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101.
Llabrés i Xamena FX Teruel L Alvaro M Garcia H 《Chemistry (Weinheim an der Bergstrasse, Germany)》2007,13(2):515-519
We have used porous anodised Al(2)O(3) membranes as inert matrix for constructing and organizing spatially ternary donor/conductor/acceptor (DCA) systems exhibiting photovoltaic cell activity on the micrometric-length scale. These DCA triads were built stepwise by first growing a conducting polymer inside the membrane pores, thus forming nanorods that completely fill the internal pore space of the membrane. Then, an electron donor and an electron acceptor were adsorbed one on each side of the membrane, so that they were separated by a distance equal to the membrane thickness (ca. 60 microm), but electronically connected through the conductive polymer. When this device was placed between two electrodes and irradiated with visible light, electrons jumped from the donor molecule, crossed the membrane from side to side through the conductive polymer (a journey of about 60 microm!) until they finally reach the acceptor molecule. In so doing, an electric voltage was generated between the two electrodes, capable of maintaining an electric current flow from the membrane to an external circuit. Our DCA device constitutes the proof of a novel concept of photovoltaic cells, since it is based on the spatial organization at the micrometric scale of complementary, but not covalently linked, electron-donor and electron-acceptor organic species. Thus, our cell is based in translating photoinduced electron transfer between donors and acceptors, which is known to occur at the molecular nanometric scale, to the micrometric range in a spatially organised system. In addition our cell does not need the use of liquid electrolytes in order to operate, which is one of the main drawbacks in dye-sensitised solar cells. 相似文献
102.
103.
Francis Leonard Deepak Alvaro Mayoral Miguel Jose Yacaman 《Applied Physics A: Materials Science & Processing》2009,96(4):861-867
The structural transformation of MoO3 nanobelts into MoS2 nanotubes using a simple sulfur source has been reported. This transformation has been extensively investigated using electron
microscopic and spectroscopic techniques including scanning electron microscopy (SEM), transmission electron microscopy (TEM),
high-resolution transmission electron microscopy (HRTEM), electron diffraction (ED), and energy-dispersive X-ray analysis
(SEM-EDAX and TEM-EDX). The method described in this report will serve as a generic route for the transformation of other
oxide nanostructures into the chalcogenide nanostructures. 相似文献
104.
John Hurtado Alvaro Muñoz-Castro Raúl Quijada René Rojas Mauricio Valderrama 《Journal of organometallic chemistry》2009,694(16):2636-223
Reactions of 2,6-bis(bromomethyl)pyridine with 3,5-dimethylpyrazole and 1H-indazole yield the terdentate ligands 2,6-bis(3,5-dimethylpyrazol-1-ylmethyl)pyridine (5) and 2,6-bis(indazol-2-ylmethyl)pyridine (6). The molecular structure of the new compound 6 was determined by single-crystal X-ray diffraction. These ligands react with the CrCl3(THF)3 complex in THF to form neutral complexes of general formula [CrCl3{2,6-bis(azolylmethyl)pyridine-N,N,N}] (7, 8) which are isolated in high yields as stable green solids and characterized by means of elemental analysis, magnetic moments, IR, and mass spectroscopy. Theoretical calculations predict that the thermodynamically preferred structure of the complexes is the fac configuration. After reaction with methylaluminoxane (MAO) the chromium(III) complexes are active in the polymerization of ethylene. 相似文献
105.
Theoretical calculations have been used to examine singlet oxygen release from a naphthalene endoperoxide which bears a flexible
(CH2)22 polymethylene “lid”. Monte Carlo and ONIOM calculations that incorporated semi-empirical and density functional theory predicted
the conformational influence of the polymethylene chain in the cycloreversion of dioxapaddlane, 1,4-diicosa naphthalene-1,4-endoperoxide,
to 1O2 and 1,4-diicosa naphthalene. This study attempts to build a connection between 1O2 generation and “jump rope” dynamics of the dioxapaddlane. The polymethylene chain appears to function as a gatekeeper for
the oxygen. Instead of coming full circle, a semi-circle rotation of the polymethylene bridge protected the peroxide group,
limiting the dissociation of 1O2 from the naphthalene site.
Dedicated to István Hargittai for his first twenty years at Structural Chemistry. 相似文献
106.
Let (M,ω) be a symplectic 4-manifold. A semitoric integrable system on (M,ω) is a pair of smooth functions J,H∈C ∞(M,ℝ) for which J generates a Hamiltonian S
1-action and the Poisson brackets {J,H} vanish. We shall introduce new global symplectic invariants for these systems; some of these invariants encode topological
or geometric aspects, while others encode analytical information about the singularities and how they stand with respect to
the system. Our goal is to prove that a semitoric system is completely determined by the invariants we introduce.
A. Pelayo was partially supported by an NSF Postdoctoral Fellowship. 相似文献
107.
In this paper, we give examples of elliptic curves E/K overa number field K satisfying the property that there exist P1,P2 K[t] such that the twists and are of positiverank over K(t). As a consequence of this result on twists, weshow that for those elliptic curves E/K, and for each , the rank of E over the fixed field (Kab) under is infinite, where Kab is the maximal abelian extension ofK. 相似文献
108.
Alvaro M Atienzar P de la Cruz P Delgado JL Troiani V Garcia H Langa F Palkar A Echegoyen L 《Journal of the American Chemical Society》2006,128(20):6626-6635
A soluble, functionalized Py-SWNT has been synthesized and characterized by solution (1)H and (13)C NMR, FT-Raman, and electron microscopy. Experimental data indicate that Py-SWNT has short tubes with pentyl esters at the tips and pyridyl isoxazolino units along the walls. The synthesis of Py-SWNT is based on a 1,3-dipolar cycloaddition of a nitrile oxide on the SWNT walls, similar to 1,3-dipolar cycloadditions that are common for fullerene functionalization. The resulting Py-SWNT forms a complex with a zinc porphyrin (ZnPor) in a way similar to that reported for pyridyl-functionalized [60]-fullerenes. Formation of this metal-ligand complex was firmly established by a detailed electrochemical study. However, in contrast to the behavior observed for the ZnPor/Py-C(60) complex, photochemical excitation of the complex between ZnPor/Py-SWNT does not lead to electron transfer with the generation of charge-separated states. Fluorescence and laser flash studies indicate that the main process is energy transfer from the singlet ZnPor excited state to the Py-SWNT with observation of emission from Py-SWNT. Triplet ZnPor excited-state quenching by Py-SWNT is only observed in polar solvents such as DMF, but not in benzonitrile. 相似文献
109.
The compound Ru(bpy)2(dppz-R)(PF6)2, where bpy is 2,2'-bipyridine and dppz-R is 11-(diethoxyphosphorylmethyl)dipyrido[3,2-a:2',3'-c]phenazine, was prepared and anchored to mesoporous nanocrystalline (anatase) TiO2 thin films as a probe of the effects of interfacial water on excited-state charge transfer processes at semiconductor interfaces. In nitrogen-saturated fluid acetonitrile, the Ru(bpy)2(dppz-R)(PF6)2 compound was found to be highly photoluminescent. Water was found to quench the excited state by a mechanism adequately described by the Perrin model, from which the radius of quenching was abstracted, 75 +/- 2 A. The Ru(bpy)2(dppz-R)(PF6)2 compounds were found to bind to the TiO2 thin films in high surface coverages, 5 x 10(-8) mol cm(-2). When these films were immersed in acetonitrile, long-lived excited states (tau = 825 ns) that were quenched by the addition of water were observed. About 30% of the excited states could not be quenched by water. Efficient electron injection, phi(inj) = 0.8, was observed after light excitation of Ru(bpy)2(dppz-R)/TiO2 in a 0.1 M LiClO4/acetonitrile solution. The addition of large concentrations of water, >0.5 M, was found to decrease the injection yield to phi(inj) = 0.3. 相似文献
110.
Automated microcolumn-switching system for drug analysis by direct injection of human plasma 总被引:1,自引:0,他引:1
Neto AJ Rodrigues JC Fernandes C Titato GM Alves C Lanças FM 《Journal of chromatography. A》2006,1105(1-2):71-76
This study presents the application of a system that joins the known advantages of capillary liquid chromatography (e.g., higher concentration of the analytes and lower consumption of mobile phase) with those of column-switching using restricted access material (RAM) (sample clean up and extraction) to the analysis of fluoxetine in plasma samples. Automatically, the system loads the biological sample, while a RAM-BSA-C18 column (50 mm x 520 microm) excludes the macromolecules and focuses the analytes; afterwards, a second mobile phase elutes the analytes, in backflush mode, and provides the separation in a C18 analytical column (100 mm x 520 microm). We optimized the procedure for a total analysis time of 25 min. Using this approach the calibration curve shows r=0.998 with a linearity range from 20 to 500 ng ml(-1). Precision, calculated as relative standard deviation (RSD), was<20%. The developed miniaturized system showed to be adequate and attractive, demonstrating a large potential for sample preparation. 相似文献