Performance of ferrite fillers on electrical behavior of polymer nanocomposite electrolyte

Dispersal of nanofillers in polymer electrolytes have shown to improve the ionic properties of Polyethylene oxide (PEO)-based polymer electrolytes in recent times. The effects of different nanoferrite fillers (i.e., Al–Zn ferrite, Mg–Zn ferrite, and Zn ferrite) on the electrical transport properties have been studied here on the composite polymer electrolyte system. The interaction of salt/filler with electrolyte has been investigated by XRD studies. SEM image and infrared spectral studies give an indication of nanocomposite formation. In conductivity studies, all electrolyte systems are seen to follow universal power law. Composition dependence (with ferrite filler) gives the maximum conductivity in [93PEO–7NH₄SCN]: X ferrite (where X?=?2% in Al–Zn ferrite, 1% Mg–Zn ferrite, and 1% Zn ferrite) system.     

Sensing mechanism of Pd-doped SnO2 sensor for LPG detection

In the present work, studies have been made to analyze the sensitivity, response, recovery time and sensing mechanism of Pd-doped thick film SnO₂ sensor for detection of LPG. To achieve this, thick film Pd-doped (0.25 and 1% by weight in available Indium doped SnO₂ thick film paste supplied by ESL, USA) along with an undoped (Indium doped) SnO₂ sensors were fabricated on a 1″ × 1″ alumina substrate. It consists of a gas sensitive layer (doped SnO₂), a pair of electrodes underneath the gas sensing layer serving as a contact pad for sensor. Also, a heater element on the backside of the substrate was printed for generating appropriate operating temperature at the substrate necessary for acquiring gas sensing properties. The sensor doped with 1% palladium showed the maximum sensitivity of 72% at 350 °C for 0.5% concentration of LPG. Possible detailed sensing mechanism of Pd-doped SnO₂ sensor for LPG detection has been proposed.     

Pd gate MOS sensor for hydrogen detection

The performance of Pd gate MOS hydrogen sensor was studied using C–V and G–V characteristics. The device was fabricated on p-type <100> (1–6Ω cm.) silicon with thermal oxide layer of about 100 Å. The C–V and G–V responses of sensor were measured at different frequencies (1 kHz, 10 kHz, and 100 kHz) upon exposure to hydrogen (conc. 1–8%) at room temperature. It was observed that value of zero bias capacitance decreases with increase in frequency as well as hydrogen concentration. The inversion potential (V_inv.) and flat band voltage (V_FB) of the device approach higher values as frequency is reduced. Interface trap density (N_it) was also determined corresponding to the peak in the conductance curve, using a bias scan conductance method at fixed frequency. N_it was found to be decreasing with increasing concentrations of hydrogen. The sensor showed better sensitivity at lower frequency.     

Neutron production in extended Cu-target irradiated with relativistic C-ions at Dubna, as studied with SSNTD and nuclear chemistry

An extended Cu-target was irradiated with 22 and 44 GeV carbon ions. The target was in contact with a (CH₂)_n-block for the moderation of secondary neutrons. Small holes in the moderator were filled with either lanthanium salts or uranium oxide. The reaction ¹³⁹La (n,γ) ¹⁴⁰La was studied via the decay of ¹⁴⁰La (40 h), and the reaction ²³⁸U (n, γ) ²³⁹U ²³⁹Np was studied via the decay of ²³⁹Np (2.3 d). In addition, a variety of solid state nuclear track detectors (SSNTD) were used. Results will be presented. The yields for the formation of (n, γ) products agree essentially with other experiments on extended targets carried out at the Synchrophasotron LHE, JINR (Dubna). To a first approximation, the breeding rate of (n, γ) products, as well as the specific track density, seen with several SSNTDs, doubles when the carbon energy is increased from 22 to 44 GeV. If, however, results at 44 GeV are compared in detail to those at 22 GeV, we observe an excess of (37 ± 9) % in the experimentally observed ²³⁹Np-breeding rate over theoretical estimations. Experiments using solid state nuclear track detectors are giving similar results. We also observed in the past such excess in the yield of other secondary particles in relativistic heavy ion interactions above a total energy of approximately 35–40 GeV.     

Streaming instability of a dusty plasma in the presence of mass and charge variation

We study the effect of the mass and charge dynamics on the collective behaviour of a dusty plasma. It is shown that the finite non-zero streaming velocity of the dust grains leads to a novel coupling of the dust mass fluctuation with other dynamic variables of the plasma and the grains. The mass fluctuations causes a collisionless dissipation and provides an alternate channel for the beam mode instability to occur. Physically the negative energy wave associated with the beam mode couples to the mass fluctuation induced dissipative medium to produce the instability. We conclude that the higher value of the ion mass density to the dust mass density ratio reduces the threshold value for the onset of the instability. Its application in the astrophysical context is discussed.     

Density dependence of solar emission lines of carbon-like ions

Steady state level population of 15 levels of carbon-like ions: NeV, MgVII, SiIX, and SXI have been computed as a function of electron density and temperature taking into account collisional processes and spontaneous radiative ones. Photo-excitation among the ground term levels has also been considered. Knowing the level density, line intensities have been computed as a function of electron density and temperature. This study indicates that line intensity ratios for carbon-like ions can be used as a diagnostic in the determination of these two parameters of the solar plasma. The resulting line fluxes from these ions at earth distance are compared with observation. Presented at the 5th Annual Radio and Space Sciences Symposium, National Physical Laboratory New Delhi, January 1979.     

Triple and quadruple integral equations occurring in diffraction theory

A formal scheme has been set up to solve the triple and quadruple integral equations of certain type which occur in diffraction theory. The operational theory has been employed in the analysis and equations have been reduced to the solution of simultaneous Fredholm equations.     

2,4-Dithiouracil as Complexing Agent. III

Pd(0), Rh(I), Rh(II), and Ru(II) complexes of 2,4-dithiouracil have been prepared. The structures of the complexes have been postulated on the basis of chemical analyses, infrared, visible spectral and magnetic susceptibility data.     

Study of the Stimulated Brillouin Scattering in a Dissipative Two-Ion Species Plasma

Analytical study of the stimulated Brillouin scattering in a two-ion species plasma has been done using the hydrodynamical model. When strong nonlinear effect becomes significant i.e., when the quiver velocity of the electron becomes of the order of or greater than its thermal velocity, the damping becomes intensity dependent which modifies the results over the weak nonlinearity. In this regime the plasma behaves as a collisionless medium. The inclusion of the second species of the ions modifies the instability and decreases the growth rate. Its application in fusion plasma has been discussed.