全文获取类型
收费全文 | 748篇 |
免费 | 50篇 |
国内免费 | 1篇 |
专业分类
化学 | 563篇 |
晶体学 | 6篇 |
力学 | 17篇 |
数学 | 55篇 |
物理学 | 158篇 |
出版年
2023年 | 7篇 |
2022年 | 13篇 |
2021年 | 20篇 |
2020年 | 27篇 |
2019年 | 24篇 |
2018年 | 24篇 |
2017年 | 24篇 |
2016年 | 35篇 |
2015年 | 24篇 |
2014年 | 31篇 |
2013年 | 77篇 |
2012年 | 56篇 |
2011年 | 61篇 |
2010年 | 28篇 |
2009年 | 26篇 |
2008年 | 44篇 |
2007年 | 46篇 |
2006年 | 42篇 |
2005年 | 28篇 |
2004年 | 15篇 |
2003年 | 17篇 |
2002年 | 23篇 |
2001年 | 7篇 |
2000年 | 5篇 |
1999年 | 5篇 |
1998年 | 4篇 |
1997年 | 6篇 |
1996年 | 3篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1993年 | 7篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1989年 | 4篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 6篇 |
1983年 | 5篇 |
1982年 | 7篇 |
1981年 | 9篇 |
1980年 | 3篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1972年 | 2篇 |
1970年 | 1篇 |
1965年 | 1篇 |
排序方式: 共有799条查询结果,搜索用时 0 毫秒
21.
M K Parida Nita Sinha B Adhikary B Allanach A Alok K S Babu B Brahmachari D Choudhury E J Chun P K Das A Ghosal D Hitlin W S Hou S Kumar H N Li E Ma S K Majee G Majumdar B Mishra G Mohanty S Nandi H Pas M K Parida S D Rindani J P Saha N Sahu Y Sakai S Sen C Sharma C D Sharma S Shalgar N N Singh S Uma Sankar N Sinha R Sinha F Simonetto R Srikanth R Vaidya 《Pramana》2006,67(5):849-860
This is the report of flavor physics and model building working group at WHEPP-9. While activites in flavor physics have been
mainly focused on B-physics, those in model building have been primarily devoted to neutrino physics. We present summary of working group discussions
carried out during the workshop in the above fields, and also briefly review the progress made in some projects subsequently. 相似文献
22.
A simple electrochemical process has been implemented to fabricated fractal structured leaf-like metallic zinc. The fabricated material was structurally characterized using X-ray diffraction that reveals the hexagonal unit cell structure. Also the growth of the structure is anisotropic. Field emission scanning electron microscopic images revealed clearly the leaf-like morphology of the fabricated material is fern like and ∼500 μm in length, ∼50-60 μm wide and the platelets thickness is ∼5 μm. The growth of this structure is diffusion controlled and locally accomplished with the oriented attachment. Raman shift measurement revealed the existence of surface optical phonon modes which is very significant for surface defects. 相似文献
23.
We consider the arrival time distribution defined through the quantum probability current for a Gaussian wave packet representing
free particles in quantum mechanics in order to explore the issue of the classical limit of arrival time. We formulate the
classical analogue of the arrival time distribution for an ensemble of free particles represented by a phase space distribution
function evolving under the classical Liouville's equation. The classical probability current so constructed matches with
the quantum probability current in the limit of minimum uncertainty. Further, it is possible to show in general that smooth
transitions from the quantum mechanical probability current and the mean arrival time to their respective classical values
are obtained in the limit of large mass of the particles. 相似文献
24.
Tania Chowdhury Kaushik Bera Debabrata Samanta Sandip Dolui Suvendu Maity Nakul C. Maiti Prasanta Kumar Ghosh Debasis Das 《应用有机金属化学》2020,34(4):e5556
Four new zinc (II) complexes [Zn (HL1H)Br2] (1), [Zn (HL1H)Cl2] (2), [Zn2(HL2)Br3] (3), and [Zn (HL2)Cl] (4) have been synthesized by adopting template synthetic strategy and utilizing two homologous Schiff base ligands (H2L1 = 4-bromo-2-{[2-(2-hydroxyethylamino)-ethylimino]-methyl}-6-methoxyphenol, H2L2 = 4-bromo-2-{[3-(2-hydroxyethylamino)propylimino]methyl}-6-methoxyphenol), differing in one -CH2- unit in the ligating backbone, by adopting template synthetic strategy. All the complexes have been characterized by single crystal X-ray diffraction analysis as well as by other routine physicochemical techniques. Ligand mediated structural variations have been observed and rationalized by density functional theoretical (DFT) calculations. Interaction of the complexes 1–4 with Bovine Serum Albumin protein (BSA) has been studied by different spectroscopic techniques. A complete thermodynamic profile (ΔHo, ΔSo and ΔGo) was evaluated initially from the change in absorption and fluorescence spectra upon addition of BSA to the complexes. Appreciable binding constant values in the range ~ 0.94–4.51 × 104 M−1 indicate efficient binding tendency of the complexes to BSA with the sequence 1 ≅ 2 > 3 ≅ 4. Circular dichroism (CD), isothermal calorimetric titration experiments, molecular docking and molecular dynamics have been performed to gain deep insight into the binding regions of complex 1 to BSA. Experimental evidences suggest an interaction of zinc complexes at the surface of BSA protein and this particular binding has been exploited to determine unknown concentration of BSA protein. For this purpose complex 1 was explored as a BSA protein quantification tool. 相似文献
25.
4-Aminophthalimide Derivatives as Environment-Sensitive Probes 总被引:2,自引:0,他引:2
The potential of 4-aminophthalimide (AP) and its derivatives as fluorescence probes for organized media is highlighted. The fluorescence response of AP, as measured from the position of the fluorescence maximum, fluorescence intensity and lifetime, is highly sensitive to the polarity of the medium. The sensitivity of the fluorescence parameters is further enhanced due to the involvement of the emitting intramolecular charge transfer state in hydrogen bonding interaction with the solvent molecules containing hydroxyl groups. It is shown that the microheterogeneous environments of organized media such as cyclodextrins and micelles can be very conveniently monitored using this probe. The results of the investigations carried out employing AP and its derivatives as fluorescence probe molecules in these media clearly suggest that a combination of the hydrophobic interaction with the host media and hydrogen bonding interaction with the solvent molecules determine the location of the fluorophore, which in all cases is found to be the interfacial region separating the nonpolar core of the micelle or the cyclodextrin cavity and the polar aqueous environment. Guidelines for the design of probes of this class of systems for the nonpolar core region of the micelles are provided and possible ways to increase the sensitivity of the fluorescence response of the systems are suggested. 相似文献
26.
Jyoti Bhawan Singh Shakti Pratap Gupta Mohit Tripathi Sudhanshu Verma Alok Kumar Singh Devraj Yadav R. R. 《Acoustical Physics》2021,67(6):584-589
Acoustical Physics - We have estimated elastic, mechanical, thermal and ultrasonic properties, in high temperature regime, of cobalt nanowires (Co-NWs) having a hexagonal close-packed (HCP)... 相似文献
27.
The new class of higher dimensional cosmological model of the early universe filled with perfect fluid source in the framework of f(R,T) theory of gravity (Harko et al. in Phys. Rev. D 84, 024020, 2011) is considered. A cosmological model with an appropriate choice of the function f(T) has been constructed. The physical behavior of the model is studied. The well known astrophysical phenomena, namely the Hubble parameter H(z), luminosity distance (d L ) and distance modulus μ(z) with redshift are discussed. 相似文献
28.
29.
Igor Dubenko Tapas Samanta Arjun Kumar Pathak Alexandr Kazakov Valerii Prudnikov Shane Stadler Alexander Granovsky Arcady Zhukov Naushad Ali 《Journal of magnetism and magnetic materials》2012
The studies of magnetocaloric properties, phase transitions, and phenomena related to magnetic heterogeneity in the vicinity of the martensitic transition (MT) in Ni–Mn–In and Ni–Mn–Ga off-stoichiometric Heusler alloys are summarized. The crystal structure, magnetocaloric effect (MCE), and magnetotransport properties were studied for the following alloys: Ni50Mn50−xInx, Ni50−xCoxMn35In15, Ni50Mn35−xCoxIn15, Ni50Mn35In14Z (Z=Al, Ge), Ni50Mn35In15−xSix, Ni50−xCoxMn25+yGa25−y, and Ni50–xCoxMn32−yFeyGa18. It was found that the magnetic entropy change, ΔS, associated with the inverse MCE in the vicinity of the temperature of the magneto-structural transition, TM, persists in a range of (125-5) J/(kg K) for a magnetic field change ΔH=5 T. The corresponding temperature varies with composition from 143 to 400 K. The MT in Ni50Mn50−xInx (x=13.5) results in a transition between two paramagnetic states. Associated with the paramagnetic austenite-paramagnetic martensite transition ΔS=24 J/(kg K) was detected for ΔH=5 T at T=350 K. The variation in composition of Ni2MnGa can drastically change the magnetic state of the martensitic phase below and in the vicinity of TM. The presence of the martensitic phase with magnetic moment much smaller than that in the austenitic phase above TM leads to the large inverse MCE in the Ni42Co8Mn32−yFeyGa18 system. The adiabatic change of temperature (ΔTad) in the vicinity of TC and TM of Ni50Mn35In15 and Ni50Mn35In14Z (Z=Al, Ge) was found to be ΔTad=−2 K and 2 K for ΔH=1.8 T, respectively. It was observed that |ΔTad|≈1 K for ΔH=1 T for both types of transitions. The results on resistivity, magnetoresistance, Hall resistivity in some In-based alloys are discussed. 相似文献
30.
This paper addresses two versions of a lifetime maximization problem for target coverage with wireless directional sensor networks. The sensors used in these networks have a maximum sensing range and a limited sensing angle. In the first problem version, predefined sensing directions are assumed to be given, whereas sensing directions can be freely devised in the second problem version. In that case, a polynomial-time algorithm is provided for building sensing directions that allow to maximize the network lifetime. A column generation algorithm is proposed for both problem versions, the subproblem being addressed with a hybrid approach based on a genetic algorithm, and an integer linear programming formulation. Numerical results show that addressing the second problem version allows for significant improvements in terms of network lifetime while the computational effort is comparable for both problem versions. 相似文献