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91.
Svetlana B. Lyubchik Irene I. Perepichka Olga L. Galushko Andrey I. Lyubchik Elena S. Lygina Isabel M. Fonseca 《Adsorption》2005,11(5-6):581-593
In order to understand the patterns of the adsorption equilibrium of Cr (III) on activated carbon, the adsorption process
was studied by two different ways: classical batch experiments on commercial Norit and Merck activated carbons and their oxidized
forms in a wide range of pHs; and extended time-based tests at the same pH values on the same adsorbents. This approach allowed
us to understand the role of texture, chemical carbon surface functionality and experimental conditions (initial pH of the
solution, contact time and adsorbate/adsorbent ratio) on the effectiveness of Cr (III) removal. The adsorption process of
Cr (III) at (24 ± 1∘C) on Merck and Norit activated carbons and their oxidized forms were studied at pH values between 1.5 and 5 (either adjusted
or buffered). Chromium concentration was fixed at 200 ppm. The carbon loading ranged from 1.2 to 20 g/l. The carbon/Cr (III)
solution contact time was varied from 0.5–1 month to 5 months, to ensure that the saturation of the carbon level was reached.
According to the data obtained, the presence of carboxylic groups on carbon surface seems to enhance Cr (III) uptake at initial
pH of the solution in the range between 2 and 4. Depending on the nature of the adsorbent surface chemistry, the contact time
to reach equilibrium may range from 3 to 5 months. There is an optimum carbon loading which limits the Cr (III) uptake/removal
at given pH value. In order to understand the adsorption process, an ion exchange, surface complex and surface precipitation
were considered.
This paper was presented in the 5th Brazilian Meeting on Adsorption, held at Natal, Brazil, 18-21 July, 2004. 相似文献
92.
Conejo-García A Campos JM Entrena A Sánchez-Martín RM Gallo MA Espinosa A 《The Journal of organic chemistry》2003,68(22):8697-8699
A complete study of the conformational behavior of 4,8-diaza-3(1,4),9(4,1)-dipyridina-1,6(1,4)-dibenzenacyclodecaphan-3(1),9(1)-bis(ilium) bishexafluorophosphate is described. This study allows us to conclude that the process observed by which the different chemical shifts of the pyridinium protons show coalescence at a high-temperature 1H NMR is the rotation around the C-N bond, whereas the conformational equilibrium between the four conformers is produced at low temperature. 相似文献
93.
Robustness experiments are performed in analytical chemistry to assess the behaviour of an analytical procedure under conditions slightly different from those of the experimental optimum. This work presents a study of robustness applied to a previously proposed fluorescent methodology using two replicated 2(7-4) saturated fractional factorial designs. A comparison is established between three different ways to test the significance of the effects of the variables involved on the response signal. Critical discussions about the most appropriate threshold to be introduced when testing for significance of the factors and the influence of the time necessary to carry out the experiments are included. 相似文献
94.
Using a multireferent MBPT method (CIPSI) the electronic affinity (EA) of F, CN and HCC is computed. Results show how UMP2 gives unbalanced truncation of the MP series, while ROMP2 has the correct (balanced) behaviour. The good agreement with the experimental EA found for some compounds is accidental and associated to an error compensation. The good agreement with the experimental data found for the ROMP2 and CIPSI EAs is analysed.This paper was presented at the International Conference on The Impact of Supercomputers on Chemistry, held at the University of London, London, UK, 13–16 April 1987 相似文献
95.
rico Marlon de Moraes Flores Ana Paula Fleig Saidelles Eder Lisandro de Moraes Flores Mrcia Foster Mesko Mrcio Pozzobon Pedroso Valderi Luiz Dressler Celso Figueiredo Bittencourt Adilson Ben da Costa 《Microchemical Journal》2004,77(2):113-118
An alternative device for the direct solid analysis (DSA) for copper determination by flame atomic absorption spectrometry (FAAS) is proposed. Copper was directly determined in commercial medicinal plants used as dietary supplements. The determination of copper in solid samples by DSA–FAAS was made by using a conventional air–acetylene flame. Between 0.05 and 1.5 mg of each test, sample was weighed directly into a small polyethylene vial connected to the device used for solid introduction into the flame. Test samples were introduced into the flame as a dry aerosol using a T-quartz cell set between the burner and the optical path. The T-quartz cell has a slit in the superior part by which the solid aerosol passes to the flame. A transient signal, evaluated as integrated absorbance, is produced and it is totally integrated in 2 s. Background signals always presented absorbance values less than 0.1. It was found a characteristic mass of 0.8 ng Cu and absolute limit of detection of 1.2 ng (3 s), or 1.2 μg g−1 if a sample mass of 1 mg was used. Optimized conditions for air flow rate, flame stoichiometry, and so on were established as well. No excessive grinding of the samples was needed and samples with particle of size less than 80 μm were used throughout. No statistical difference between the results from the proposed system and those obtained by sample digestion and determination by conventional FAAS was observed. With the proposed procedure, more than 50 test samples can be analyzed in 1 h and it can be easily adapted to conventional spectrometers for FAAS. 相似文献
96.
Optimization of culture medium and conditions for penicillin acylase production by Streptomyces lavendulae ATCC 13664 总被引:1,自引:0,他引:1
Torres-Bacete J Arroyo M Torres-Guzmán R De La Mata I Acebal C Castillón MP 《Applied biochemistry and biotechnology》2005,126(2):119-132
The culture medium for Streptomyces lavendulae ATCC 13664 was optimized on a shake-flask scale by using a statistical factorial design for enhanced production of penicillin acylase. This extracellular enzyme recently has been reported to be a penicillin K acylase, presenting also high hydrolytic activity against penicillin V and other natural aliphatic penicillins such as penicillin K, penicillin F, and penicillin dihydroF. The factorial design indicated that the main factors that positively affect penicillin acylase production by S. lavendulae were the concentration of yeast extract and the presence of oligoelements in the fermentation medium, whereas the presence of olive oil in the medium had no effect on enzyme production. An initial concentration of 2.5% (w/v) yeast extract and 3 microg/mL of CuSO4 x 5H2O was found to be best for acylase production. In such optimized culture medium, fermentation of the microorganism yielded 289 IU/L of enzyme in 72 h when employing a volume medium/volume flask ratio of 0.4 and a 300-rpm shaking speed. The presence of copper, alone and in combination with other metals, stimulated biomass as well as penicillin acylase production. The time course of penicillin acylase production was also studied in the optimized medium and conditions. Enzyme production showed catabolite repression by different carbon sources such as glucose, lactose, citrate, glycerol, and glycine. 相似文献
97.
The main features of transition structures associated with eight-electron electrocyclic reactions have been studied with Density Functional Theory. It is found that conrotatory electrocyclization reaction of (3Z,5Z)-octa-1,3,5,7-tetraenes takes place via M?bius aromatic transition structures of helical conformation. The reaction is completely periselective. In general, transition structures having outward substituents are preferred with respect to the inward transition structures, irrespective of the pi-donor or pi-acceptor character of the substituent. In contrast with four-electron thermal conrotatory electrocyclic reactions, there is no satisfactory correlation between the difference in energy of activation between inward and outward substituents and the Taft resonance sigma(R) parameter. 相似文献
98.
Ana I. Cabañero 《Analytica chimica acta》2004,526(1):51-61
The assessment of hazard from selenium (Se) and mercury (Hg) contaminants in the food chain based on their potential bioaccessibility and on estimate of their actual content in fish is reported under an in vitro model. Atomic fluorescence spectroscopy (AFS) was applied for total selenium and mercury quantification. Selenium and mercury bioaccessibility varied depending on the type of fish analyzed. Se solubility in the gastrointestinal supernatants was higher in swordfish and sardine (76 and 83%, respectively) than in tuna (50%). A low Hg bioaccessibility (9-17%) was found for all the samples.Simulated human gastric and intestinal digestion led to the identification of selenomethionine (SeMet) and organic mercury in the three digested fish. Furthermore, these species were not modified during the digestion. Speciation of selenium compounds was done by liquid chromatography in conjunction with inductively coupled plasma mass spectrometry (LC-ICP-MS).Sardine had the most favorable Se:Hg, [Se:Hg]bioaccessible and [SeMet:Hg]bioaccessible molar ratios, making it preferable to tuna and swordfish.The effect of cooking was also evaluated. 相似文献
99.
Jos Luis Lpez Marcos Mandado Ana M. Graa Ricardo A. Mosquera 《International journal of quantum chemistry》2002,86(2):190-198
The atomic and bond properties of a series of alkanenitriles were calculated in order to analyze the transferability of the CN, methyl, and methylene groups. The calculations were carried out using the atoms in molecules (AIM) theory on RHF/6‐31++G**// RHF/6‐31G** wave functions obtained for compounds CN–R (R ranging from H to C11H23). Linear correlations between L(Ω) and N(Ω) were used to establish N(CH2) and N(CH3) nearly transferable values. Average values and maximum differences to the mean value of several properties were used for classifying the CN group. It shows a transferable behavior along the CN–R series for R>Et. The methyl group presents specific properties when R<Pr. The methylene groups can be classified considering both their position with respect to the end of the chain and the position with respect to the CN group. The atomic energy displays a dependence on the molecular size. Although this behavior does not allow to consider this property as transferable, both the ab initio total electronic molecular energies and the experimental heats of formation can be fitted, by linear regression analysis, as a function of the number of methylene groups. © 2001 John Wiley & Sons, Inc. Int J Quantum Chem, 2001 相似文献
100.
Campomanes P Menéndez MI Cárdenas-Jirón GI Sordo TL 《The journal of physical chemistry. A》2005,109(34):7822-7831
A theoretical analysis of the silver-induced ring expansion of N-chloro-N-methyl-1-hydroxycyclopropylamine to form N-methyl-2-azetidinone, and of the Cl(-) elimination from this substrate without Ag(+) assistance, was performed using the B3LYP method and the 6-31+G(d) basis set for C, N, O, H, and Cl atoms and the relativistic effective core pseudopotential LANL2DZ complemented with one set of f polarization functions (zeta(f) = 0.473) for the Ag atom. The partial Ag(+)-assisted extrusion of Cl(-) at the rate-determining transition state provokes an important change in the nodal properties of the frontier molecular orbitals of the H(3)CClNCOHAg(+) fragment, thus making very stabilizing HOMO-LUMO interactions between this fragment and the C(2)H(4) moiety possible. This interaction leads to the ring opening and release of most of the strain energy, giving rise to a low energy barrier for the process. Also, by assisting the Cl(-) extrusion, Ag(+) avoids the elimination of the hydroxyl hydrogen atom, which would provoke the fragmentation of the system instead of the formation of the beta-lactam. 相似文献