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41.
Aydin Tavman Naz M. Agh-Atabay Abdollah Neshat Fahrettin Gucin Basaran Dulger Durata Haciu 《Transition Metal Chemistry》2006,31(2):194-200
2-(5-H/methyl-1H-benzimidazol-2-yl)-4-bromo/nitro-phenol (HLx:X=1–4) ligands and their iron(III) nitrate complexes have been synthesized and characterized. In all of the complexes, the
ligands are bidentate, via one imine nitrogen atom and a phenolate oxygen atom. The coordination is completed with a bidentate nitrate anion, and a
water molecule. Elemental analysis, molar conductivity, magnetic susceptibility, FT-Raman, FT-IR (mid i.r., far i.r.), UV–visible
and as well as quantum chemical calculations performed with CACHE are in agreement with a 1:1 electrolyte structures that
are mononuclear, and distorted 5-coordinate square pyramidal. The antimicrobial activities of free ligands, their hydrochloride
salts and the complexes were evaluated using the disk diffusion method in dimethyl sulfoxide (DMSO) toward nine bacteria,
each with multiple, fresh clinical isolates, and the results are compared with those for penicillin-g, ampicillin, cefotaxime,
vancomycine, oflaxacin and tetracycline. Antifungal activities were reported for Kluyveromyces fragilis, Rhodotorula rubra, Candida albicans, Hanseniaspora Guilliermondii and Debaryomyces hansenii yeasts, each with multiple isolates, and the results were referenced against nystatin, ketaconazole and clotrimazole antifungal
agents. In most cases, the compounds tested showed broad-spectrum (Gram+ and Gram−) activities that were either more active or as potent as the references particularly as antifungal agents. 相似文献
42.
A quantitative analytical method using gas chromatography/mass spectrometry (GC/MS) to determine urinary concentrations of eight progesterones and corticosteroids has been developed. After enzymatic hydrolysis with beta-glucouronidase/arylsulfatase, urine samples were extracted by simple one-step solid-phase extraction. Obtained extracts were derivatized with a mixture of N-methyl-N-(trimethylsilyl)trifluoroacetamide/ammonium iodide/dithiothreitol and determined by GC/MS in selected ion monitoring mode to increase the sensitivity. d(4)-Cortisol and d(9)-progesterone were used as internal standards for two different steroid groups. The linear correlation coefficient was in the range of 0.9913 to 0.9998 and recoveries were over 80% for all compounds. Precision and accuracy were in the range of 0.9-18.1 and 84.1-118.7%, respectively. The limit of quantitation (LOQ) was 10 ng/mL for 11-deoxycorticosterone and 21-deoxycortisol and 5 ng/mL for all other analytes. The developed method was successfully applied on pelvic organ prolapsed patients (n = 10, age: 67.9 +/- 4.9) and post-menopausal (n = 10, age: 63.6 +/- 5.5) control women. Urinary levels of most progesterones and corticosteroids except 11-deoxycorticosterone decreased but only that of 17 alpha-hydroxyprogesterone significantly decreased in patients compared with the control groups. Thus, it is concluded that progesterones could be a factor in the pathogenesis of pelvic organ prolapse, and, among them, 17 alpha-hydroxyprogesterone could be a biomarker for pelvic organ prolapse. 相似文献
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Synthesis,Characterization, and Catalytic Activity of Heteroleptic Rhodium Complex for C–N Couplings
Zafar M. N. Perveen Fouzia Naz A. Mughal Ehsan Ullah Gul-e-Saba Hina K. 《Russian Journal of Coordination Chemistry》2019,45(1):62-73
Russian Journal of Coordination Chemistry - We have reported synthesis of complex [Rh(COD)(L{Me})Cl] (III), where L{Me} (II) is N-(1-methylpyridin-4(1H)-ylidene)benzamide and COD is... 相似文献
45.
Shama Naz Antonia Garcia Magdalena Rusak Coral Barbas 《Analytical and bioanalytical chemistry》2013,405(14):4849-4858
In the search for a noninvasive and reliable rapid screening method to detect biomarkers, a metabolomics fingerprinting approach was developed and applied to rat serum samples using capillary electrophoresis coupled to an electrospray ionization-time of flight-mass spectrometer (CE–TOF-MS). An ultrafiltration method was used for sample pretreatment. To evaluate performance the method was validated with carnitine, choline, ornithine, alanine, acetylcarnitine, betaine, and citrulline, covering the entire electropherogram of pool of rat serum. The linearity for all metabolites was >0.99, with good recovery and precision. Approximately 34 compounds were also confirmed in the pool of rat serum. The method was successfully applied to real serum samples from rats with ventilator-induced lung injury, an experimental rat model for acute lung injury (ALI), giving a total of 1163 molecular features. By use of univariate and multivariate statistics 18 significant compounds were found, of which five were confirmed. The involvement of arginase and nitric oxide synthase has been proved for other lung diseases, meaning the increase of asymmetric dimethyl arginine (ADMA) and ornithine and the decrease of arginine found were in accordance with published literature. Ultimately this fingerprinting approach offers the possibility of identifying biomarkers that could be regularly screened for as part of routine disease control. In this way it might be possible to prevent the development of ALI in patients in critical care units. Figure
A fingerprinting approach in serum using capillary electrophoresis and mass spectrometry 相似文献
46.
Rodríguez-Delgado A Cámpora J Naz AM Palma P Reyes ML 《Chemical communications (Cambridge, England)》2008,(41):5230-5232
Separation of a diiminopyridine iron(II) complex into its rac- and meso- diastereoisomers provides for first time the opportunity of observing the enantiomorphic site control competing with the chain-end control mechanism in a non-metallocene catalyst system. 相似文献
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Simple, isocratic and rapid RP‐HPLC method has been developed for the simultaneous analysis of gemifloxacin and H2‐receptor antagonists i.e. Cimetidine, Famotidine and Ranitidine, in bulk, pharmaceutical formulation and human serum. Separation was achieved on the RP‐Mediterranea column [C18 (250 × 4.6 mm, 5 μ)] at ambient temperature using mobile phase consisting of acetonitrile: methanol: water (20:28:52 v/v/v pH 2.8 adjusted by phosphoric acid). Flow rate was 1.0 mL/min with an average operating pressure of 180 kg/cm2. Gatifloxacin (GATI) was used as an internal standard (IS). Quantitation was achieved with UV detection at 221, 256 and 267 nm, respectively. Linear calibration curves, at concentration ranges of 0.05‐37.5 μgmL‐L with a correlation coefficient of ±0.9994. The detection and quantification limits were in the ranges of 0.023‐0.250 μgmL‐L and 0.071‐0.756 μgmL‐L, respectively. Friedman's and Student's t‐test were applied to correlate these results. Method was validated in terms of selectivity, linearity, precision, robustness, recovery, limits of detection and quantitation and is applicable to the routine analysis of GFX and H2‐receptor antagonists, alone or in combination. 相似文献
48.
Shahid Khan Durrani S. Naz M. Nadeem A. A. Khan 《Journal of Thermal Analysis and Calorimetry》2014,116(1):309-320
Nanocrystalline magnesium chromite spinel was synthesized through hydrothermal reaction of metal nitrate solutions in stoichiometric amount at different pH, temperature and time intervals. The synthesized products were characterized for crystallinity, phase identification, and surface morphology by X-ray diffraction (XRD) and scanning electron microscope (SEM). XRD patterns showed that as-synthesized product remained amorphous up to 250 °C. However, well-crystallized magnesium chromite spinel structure is formed after calcination at 850 °C. Rietveld refinement study confirms the formation of single-phase cubic structure MgCr2O4 with lattice parameter a = 8.3347 Å, and Fd3m space group. The as-processed MgCr2O4 products showed extensive XRD line broadening, and the mean crystallite size of such crystals was found to be mainly in size range of 85–124 nm. Surface SEM images of calcined specimens revealed that the matrix is uniform, and no separation of secondary phase was detected. Thermal stability was examined by thermogravimetry (TG), differential thermal analysis (DTA), and differential scanning calorimetry. TG/DTA reveals that MgCr2O4 is thermally stable above 700 °C. Fourier transform infrared (FTIR) spectra studies shows two strong bands, one around 600 cm?1 which is attributed to the intrinsic vibrations of tetrahedral and other at 400 cm?1 is due to octahedral one. FTIR confirms the formation of metal oxides. The bandgap energy was estimated by absorption spectroscopy in ultraviolet–visible range and was found to be 0.693 eV for MgCr2O4 specimen sintered at 1,000 °C. Isothermal shrinkage characteristic and coefficient of thermal expansion were determined by dilatometry. The powder specimens showed excellent densification at 1,250 °C temperature and uniformly fine grain sintered ceramics (>90 % relative density) with submicron grain size (2–5 μm) were obtained after sintering at 1,000–1,250 °C. Impedance studies were carried out at room temperature and equivalent circuit model (R 1 Q 1) (R 2 Q 2) (R 3 Q 3) is used to explain different relaxation processes. We report largest impedance values i.e., 6.74 × 108 Ω, reduced dielectric constant (≈1.0), and low tangent loss (0.8) for MgCr2O4 sintered at 1,250 °C. 相似文献
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Dr. Raheela Naz Prof. Qinglei Liu Dr. Waseem Abbas Dr. Muhammad Imtiaz Dr. Imran Zada Dr. Javed Ahmad Dr. Tengfei Li Prof. Jiajun Gu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(70):16054-16062
A new ternary composite of 1T-molybdenum disulfide, hexagonal tungsten trioxide, and reduced graphene oxide (M-W-rGO) is synthesized by using a one-pot hydrothermal process. The synergetic effect of 1T-MoS2 and hexa-WO3 nanoflowers improves the electrochemical performance for supercapacitors by inducing additional active sites and hexagonal tunnels, respectively, which lead to high storage capacity and easy transfer of electrolyte ions. The ternary M-W-rGO composite has a high specific capacitance of 836 F g−1 at 1 A g−1, which is nearly twice that of binary composites of M-rGO and W-rGO with high capacitance retention of 86.35 % after 3000 cycles at a high current density of 5 A g−1. This study provides a new ternary composite that can be used as an electrode material for high-performance supercapacitors. 相似文献