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21.
    
Strong control over experimental conditions in microfluidic channels provides a unique opportunity to study and optimize membraneless microbial fuel cells (MFCs), particularly with respect to the role of flow. However, improved performance and transferability of results to the wider MFC community require improvements to device stability under all applied operational conditions. To address these challenges, we present an easy-to-fabricate membraneless MFC that combines i) O2 protection via a gas diffusion barrier, ii) integrated graphite electrodes, and iii) optimized electrode placement to avoid cross-contamination under all applied flow rates. Attention to all of these design features in the same platform resulted in the operation of a MFC with a pure-culture anaerobic Geobacter sulfurreducens biofilm for half a year, that is, six times longer than previously reported, without the use of an oxygen scavenger. As a result of higher device stability under high flow rates, power densities were four times higher than reported previously for microfluidic MFCs with the same biofilm.  相似文献   
22.
    
Invited for this month's cover picture is the group of Jesse Greener at Laval University in Quebec City (Canada). The cover picture shows a real microfluidic microbial fuel cell (MFC) used in this study. Three graphical elements are superimposed to highlight critical design enhancements over previous literature examples. These include: i) improved anaerobic environment with an oxygen protection barrier, ii) robust and kinetically favorable graphite electrodes, and iii) reduced anolyte/catholyte cross-over to opposite electrodes via computer-optimized device architecture. Bringing these improvements together into the same platform, we demonstrate an opportunity to bridge the gap between the micro- and macro-MFC studies. Read the full text of the Article at 10.1002/celc.202000040 .  相似文献   
23.
    
Detection of relevant contaminants using screening approaches is a key issue to ensure food safety and respect for the regulatory limits established. Electrochemical sensors present several advantages such as rapidity; ease of use; possibility of on-site analysis and low cost. The lack of selectivity for electrochemical sensors working in complex samples as food may be overcome by coupling them with molecularly imprinted polymers (MIPs). MIPs are synthetic materials that mimic biological receptors and are produced by the polymerization of functional monomers in presence of a target analyte. This paper critically reviews and discusses the recent progress in MIP-based electrochemical sensors for food safety. A brief introduction on MIPs and electrochemical sensors is given; followed by a discussion of the recent achievements for various MIPs-based electrochemical sensors for food contaminants analysis. Both electropolymerization and chemical synthesis of MIP-based electrochemical sensing are discussed as well as the relevant applications of MIPs used in sample preparation and then coupled to electrochemical analysis. Future perspectives and challenges have been eventually given.  相似文献   
24.
Let T5 be the regular 5-tournament. B. Grünbaum proved that T5 is the only 5-tournament which contains no copy of the antidirected path P4. In this Note, we prove that, except for T5, any connected 5-chromatic oriented digraph in which each vertex has out-degree at least two contains a copy of P4. It will be shown, by an example, that the condition that each vertex has out-degree at least two is indispensable. To cite this article: A. El Sahili, C. R. Acad. Sci. Paris, Ser. I 339 (2004).  相似文献   
25.
A direct modeling of colloidal suspensions consists of calculating trajectories of all suspended objects. Due to the large time computing and the large cost involved in such calculations, we consider in this paper another route. Colloidal suspensions are described on a mesoscopic level by a distribution function whose time evolution is governed by a Fokker–Planck-like equation. The difficulty encountered on this route is the high dimensionality of the space in which the distribution function is defined. A novel strategy is used to solve numerically the Fokker–Planck equation circumventing the curse of dimensionality issue. Rheological and morphological predictions of the model that includes both direct and hydrodynamic interactions are presented in different flows.  相似文献   
26.
Olive oil is one of the most valued sources of fats in the Mediterranean diet. Its storage was generally done using glass or metallic packaging materials. Nowadays, plastic packaging has gained worldwide spread for the storage of olive oil. However, plastics are not inert and interaction phenomena may occur between packaging materials and olive oil. In this study, extra virgin olive oil samples were submitted to accelerated interaction conditions, in contact with polypropylene (PP) and polylactide (PLA) plastic packaging materials. 3D-front-face fluorescence spectroscopy, being a simple, fast and non destructive analytical technique, was used to study this interaction. Independent components analysis (ICA) was used to analyze raw 3D-front-face fluorescence spectra of olive oil. ICA was able to highlight a probable effect of a migration of substances with antioxidant activity. The signals extracted by ICA corresponded to natural olive oil fluorophores (tocopherols and polyphenols) as well as newly formed ones which were tentatively identified as fluorescent oxidation products. Based on the extracted fluorescent signals, olive oil in contact with plastics had slower aging rates in comparison with reference oils. Peroxide and free acidity values validated the results obtained by ICA, related to olive oil oxidation rates. Sorbed olive oil in plastic was also quantified given that this sorption could induce a swelling of the polymer thus promoting migration.  相似文献   
27.
Let B be an Archimedean reduced f-ring. A positive element \({\omega}\) in B is said to satisfy the property \({(\ast)}\) if for every f-ring A with identity e and every \({\ell}\)-group homomorphism \({\gamma : A \rightarrow B}\) with \({\gamma(e) = \omega}\), there exists a unique \({\ell}\)-ring homomorphism \({\rho: B \rightarrow B}\) such that \({\gamma = \omega \rho}\) and \({\rho(e)^{\perp \perp} = \omega^{\perp \perp}}\). Boulabiar and Hager proved that any (positive) von Neumann regular element in B satisfies the property \({(\ast)}\) and proved that the converse holds in the C(X)-case. In this regard, they asked about this converse in the general case. Our main purpose in this note is to prove, via a counter-example, that the converse in question fails in general. In addition, we shall take the opportunity to extend the direct result obtained by Boulabiar and Hager, and to get the C(X)-case we were talking about in an easier way.  相似文献   
28.
We consider a random walk in random scenery {Xn=η(S0)+?+η(Sn),nN}, where a centered walk {Sn,nN} is independent of the scenery {η(x),xZd}, consisting of symmetric i.i.d. with tail distribution P(η(x)>t)∼exp(−cαtα), with 1?α<d/2. We study the probability, when averaged over both randomness, that {Xn>ny} for y>0, and n large. In this note, we show that the large deviation estimate is of order exp(−ca(ny)), with a=α/(α+1).  相似文献   
29.
Periodica Mathematica Hungarica - We discuss the rational solutions of the Diophantine equations $$f(x)^2 \pm f(y)^2=z^2$$ . This problem can be solved either by the theory of elliptic curves or by...  相似文献   
30.
A series of cross-linked network polysiloxanes containing oligoethylene oxide units, (OCH2CH2)n, as internal free chains have been synthesized by performing hydrosilylation of partially PEO-substituted polysiloxane precursor with , ω-diallyl terminated poly(ethylene glycol). The polymer electrolytes were formed by complexing with LiN(CF3SO2)2 electrolyte salt and exhibited superior conductive property. The σRT of the network polymer electrolytes is in the range of 2.50×10−5 to 1.62×10−4 S/cm and depends on the cross-linking density (in terms of Si–H amount of the siloxane precursor), repeating unit number of internal oligoethylene oxide and chain length of the cross-linker. The significant enhancement of the conductivity was observed when low molecular weight dimethyl poly(ethylene glycol) was added as plasticizer. The temperature dependence of the ionic conductivity was also studied, following the Vogel–Tamman–Fulcher (VTF) equation.  相似文献   
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