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排序方式: 共有214条查询结果,搜索用时 15 毫秒
41.
Angela LaBella Francesca Leonelli Ilse DeSalve LuisaM. Migneco Rinaldo MariniBettolo 《Helvetica chimica acta》2004,87(8):2120-2124
A new preparation and the isolation and spectroscopic characterization of 1,3,3‐trimethylbicyclo[2.2.2]octan‐2,6‐dione ( 3 ), a so far elusive key intermediate in the Liu–Ralitsch total synthesis of (+)‐norpatchoulenol ((+)‐ 1a ), is described. The preparation of 3 constitutes also a formal total synthesis of (±)‐iso‐norpatchoulenol ((±)‐ 1b ), since 3 is correlated to an intermediate in the Monti and co‐workers synthesis of (±)‐ 1b . 相似文献
42.
Amol Sasane 《Complex Analysis and Operator Theory》2009,3(1):323-330
Let E be a separable infinite-dimensional Hilbert space, and let denote the algebra of all functions that are holomorphic. If is a subalgebra of , then using an algebraic result of Corach and Larotonda, we derive that under some conditions, the Bass stable rank of is infinite. In particular, we deduce that the Bass (and hence topological stable ranks) of the Hardy algebra , the disk algebra and the Wiener algebra are all infinite.
Submitted: October 10, 2007., Revised: January 11, 2008., Accepted: January 12, 2007. 相似文献
43.
Amol Sasane 《Journal of Mathematical Analysis and Applications》2010,370(2):703-715
We prove an abstract Nyquist criterion in a general set up. As applications, we recover various versions of the Nyquist criterion, some of which are new. 相似文献
44.
We extend the ν-metric introduced by Vinnicombe in robust control theory for rational plants to the case of infinite-dimensional systems/classes of nonrational transfer functions. 相似文献
45.
Conformationally rigid aromatic amino acids as potential building blocks for abiotic foldamers 总被引:1,自引:0,他引:1
Ramesh VV Roy A Vijayadas KN Kendhale AM Prabhakaran P Gonnade R Puranik VG Sanjayan GJ 《Organic & biomolecular chemistry》2011,9(2):367-369
This communication describes the development of conformationally constrained unnatural aromatic amino acids, constructed on rigid backbone wherein the carboxyl and amino groups project in two dimensions (planes) on the aromatic framework. Such a feature offers the possibility of design and development of conformationally ordered synthetic oligomers with intriguing structural architectures distinct from those classically observed. Furthermore, such amino acids will have the potential to extend the conformational space available for foldamer design with diverse backbone conformation and structural architectures. 相似文献
46.
Siddiqui Madiha M. Nagargoje Amol A. Akolkar Satish V. Sangshetti Jaiprakash N. Khedkar Vijay M. Pisal Parshuram M. Shingate Bapurao B. 《Research on Chemical Intermediates》2022,48(3):1199-1225
Research on Chemical Intermediates - A simple and efficient protocol has been developed for the synthesis of new1,2,3-triazole-2,3-dihydroquinazolin-4[1H]-one (DHQ) conjugates(6a?j) via... 相似文献
47.
Chandrachood Pranav S. Jadhav Amol R. Garud Dinesh R. Deshpande Nirmala R. Puranik Vedavati G. Kashalkar Rajashree V. 《Research on Chemical Intermediates》2020,46(12):5219-5230
Research on Chemical Intermediates - A series of quinoxaline derivatives were efficiently synthesized by convenient and simple procedure in excellent yields using 1 wt.% of titanium silicate (TS-1)... 相似文献
48.
The objective of this research work was to investigate the kinetics of esterification of acetic acid with n-butanol through the variation of experimental parameters. The reaction mixture was catalyzed heterogeneously by a sulfonated catalyst in batch mode of operation. The catalyst was prepared from abundantly available agro-waste, Cajanus cajan husk by chemical activation process, which produces a carbon-based solid catalyst with high surface area. The catalyst was characterized by a Brunauer-Emmet-Teller surface analyzer and Fourier transform infrared spectroscopy to know the surface morphology. Process parameters such as contact time, reaction temperature, and catalyst loading, which can influence the extent of conversion of reactants, were studied. Furthermore, the kinetic investigation was also carried out to estimate the kinetic parameters for uncatalyzed and catalyzed reaction using the second-order pseudo-homogeneous (P-H), Eley-Rideal (E-R), and Langmuir-Hinshelwood (LH) kinetic models for this research work. The kinetic parameters such as activation energy, preexponential factor, and the thermodynamic parameters such as enthalpy and entropy were estimated for uncatalyzed and catalyzed reactions using these three models. The process conditions were optimized for catalyzed and uncatalyzed reactions to obtain the maximum product yield by minimizing root mean square error of each experimental data using the MS-excel solver tool. Thus, this study reveals the high potential of an agro-waste, Cajanus cajan husk as raw material for the synthesis of catalyst. The results show that the E-R model is more appropriate for predicting the dynamic data of an esterification reaction, as the forward rate of reaction estimated using the E-R model are more modified than P-H and L-H models. 相似文献
49.
Ikhlas Gadwal Prakash P. Wadgaonkar Amol B. Ichake Shivshankar R. Mane 《Journal of polymer science. Part A, Polymer chemistry》2019,57(2):146-156
A new approach was developed for synthesis of certain A3B3‐type of double hydrophilic or amphiphilic miktoarm star polymers using a combination of “grafting onto” and “grafting from” methods. To achieve the synthesis of desired miktoarm star polymers, acetyl protected poly(ethylene glycol) (PEG) thiols (Mn = 550 and 2000 g mol?1) were utilized to generate A3‐type of homoarm star polymers through an in situ protective group removal and a subsequent thiol–epoxy “click” reaction with a tris‐epoxide core viz. 1,1,1‐tris(4‐hydroxyphenyl)ethane triglycidyl ether. The secondary hydroxyl groups generated adjacent to the core upon the thiol–epoxy reaction were esterified with α‐bromoisobutyryl bromide to install atom transfer radical polymerization (ATRP) initiating sites. ATRP of N‐isopropylacrylamide (NIPAM) using the three‐arm star PEG polymer fitted with ATRP initiating sites adjacent to the core afforded A3B3‐type of double hydrophilic (PEG)3[poly(N‐isopropylacrylamide)] (PNIPAM)3 miktoarm star polymers. Furthermore, the generated hydroxyl groups were directly used as initiator for ring‐opening polymerization of ε‐caprolactone to prepare A3B3‐type of amphiphilic (PEG)3[poly(ε‐caprolactone)]3 miktoarm star polymers. The double hydrophilic (PEG)3(PNIPAM)3 miktoarm star polymers showed lower critical solution temperature around 34 °C. The preliminary transmission electron microscopy analysis indicated formation of self‐assembly of (PEG)3(PNIPAM)3 miktoarm star polymer in aqueous solution. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 146–156 相似文献
50.
We determine when a submodule is Willems with respect to thespace of distributions that are tempered in the spatial direction.
Received 14 October 2002. Accepted 9 February 2003. 相似文献