A rigid bicyclo[3.3.0]octane (octahydropentalene): a heavily constrained novel aliphatic template for molecular self-assembly

This Letter reports the utility of a heavily constrained cis-fused bicyclo[3.3.0]octane (octahydropentalene) aliphatic template for effecting molecular self-assembly. An attractive feature of this system is its heavily constrained alicyclic backbone that would allow for the exploration of self-assembling systems with conformationally ordered features.     

On the Krull Dimension of Rings of Transfer Functions

In this article, we prove that the Krull dimension of several commonly used classes of transfer functions of infinite dimensional linear control systems is infinite. On the other hand, we also show that the weak Krull dimension of the Hardy algebra , the disk algebra and the Wiener algebra is equal to 1. A. Sasane is supported by the Nuffield Grant NAL/32420.     

Actinides selective extractants coated magnetite nanoparticles for analytical applications

N,N,N′,N′-tetraoctyl diglycolamide (TODGA) and bis(2-ethylhexy)phosphoric acid (HDEHP) were coated on Fe₃O₄ nanoparticles under different chemical conditions. The TODGA-coated magnetite nanoparticles (Fe₃O₄@TODGA) captured representative actinides Am(III) and Pu(IV) at 3–4 M HNO₃ with high efficiency. However, the HNO₃ induced pre-organization of TODGA, before coating on the magnetite nanoparticles, was found to be important for the sorption of Am(III) and Pu(IV) ions. The Fe₃O₄@HDEHP particles exhibited selectivity toward Pu(IV), and Am(III) did not sorb from 3 to 4 M HNO₃. The quantification of Pu(IV) preconcentrated on coated particles was carried out by removing the extractant coating in dioxane based scintillator, followed by liquid scintillation counting.

     

Noncoherence of some rings of functions

Let , denote the unit disc and unit circle, respectively, in , with center 0. If , then let denote the set of complex-valued functions defined on that are analytic in , and continuous and bounded on . Then is a ring with pointwise addition and multiplication. We prove that if the intersection of with the set of limit points of is not empty, then the ring is not coherent.

     

Tolokonnikov’s Lemma for Real H ∞ and the Real Disc Algebra

We prove Tolokonnikov’s Lemma and the inner-outer factorization for the real Hardy space , the space of bounded holomorphic (possibly operator-valued) functions on the unit disc all of whose matrix-entries (with respect to fixed orthonormal bases) are functions having real Fourier coefficients, or equivalently, each matrix entry f satisfies for all z ∈ . Tolokonnikov’s Lemma for means that if f is left-invertible, then f can be completed to an isomorphism; that is, there exists an F, invertible in , such that F = [ f f _c ] for some f _c in . In control theory, Tolokonnikov’s Lemma implies that if a function has a right coprime factorization over , then it has a doubly coprime factorization in . We prove the lemma for the real disc algebra as well. In particular, and are Hermite rings. The work of the first author was supported by Magnus Ehrnrooth Foundation. Received: December 5, 2006. Revised: February 4, 2007.     

Synthesis,Characterization, and DGAT1 Inhibition of New 5‐Piperazinethiazole and 5‐Piperidinethiazole Analogs

In this study, a novel series of 5‐piperazinethiazole 2,2‐dimethylbutanoic acid and 5‐piperidinethiazole 2,2‐dimethylbutanoic acid derivatives have been synthesized. Structures of the newly synthesized compounds have been elucidated using ¹H‐NMR, ¹³C‐NMR, high‐resolution mass spectroscopy, and high‐performance liquid chromatographic analysis. The synthesized derivatives have been evaluated in vitro for their ability to inhibit the enzyme diacylglycerol acyltransferase 1 responsible for triglyceride biosynthesis.     

Size-controlled flow synthesis of gold nanoparticles using a segmented flow microfluidic platform

Segmented flow is often used in the synthesis of nanomaterials to achieve narrow particle size distribution. The narrowness of the distribution is commonly attributed to the reduced dispersion associated with segmented flows. On the basis of the analysis of flow fields and the resulting particle size distribution, we demonstrate that it is the slip velocity between the two fluids and internal mixing in the continuous-phase slugs that govern the nature of the particle size distribution. The reduction in the axial dispersion has less impact on particle growth and hence on the particle size distribution. Synthesis of gold nanoparticles from HAuCl(4) with rapid reduction by NaBH(4) serves as a model system. Rapid reduction yields gold nuclei, which grow by agglomeration, and it is controlled by the interaction of the nuclei with local flow. Thus, the difference in the physical properties of the two phases and the inlet flow rates ultimately control the particle growth. Hence, a careful choice of continuous and dispersed phases is necessary to control the nanoparticle size and size distribution.     

Study of arsenic (As) mobilization in the Ganga Alluvial Plain using neutron activation analysis

In northern part of Indian sub-continent, As related environmental and health issues receive attention from all over the world. Forty-eight sediment samples were collected from the Ganga Alluvial Plain (GAP) and its weathering products (from the Gomati River) for the study of As distribution and mobilization. These sediment samples were analyzed by Instrumental Neutron Activation Analysis (INAA) method using Cirus Research Reacter of Bhabha Atomic Research Centre, Mumbai. Average As concentrations in the GAP sediments (10.44?mg?kg^?1), the Gomati River bed sediments (1.36?mg?kg^?1) and the Gomati River suspended sediments (5.30?mg?kg^?1) were reported. Significant decrease of As content from the alluvial sediments to the river sediments is a clear indication of its mobilization by chemical weathering processes of mineral biotite. Present study demonstrates the importance of INAA for quantification and mobilization of As and improves our understanding related to As related environmental issues in northern India and elsewhere.     

Strength from weakness: opportunistic CH···O hydrogen bonds differentially dictate the conformational fate in solid and solution states

We show that the CH···O hydrogen bond can be opportunistic to differentially dictate the conformation of cyclitols in solution and solid states. While several intermolecular CH···O stabilize the chair-conformation in the solid, single intramolecular CH···O stabilizes an otherwise unfavorable boat-conformation in solutions analogous to the boat-conformation of cis-1,4-cyclohexanediols by OH···O bonds.