Schiff base centered fluorescent organic compound 1,1′-[(1E,2E)-hydrazine-1,2-diylidenedi(E)methylylidene]- dinaphthalen-2-ol (HN) was synthesized followed by spectral characterization viz., NMR, IR and Mass spectroscopy. The fluorescent nanoparticles of HN prepared using reprecipitation method shows red shifted aggregation induced enhanced emission (AIEE) with respect to HN solution in acetone. The average particle size of nanoparticles (HNNPs) is of 67.2 nm shows sphere shape morphology. The surfactant cetyltrimethyl ammonium bromide (CTAB) used to stabilize HNNPs induces positive charge surface with zeta potential of 11.6 mV. The positive charge of HNNPs responsible to adsorb oppositely charged analyte on its surface with binding interactions. The fluorescence experiments performed with and without addition of different analytes to the aqueous suspension of HNNPs shows selective fluorescence quenching of HNNPs by D-Penicillamine (D-PA). The effect of other coexisting analytes does not affect the selective sensing behavior of D-PA. The mechanism of binding between HNNPs and D-PA was discussed on the basis of electrostatic interaction and adsorption phenomenon. The results interpreted by using DLS-Zeta sizer, Fluorescence lifetime measurements, conductometric titration supports the electrostatic adsorption between HNNPs and D-PA. The method has extremely low limit of detection (LOD) value 0.021 ppm is of significant as compared to reported methods. The proposed fluorescence quenching method was effectively used for quantitative estimation of D-PA from pharmaceutical medicine.
Graphical Abstract The fluorescence quenching based selective recognition of D-Penicillamine (D-PA) by using Schiff base centered fluorescent organic nanoparticles was developed and successfully applied to quantitative determination of D-PA from pharmaceutical samples viz. capsule and tablet.
The importance of hydrogen bonding in beta-peptide 3(14)-helices is demonstrated by an NMR analysis of three beta-heptadepsipeptides containing a 3-hydroxybutanoic residue in position 2, 4 or 6. 相似文献
The crystal structure of acetylcholine perchlorate has been determined from three-dimensional X-ray diffractometer data. The molecular geometry of this compound differs from that observed for acetylcholine bromide but is structurally similar to that observed for acetylcholine chloride. 相似文献
The effect of the inside profile of a hollow cathode on the intensity of plasma plume has been studied in a low-pressure (~3-torr) argon discharge. The effectiveness of three different `inside' profiles of a hollow cathode was compared by performing emission spectroscopy on the plasma plume in each case. A conical-profile hollow cathode produced a plasma plume that was much more intense than the one in a commonly used cylindrical-profile hollow cathode 相似文献
According to the open-shell CNDO/2 calculations on ClF2, performed by using the computer programme developed by Pople, Beveridge and Dobosh, the molecule is linear and stable, with equilibrium bond length 1.507Å and binding energy ?173.7 kcal/mole. The molecule has a tendency to dimerise and to disproportionate into ClF3 and ClF. The netd-orbital population in the monomer is 0.88. Bonding characteristics and other molecular properties are also discussed. 相似文献
A silver ion-selective electrode was prepared with a polymeric membrane incorporating 2,6-bis-methylsulfanyl-[1,3,5]thiadiazine-4-thione as an ionophore, tri-n-butylphosphate (TBP) as a plasticizer and sodium tetraphenylborate (NaTPB) as an additive. The electrode exhibited a near-Nernstian response of 52 mV/decade over a wide linear concentration range of 1.0 x 10(-5) - 1.0 x 10(-1) M with a lower detection limit of 9.77 x 10(-6) M. The electrode exhibited excellent selectivity for silver ion over many of the alkali, alkaline-earth and transition metal ions. The electrode worked well over a wide pH range of 1.77 - 7.13. The response time of the electrode was less than 20 s. The sensor can be applied as indicator electrode for the potentiometric titration of Ag+ ions with Cl- ions. 相似文献
The paramagnetic fluid composed of manganese chloride tetrahydrate dissolved in water was used to form bridges held between two parallel collinear rods. Magnetic levitation was used to control the effective gravity felt by the bridges. Their stability was studied as a function of Bond number and volume of the supported liquid. Data are compared with theoretical predictions for liquid bridges as well as with experimental results, where available. Copyright 1999 Academic Press. 相似文献
An inclusive study towards the stereospecific synthesis of novel cis-3-monosubstituted-β-lactams from cis-3-functionalized 3-phenylsulfonyl/sulfinyl-β-lactams is described. 3-Sulfinyl-β-lactams 5/5? successfully furnished stereospecific cis-3-monosubstituted-β-lactams 6, however 3-sulfonyl-β-lactams 2 failed to give the desulfurized product 6?. The final stereochemical and structural conformations of novel β-lactams were established by single crystal X-ray crystallographic study (5c). The cis configuration of the β-lactams 5/5? and 6 was assigned in relevance to E and C4-H and C3-H and C4-H respectively. 相似文献
Jiang et al. proposed an algorithm to solve the inverse minimum cost flow problems under the bottleneck-type weighted Hamming distance [Y. Jiang, L. Liu, B. Wuc, E. Yao, Inverse minimum cost flow problems under the weighted Hamming distance, European Journal of Operational Research 207 (2010) 50–54]. In this note, it is shown that their proposed algorithm does not solve correctly the inverse problem in the general case due to some incorrect results in that article. Then, a new algorithm is proposed to solve the inverse problem in strongly polynomial time. The algorithm uses the linear search technique and solves a shortest path problem in each iteration. 相似文献