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361.
P. Parthasarathy P. Habisreuther N. Zarzalis 《Journal of Quantitative Spectroscopy & Radiative Transfer》2012,113(15):1961-1969
The radiative properties of reticulated porous inert media are computationally identified using the real three-dimensional structural data of porous media. The computational grids data are reconstructed from three-dimensional computer tomography scans and magnetic resonance image scans of different reticulated porous media. A ray tracing algorithm is used to track the rays inside the grid structure. Statistically large numbers of rays are traced for their path length and incident angle, which are used to find the probability based equivalent extinction coefficient and scattering phase function. The equivalent extinction coefficients are found for porous media with different porosities and pore densities. The dependency of specular and diffuse scattering phase functions on the porous structure and surface reflectance are also studied. 相似文献
362.
A. Abdul Ajees M. N. Ponnuswamy S. Parthasarathy C. A. M. A. Huq 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(7):824-826
In the structures of the title compounds, 6,7‐dihydrodibenzo[e,g]azulen‐8(5H)‐one, C18H14O, (I), and 12,13‐dihydrobenzo[e]napth[2,1‐g]azulen‐14(11H)‐one, C22H16O, (II), the azulene group is in a boat‐envelope conformation. The structures are stabilized by weak C—H?O interactions. 相似文献
363.
We show how to color the tiles in a heirarchical tiling system so that the resulting system is not only repetitive (i.e.,
has the local isomorphism property) but has prescribed color symmetries as well.
Received March 9, 1998, and in revised form August 3, 1998. 相似文献
364.
Deformations of associative algebras in which time is the deformation parameter are constructed using quantum stochastic flows in which the usual multiplicativity requirement is replaced by multiplicativity with respect to the deformed multiplication. The theory is restricted by a commutativity requirement on the structure maps of the flow, but examples which can be constructed in this way include the noncommutative torus and the Weyl–Moyal deformation. 相似文献
365.
Dr. Pawan Kumar V. B. Raja Mani Kandan Prabukumar Balakrishnan Dr. P. K. Sudhadevi Antharjanam Dr. Venkatakrishnan Parthasarathy 《Angewandte Chemie (International ed. in English)》2023,62(41):e202305005
Though the chemistry of resorcinarenes is half a century old, the conformationally-locked resorcinarene crowns are generally constructed using hydrogen bonds or covalent tethers. Often, covalent tethering involves extra post-macrocyclization steps involving upper-rim functionalities. We have leveraged the torsional and steric strains through α-substituents of the lower-rim C-alkyl chains and accomplished conformationally-rigid fluorescent m-cyclophane deep-crowns in a predetermined way. The strategy offers a pre-macrocyclization route conserving upper-rim functionalities, an aspect overlooked in resorcinarene chemistry. X-ray structural and computational analyses unveil the cause for conformational rigidity in m-cyclophanes due to α-branching in C-alkyls (linear vs. α-/β-branched). The conformationally-locked fluorescent deep-crown with a preorganized cavity captures hydrophobic spherical guest C60 in both solution and solid states specifically, when compared to conformationally-dynamic boats, enabling conformation-specific binding. 相似文献