Excitation functions for some output channels following the p +55Mn interaction atE p=1·3–2·0 MeV

Excitation functions for the⁵⁵Mn(p, p )⁵⁵Mn,⁵⁵Mn(p, n )⁵⁵Fe and⁵⁵Mn(p, )⁵⁶Fe reactions are studied for proton beam energyE _p=1·3–2 MeV. The excitation functions are established from yield functions for -rays emitted from the first excited states of final nuclei. Many resonances are observed and competition of their decay into all three output channels is analysed. Spin-parity assignment for some resonant states in the⁵⁶Fe compound nucleus is deduced.Participated partly in the course of his work on a Thesis.The authors wish to thank the staff of the Van de Graaff accelerator at Charles University in Prague for the efficient operation of the machine and dr. I. Wilhelm for the valuable technical help in the early period of the experimental work. One of us (N. A. N.) acknowledges the staff of the Dept. of Nuclear Physics of Charles University in Prague for the excellent working conditions.     

微波常压法合成水杨酸酯

在浓硫酸催化下，采用微波常压法由水杨酸分别与正丁醇、异丁醇、正戊醇和异戊醇反应合成相应的水杨酸酯。结果表明：当水杨酸：醇：Ｈ２ＳＯ４＝１：５．５：０．３（摩尔比）时，采用５６０Ｗ微波辐射２２ｍｉｎ，水杨酸酯的产率可达８８．７％￣９６．４％，反应速度至少是常规反应的１４倍。     

Investigation of a liquid-liquid extraction system based on non-ionic surfactant-salt-H2O and mechanism of drug extraction

Based on the investigation of a non-ionic surfactant-salt-H₂O liquid-liquid extraction system, general rules concerning salt selection are concluded and the mechanism of phase separation is explained. The extraction behavior of chlorpromazine hydrochloride (CPZ) and procaine hydrochloride (PCN) in such a system is studied. Research shows that the extraction efficiency of CPZ can amount to 96% by twice extraction, which means that quantitative extraction is realized, while that of PCN is 77%. This system produces distribution coefficients (K_D) of 12.3 and 2.6, respectively, for CPZ and PCN. Extraction mechanism is deduced according to ultraviolet absorbance; and molecular fluorescence spectra change of the drugs in the system studied.     

π键及大π键对正电集团和负电集团的作用——分子间引力的选择性

The selectivity of intermolecular force is caused by the special interaction between two adaptable groups on the molecules. π bond and conjugated π bonds such as benzene ring are negative charged groups,which may attract stongly positively charged H groups such as 3H in β-C_6H_6Cl_6, and repulse other ne- gatively charged groups such as-C=O(Q). Our experiments show that the reduced retention time tr of benzene on non- polar β-C_6H_6Cl_6 is much greater than that on polar fixed phases such as CH_3— —NO_2 in gas chromatography and that the het of solvation of β-C_6H_6Cl_6 in benzene is also much greater than that of the polar α-C_6H_6Cl_6 and γ-C_6H_6Cl_6. This can′t be explained by the usual Van de Waals′ force. It results from the selective intermoleccular force....     

希土Eu(Ⅲ)与2-丙酰-茚满二酮-1,3的二元、三元配合物的合成、表征及发光性能研究

合成2-丙酰-茚满二酮-1,3及其Eu(Ⅲ)的二元、三元固态配合物,经化学分析、元素分析确定了配合物的化学组成,通过红外光谱、紫外光谱进行表征,用配合物的荧光光谱和配体低温磷光光谱分析了配合物的荧光强度和能有效发光的原因.     

裂解色谱法研究PMR型聚酰亚胺前体的反应过程

用裂解气相色谱法研究ＰＭＲ型聚酰亚胺前体在反应中的化学变化过程，以裂解产物醇和环戊二烯的生成率表示酰胺化或酰亚胺化及交联的程度，结果表明，酰胺化或酰亚胺化在５０℃以下不发生，在１８０～２２０℃完成，降冰片烯端基在１５０℃以下不发生交联反应，在２８０℃，１０～１８小时可完成交联反应。     

Molecular Spectroscopic Study on the Interaction between Heparin and Neutral Red

The interaction between heparin and neutral red was investigated by molecular spectroscopic methods. The change of all spectra suggested that positively charged neutral red had interacted with negatively charged heparin. The study of influence factors indicated that electrostatic force and hydrophobic bond might be involved in the interaction. The total binding number per disaccharide unit and intrinsic binding constant were obtained using Scatchard model.     

Tunable magnetic arrangement of iron oxide nanoparticles in situ synthesized on the solid substrate from diblock copolymer micelles

Hexagonal arrangement of iron oxide nanoparticles was fabricated by utilizing a single-layered film of diblock copolymer micelles. The synthesis was directly performed on the solid substrate by oxygen plasma with preserving the dimensional order of micelles so that separate procedures for synthesis and deposition of nanoparticles were not necessary. Since the oxygen plasma treatment also eliminated polymers, pure patterns of iron oxide nanoparticles were obtained. Moreover, easy control over the size of nanoparticles enabled us to selectively create a ferrimagnetic or a superparamagnetic pattern of iron oxide nanoparticles without altering the fabrication process.