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61.
Pregnane oligoglycoside, namely roylinine, and a pregnane derivative, namely marsgenin, have been isolated from chloroform-soluble extract of dried stem of Marsdenia roylei, and their structures were determined using 1H-NMR, 13C-NMR, 1H-1H COSY, HSQC, TOCSY and FABMS spectral techniques as well as chemical degradation and derivatisation. 相似文献
62.
Lingam Venkata Reddy Mamatha Nakka Alishetty Suman Soumen Ghosh Madeleine Helliwell Khagga Mukkanti Alok Kumar Mukherjee Sarbani Pal 《Journal of heterocyclic chemistry》2011,48(3):555-562
Reduction of nimesulide followed by treating the N‐acyl derivative of resulting arylamine with Vilsmeier‐Haack reagent provided novel 2‐chloro‐3‐formylquinoline derivatives. The construction of quinoline ring using Vilsmeier‐Haack reagent afforded an unexpected compound, N‐(2‐chloro‐3‐formyl‐7‐phenoxy quinolin‐6‐yl)formamide, in addition to the expected product. The structure of this unexpected quinoline derivative was established via single‐crystal X‐ray analysis and its formation could be explained by an unprecedented N‐S bond cleavage under Vilsmeier‐Haack reaction conditions. The 2‐chloro‐3‐formylquinoline derivatives obtained were converted to a number of corresponding Schiff bases with potential pharmacological importance. J. Heterocyclic Chem., 2011. 相似文献
63.
64.
Itinerant electron metamagnetism in Dy(Co1-xSix)2 compounds was studied in the light of a recent theoretical model based on magnetovolume effect and spin fluctuations. The nature of the magnetic transition in these compounds was analyzed within the framework of this model. The magnetocaloric effect in these compounds has been calculated and correlated with the strength of itinerant electron metamagnetism. The domain wall pinning effect was found to be dominant at low temperatures. 相似文献
65.
The aromatic compounds p‐nitrobenzaldehyde, p‐hydroxybenzaldehyde, naphthalene, toluene, catechol, quinol, aniline and toluidine dissolved in aqueous acetic acid or aqueous medium were oxidized in quantitative to good yields by 50% H2O2 in the presence of traces of RuCl3 (~10?8 mol; substrate/catalyst ratio 1488:1 to 341 250:1). Conditions for highest yields, in the most economical way, were obtained. Higher catalyst concentrations decrease the yield. Oxidation in aromatic aldehydes is selective at the aldehydic group only. In the case of hydrocarbons, oxidation results in the introduction of a hydroxyl group with >85% (in the case of toluene) selectivity for the ortho position. Formation of low‐molecular‐weight polyaniline was reduced to 10%, along with 90% formation of higher molecular weight polyaniline. In this new, simple and economical method, which is environmentally safe and requires less time, oxo‐centered carboxylate species of ruthenium(III) in acetic acid medium and hydrated ruthenium(III) chloride in aqueous medium probably catalyze the oxidation. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
66.
We consider the arrival time distribution defined through the quantum probability current for a Gaussian wave packet representing
free particles in quantum mechanics in order to explore the issue of the classical limit of arrival time. We formulate the
classical analogue of the arrival time distribution for an ensemble of free particles represented by a phase space distribution
function evolving under the classical Liouville's equation. The classical probability current so constructed matches with
the quantum probability current in the limit of minimum uncertainty. Further, it is possible to show in general that smooth
transitions from the quantum mechanical probability current and the mean arrival time to their respective classical values
are obtained in the limit of large mass of the particles. 相似文献
67.
68.
Alok Kumar Rastogi A. K. Tiwari R. P. Shrivastava 《International Journal of Infrared and Millimeter Waves》1993,14(7):1445-1453
The dielectric optical wave guide is finding growing attention at millimeter wave frequencies. However the dielectric optical waveguide radiates at bends and thus transmission loss increases. These radiations are in the outword direction of bends. This output radiation at output bends arises due to change in phase velocities of the propagating wave at the centre of the dielectric guide and the phase velocity at the outer surface of the dielectric guide. A unique methiod is suggested to avoid these radiation losses.Experimental results are also shown at microwave frequencies. 相似文献
69.
Occurrence of a new electron transfer mechanism in the LiAlH4 reduction of 9-chloromethylanthrancene, diphenylchloromethane and 9-bromofluorene is demonstrated. Alanate anion serves as a source of electrons and hydrogen atoms. 相似文献
70.
Über die Verformung der Röntgenabsorptionskanten in Metallen und Legierungen durch Gitterleerstellen
Amar Nath Nigam 《Zeitschrift für Physik A Hadrons and Nuclei》1961,161(5):496-499
In order to account for the distortion in the shape of x-ray absorption edges in some metals and alloys, a mechanism involving lattice vacancies is proposed. It is shown that an atom near a lattice vacancy will be under the influence of an electrical field resulting from the asymmetric surroundings. The magnitude of this field is found to be large enough to produce a Stark-splitting in the exciton orbit of the absorbing atom. The distortion appearing as a kink on the slope of the absorption curve is shown to be a consequence of this splitting. 相似文献