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71.
An experimental study was performed to measure the flow properties of a vertically-orientated shear layer in the vicinity of a free-surface. The effect of surface contamination on the near surface flow field was also determined. Digital Particle Image Velocimetry was used to measure instantaneous and averaged velocity, vorticity, and Reynolds stresses. Results show that the presence of surfactants can cause directional shifts of the shear layer, as well as an overall damping of the turbulence in the vicinity of the free-surface, except in the vicinity of a Reynolds ridge where an increase in Reynolds stress was observed. 相似文献
72.
73.
Kieran AL Bond AD Belenguer AM Sanders JK 《Chemical communications (Cambridge, England)》2003,(21):2674-2675
Disulfide-linked cyclic porphyrin oligomers from dimer to tetramer can be selected and amplified virtually quantitatively from a dynamic combinatorial library using bis-thiol substituted zinc(II) porphyrin units with appropriate amine donor templates. 相似文献
74.
Gamble BM Gallagher PA Shoemaker JA Parks AN Freeman DM Schwegel CA Creed JT 《The Analyst》2003,128(12):1458-1461
This paper evaluates the chemical stability of four arsenosugars using tetramethylammonium hydroxide (TMAOH) as an extraction solvent. This solvent was chosen because of the near quantitative removal of these arsenicals from difficult to extract seafood (oysters and shellfish). Four arsenosugars (3-[5'-deoxy-5'-(dimethylarsinoyl)-beta-ribofuranosyloxy]-2-hydroxypropylene glycol--As(328), 3-5'-deoxy-5'-(dimethylarsinoyl)-beta-ribofuranosyloxy]-2-hydroxypropanesulfonic acid--As(392), 3-[5'-deoxy-5'-(dimethylarsinoyl)-beta-ribofuranosyloxy]-2-hydroxypropyl hydrogen sulfate--As(408), and 3-[5'-deoxy-5'-(dimethylarsinoyl)-beta-ribofuranosyloxy]-2-hydroxypropyl-2,3-hydroxypropyl phosphate--As(482)) were evaluated. The stability of these four arsenosugars were studied independently in a solution of 2.5% TMAOH at 60 degrees C over a period of up to 8 h. Two arsenosugars, As(328) and As(392), were found to be relatively stable in this solution for up to 8 h. However, As(408) and As(482) formed detectable quantities of dimethylarsinic acid (DMAA) and As(328) within 0.5 and 2 h, respectively. It was found that 97% of As(408) degrades after 8 h of treatment producing 3.4 times as much DMAA as As(328). This is contrary to As(482), which produces 13 times as much As(328) as DMAA and only 37% of the As(482) was converted by the 8 h treatment at 60 degrees C. These degradation products led to the investigation of weaker TMAOH extraction solvents. Three different concentrations (2.5%, 0.83% and 0.25%) were used to determine the effect of TMAOH concentration on the degradation rate of As(408). By reducing the TMAOH concentration to 0.83%, the conversion of the arsenosugar to As(328) and DMAA is nearly eliminated (less than 5% loss). Arsenosugars, As(408) and As(482), were also studied in 253 mM NaOH to verify the degradation products. The NaOH experiments were conducted to investigate a possible hydroxide based reaction mechanism. Similar degradation plots were found for each arsenosugar when compared to the 2.5% TMAOH data. A mechanism has been proposed for the formation of As(328) from As(408) and As(482) in base via an SN2 reaction (hydroxide attack) at the side chain carbon adjacent to the inorganic ester. The formation of DMAA is observed in all arsenosugars after prolonged exposure. This probably occurs via an SN2 attack at the arsenic atom. 相似文献
75.
Yuan-Qing Qiao Franklin D. Tall 《Proceedings of the American Mathematical Society》2003,131(12):3929-3936
In this paper we prove the equivalence between the existence of perfectly normal, non-metrizable, non-archimedean spaces and the existence of ``generalized Souslin lines", i.e., linearly ordered spaces in which every collection of disjoint open intervals is -discrete, but which do not have a -discrete dense set. The key ingredient is the observation that every first countable linearly ordered space has a dense non-archimedean subspace.
76.
In this paper, we obtain a generalization of an identity due to Carlitz on Bernoulli polynomials. Then we use this generalized formula to derive two symmetric identities which reduce to some known identities on Bernoulli polynomials and Bernoulli numbers, including the Miki identity. 相似文献
77.
George D. Bachand Amy Allen Marlene Bachand Komandoor E. Achyuthan Jean Clare Seagrave Susan M. Brozik 《Journal of nanoparticle research》2012,14(10):1-10
This study explores the viability of rare earth-doped zirconia nanophosphors as probable candidates for white light emission. Undoped ZrO2 and single- and double-doped ZrO2:M (where M?=?Tb3+ and Eu3+) nanophosphors have been synthesized using a simple sonochemical process. The products were characterized using X-ray diffraction, scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), energy dispersive X-ray spectroscopy (EDS), and photoluminescence spectrophotometry. The SEM micrographs show that resultant nanoparticles have dendritic shape. TEM and HRTEM studies showed that the size of the majority of the nanoparticles were around 28?±?5?nm. Characteristic blue and green emission from Tb3+ ions and red from Eu3+ dopant ions were observed. The CIE coordinates of the double-doped ZrO2:Tb3+ (1.2?%):Eu3+ (0.8?%) nanophosphor lie in the white light region of the chromaticity diagram and show promise as good phosphor materials for new lighting devices. 相似文献
78.
A student laboratory exercise in qualitative analysis has been developed to address student misconceptions associated with electrolyte and nonelectrolyte solutions. This exercise uses a previously reported, inexpensive, home-built conductivity meter to identify acid solutions. An additional short preparatory exercise provides students the opportunity to classify known solutions as strong, weak, or nonelectrolytes and gives students experience using a conductivity meter. These activities have been used successfully with both high school and introductory college chemistry students. 相似文献
79.
We give a Newton type rational interpolation formula (Theorem 2.2). It contains as a special case the original Newton interpolation, as well as the interpolation formula of Liu, which allows to recover many important classical q-series identities. We show in particular that some bibasic identities are a consequence of our formula. 相似文献
80.