Ru(II)-catalyzed C-H bond activation for the synthesis of substituted isoquinolinium salts from benzaldehydes, amines, and alkynes

An efficient method for the synthesis of substituted isoquinolinium salts from benzaldehydes, amines, and alkynes via ruthenium-catalyzed C-H bond activation and annulation in one pot is described.     

Synthesis and characterization of Li<Subscript>1-x</Subscript>Tb<Subscript>x</Subscript>NiPO<Subscript>4</Subscript> solid solution as cathode materials for lithium ion battery application

Modified Pechini-type polymerizable precursor method has been used to prepare nanosized Li_1-xTb_xNiPO₄ (x = 0, 0.03, 0.05, and 0.07) solid solutions to obtain homogeneous with controlled stoichiometry and smaller particle size. The reaction temperature was determined by thermogravimetric (TG/DTA) analysis. X-ray diffraction analysis reveals the formation of orthorhombic structure and the calculated crystallite sizes are found to be in the range of 75–89 nm. Morphological, compositional, and vibrational properties were performed by SEM, EDAX, and FTIR, respectively. Conductivity measurements were carried out at room temperature by AC impedance analysis. The Li_0.97Tb_0.03Ni_0.99PO₄ sample shows one order of higher conductivity than pure LiNiPO₄. Higher concentration of terbium samples such as Li_0.95Tb_0.05Ni_0.99PO₄ and Li_0.93Tb_0.07Ni_0.99PO₄ lead to decrease of conductivity. The frequency dependency of dielectric permittivity, dielectric loss, and electric modulus of Li_1-x Tb_xNiPO₄ solid solutions are studied. The frequency-dependent plot of modulus reveals that the conductivity relaxation is of non-Debye type.     

Electron and x-ray diffraction studies on Al86Fe14, Al82Fe18 and Al75Fe25 quasicrystals

Electron and x-ray diffraction experiments on the metlt-spun Al_100−x Fe _x (x=14, 18, 25) alloys are carried out. It is observed that all the melt-spun alloys possessing the quasi-crystalline phases have icosahedral point-group symmetry. The authors felicitate Prof. D S Kothari on his eightieth birthday and dedicate this paper to him on this occasion.     

On the exact bound of the Coulomb potential with respect to the Dirac operator

Summary The exact bound of the Coulomb potential with respect to the self adjoint Dirac operator is evaluated.     

Effect of correlations on nuclear muon capture

The process μ⁻+¹²C→¹²B+v _μ is studied using the modified Hartree Fock wavefunction obtained with the unitary-model-operator-approach starting from the realistic hardcore nucleon-nucleon interaction, with the aim of testing the wavefunctions and obtaining a numerical value for the induced pseudoscalar coupling constant (g _P ). These observables, namely, the partial capture rate to the¹²B(1⁺; g.s), its recoil nuclear polarisation and the total capture rate, which exhaust the available experimental data in the above process have been calculated and compared with the other theoretical and experimental results. As far as the partial capture rate is concerned the use of the unitary-model operator approach wave functions for¹²C withb=2.09 fm and Cohen-Kurath wave function for¹²B(1⁺; g.s) reduces the pure shell model capture rate by about 30%. The effect of strong configuration mixing in the ground state of¹²C in taken into account by introducing a scale factor ξ similar to the ‘amplitude reduction factor’ of Donnelly and Walecka. With this ξ the agreement with the experiment both for the partial capture rate and the beta decay ‘ft’ value is found to be satisfactory. The¹²B(1⁺; g.s) recoil polarisation is found to be insensitive to the use of the unitary-model-operator-approach wave functions. When compared with the experimental data, we obtaing _P =(14.9±1.9)g _A . The total capture rate is found to be sensitive to the use of the unitary-modeloperator-approach wave functions which contain the effect of nucleon-nucleon short range correlations and we obtain a satisfactory agreement with the experiment for¹⁶O and¹²C, thereby revealing the importance of the effect of such correlations in the total capture rate studies.     

Some general constructions of geodetic blocks

A general construction procedure for geodetic blocks, starting from an arbitrary geodetic block is given, which unifies and generalizes many of the known general procedures. The construction of geodetic blocks homeomorphic to a given one is also analysed and the problem of Bosák on the existence of such a graph for the Hoffman-Singleton graph is settled in the affirmative. A simple characterization theorem for geodetic blocks is given and the existence of geodetic blocks with given girth and diameter is investigated.     

Carbon-13 enrichment by IR laser chemistry of CHF3-Cl2

IR laser chemistry of CHF₃ is investigated in both neat form and in the presence of Cl₂ for carbon-13 enrichment. Infrared multiple-photon dissociation of CHF₃ is an order of magnitude more efficient in the scavenged system compared to the neat case. The photolysis of CHF₃/Cl₂ mixture results in two products, viz., CF₂Cl₂ and C₂F₄Cl₂ but with different enrichment factors. The parametric studies show that C₂F₄Cl₂ arises due to MPD of CF₂Cl₂ in secondary photolysis.