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1.
Allylic hydroxy phosphonates and their derivatives can be interconverted by using cross metathesis with second generation Grubbs catalyst. The absolute stereochemistry of the starting phosphonate is conserved in the product. Cross metathesis reaction of the acrolein-derived phosphonate 2a yields a series of functionalized allylic hydroxy phosphonates. However, the cross metathesis reaction is often accompanied by competing dimerization and alkene migration reactions leading to a reduction in yield. The cinnamaldehyde- and crotonaldehyde-derived phosphonates 2b and 2c were also examined. In general, the metathesis reactions of phosphonates 2b and 2c are considerably slower than those for phosphonate 2a leading to mixtures. Several hydroxyl-protected derivatives of the phosphonate 2a (methyl carbonate 3a, acetate 4a, N-tosyl carbamate 5a, TBDMS 6a, and acetoacetate 7a) undergo metathesis without competing side reactions to give substituted allylic phosphonates in good to excellent yield. 相似文献
2.
The mercury(II)-catalysed replacement of cyanide in hexacyanoferrate(II) by p-nitrosodiphenylamine (p-NDA) in aqueous solution has been investigated spectrophotometrically by measuring the change in absorbance of the green complex ion, [Fe(CN)(5).p-NDA](3-), at 640 nm. Activation parameters of the catalysed and uncatalysed reactions have been calculated. The effects of the dielectric constant and water content of the medium on reaction rates are used to explain the formation of a polar activated complex and suggest an I(d) mechanism for the catalysed reaction. The varying catalytic activity of Hg(II) as a function of concentration has been discussed. 相似文献
3.
Ayan Ray Md. Sabir Ali Alok Chakrabarti 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2013,67(4):1-9
Liquid Lennard-Jones clusters with magic number of atoms N = 55, 147, 309, 561 and 923 were cooled down in Monte Carlo simulations until freezing. Structural properties of the clusters, including the radial dependence of atomic concentration/density and the local regular structure in arrangement of atoms, just before freezing were analysed. Existence of spherical layers in atomic density around the centre of mass of liquid LJ clusters was confirmed. Formation of layers is explained by central net forces acting on every cluster atom and leading to positioning an atom close to the cluster centre of mass. The strong layering in small clusters of N = 55 and 147 affects atomic diffusion in radial and tangential directions inside the cluster, leading to easier movement of atoms on the layer surface. Analysis of radial profiles of four types of structural units detected in liquid clusters reveals that icosahedral units are the most numerous and are located mainly near cluster surface of all clusters and also in the centre of small clusters. 相似文献
4.
Jyoti Bhawan Singh Shakti Pratap Gupta Mohit Tripathi Sudhanshu Verma Alok Kumar Singh Devraj Yadav R. R. 《Acoustical Physics》2021,67(6):584-589
Acoustical Physics - We have estimated elastic, mechanical, thermal and ultrasonic properties, in high temperature regime, of cobalt nanowires (Co-NWs) having a hexagonal close-packed (HCP)... 相似文献
5.
6.
The effect of gamma irradiation on MOS devices prepared under different oxidation conditions Is investigated. The C-V characteristics of the devices are studied before and after exposing the latter with gamma radiations of CO60 (1.17 and 1.33 MeV gamma rays). For MOS transistor (n-channel depletion type devices) the C-V characteristics change slightly towards the negative voltage axis and the Cmin also decreases after Irradiation. For MOS capacitor (wet oxide) there is a change from high frequency C-V characteristics to low frequency C-V characteristics. In the case of a MOS capacitor (HCl grown) breakdown occurs relatively at lower voltage. 相似文献
7.
Stokes’ and Seth’s solutions for the slow motion of a sphere in a viscous, incompressible liquid have been discussed from the viewpoint of the structure of the velocity field and its relation to the drag of the sphere. The problem is analysed from a different angle in this paper. It is believed that it throws more light on thephysics of the problem. 相似文献
8.
Summary If hydrogen is diffused electrolytically in a metal, it subsequently escapes out if the metal is left to itself. However this
hydrogen-treated metal does not totally regain the original magnitudes of its various physical properties,e. g., thermo e.m.f., electrical resistivity, elastic modulii etc. This effect has also been observed in the second-order elastic
effect (the Poynting effect) in nickel and two varieties of steel. Measurements were carried out first before hydrogen diffusion.
The samples were electrolytically diffused with hydrogen and the left to themselves for a few days and the measurements were
repeated. The changed values of the coefficient of Poynting effect are discussed in terms of the dislocations created by in-and
out-going hydrogen.
Now retired 相似文献
9.
Summary Films of cobalt and nickel were electroplated in the presence of an external magnetic-induction field. This resulted in the
deposition of magnetic films which show, in addition to a magnetic anisotropy, also thermo-e.m.f. anisotropy. The latter is
a new effect, not deriving from the anisotropy in electrical conduction deduced earlier by Kornevet al. on the basis of measurements of transmission coefficients of polarized RF field. 相似文献
10.
M K Parida Nita Sinha B Adhikary B Allanach A Alok K S Babu B Brahmachari D Choudhury E J Chun P K Das A Ghosal D Hitlin W S Hou S Kumar H N Li E Ma S K Majee G Majumdar B Mishra G Mohanty S Nandi H Pas M K Parida S D Rindani J P Saha N Sahu Y Sakai S Sen C Sharma C D Sharma S Shalgar N N Singh S Uma Sankar N Sinha R Sinha F Simonetto R Srikanth R Vaidya 《Pramana》2006,67(5):849-860
This is the report of flavor physics and model building working group at WHEPP-9. While activites in flavor physics have been
mainly focused on B-physics, those in model building have been primarily devoted to neutrino physics. We present summary of working group discussions
carried out during the workshop in the above fields, and also briefly review the progress made in some projects subsequently. 相似文献