‐dependent equilibria between diastereomeric cages are also quantified. The model thus provides a unified understanding of the factors that shape the chirotopic void spaces enclosed by metal–organic container molecules. 相似文献
998.
999.
Saad Ihsan Butt Josip Pečarić Ana Vukelić 《Mediterranean Journal of Mathematics》2016,13(4):1495-1511
We obtained useful identities via Fink’s identity, by which the inequality of Popoviciu for convex functions is generalized for higher order convex functions. We investigate the bounds for the identities related to the generalization of the Popoviciu inequality using inequalities for the ?eby?ev functional. Some results relating to the Grüss- and Ostrowski-type inequalities are constructed. Further, we also construct new families of exponentially convex functions and Cauchy-type means by looking at linear functional associated with the obtained inequalities. 相似文献
1000.
Novel silica stabilization method for the analysis of fine nanocrystals using coherent X‐ray diffraction imaging
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Marianne Monteforte Ana K. Estandarte Bo Chen Ross Harder Michael H. Huang Ian K. Robinson 《Journal of synchrotron radiation》2016,23(4):953-958
High‐energy X‐ray Bragg coherent diffraction imaging (BCDI) is a well established synchrotron‐based technique used to quantitatively reconstruct the three‐dimensional morphology and strain distribution in nanocrystals. The BCDI technique has become a powerful analytical tool for quantitative investigations of nanocrystals, nanotubes, nanorods and more recently biological systems. BCDI has however typically failed for fine nanocrystals in sub‐100 nm size regimes – a size routinely achievable by chemical synthesis – despite the spatial resolution of the BCDI technique being 20–30 nm. The limitations of this technique arise from the movement of nanocrystals under illumination by the highly coherent beam, which prevents full diffraction data sets from being acquired. A solution is provided here to overcome this problem and extend the size limit of the BCDI technique, through the design of a novel stabilization method by embedding the fine nanocrystals into a silica matrix. Chemically synthesized FePt nanocrystals of maximum dimension 20 nm and AuPd nanocrystals in the size range 60–65 nm were investigated with BCDI measurement at beamline 34‐ID‐C of the APS, Argonne National Laboratory. Novel experimental methodologies to elucidate the presence of strain in fine nanocrystals are a necessary pre‐requisite in order to better understand strain profiles in engineered nanocrystals for novel device development. 相似文献