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71.
The aromatic compounds p‐nitrobenzaldehyde, p‐hydroxybenzaldehyde, naphthalene, toluene, catechol, quinol, aniline and toluidine dissolved in aqueous acetic acid or aqueous medium were oxidized in quantitative to good yields by 50% H2O2 in the presence of traces of RuCl3 (~10?8 mol; substrate/catalyst ratio 1488:1 to 341 250:1). Conditions for highest yields, in the most economical way, were obtained. Higher catalyst concentrations decrease the yield. Oxidation in aromatic aldehydes is selective at the aldehydic group only. In the case of hydrocarbons, oxidation results in the introduction of a hydroxyl group with >85% (in the case of toluene) selectivity for the ortho position. Formation of low‐molecular‐weight polyaniline was reduced to 10%, along with 90% formation of higher molecular weight polyaniline. In this new, simple and economical method, which is environmentally safe and requires less time, oxo‐centered carboxylate species of ruthenium(III) in acetic acid medium and hydrated ruthenium(III) chloride in aqueous medium probably catalyze the oxidation. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
72.
S Chakrabarty 《Pramana》1985,25(6):673-683
Transport coefficients of quark-gluon plasma are discussed in the framework of relativistic kinetic theory with the relaxation
time approximation of Boltzmann transport equation. The expressions for the coefficients of shear and volume viscosities and
heat conductivity are derived assuming quark-gluon plasma to be a non-reactive mixture of quarks, anti-quarks and gluons.
A lowest order in deviations from local thermal equilibrium and in plasma phase, lowest order in coupling constant are assumed.
Entropy production due to irreversible processes is discussed. 相似文献
73.
Alok Kumar Rastogi A. K. Tiwari R. P. Shrivastava 《International Journal of Infrared and Millimeter Waves》1993,14(7):1445-1453
The dielectric optical wave guide is finding growing attention at millimeter wave frequencies. However the dielectric optical waveguide radiates at bends and thus transmission loss increases. These radiations are in the outword direction of bends. This output radiation at output bends arises due to change in phase velocities of the propagating wave at the centre of the dielectric guide and the phase velocity at the outer surface of the dielectric guide. A unique methiod is suggested to avoid these radiation losses.Experimental results are also shown at microwave frequencies. 相似文献
74.
Occurrence of a new electron transfer mechanism in the LiAlH4 reduction of 9-chloromethylanthrancene, diphenylchloromethane and 9-bromofluorene is demonstrated. Alanate anion serves as a source of electrons and hydrogen atoms. 相似文献
75.
Amarendra Patra Apurba K. Mukhopadhyay Alok K. Mitra 《Magnetic resonance in chemistry : MRC》1981,17(3):166-168
Carbon-13 signal assignments of taraxasteryl acetate, taraxasteryl palmitate, taraxasterol and epi-friedelinyl acetate are reported. Some signal assignments of the friedelanones, reported recently by others, are inconsistent and require revision. 相似文献
76.
77.
Conformational flexibility of the ammonium complex of macrocyclic 18-crown-6 at 100 K < or = T < or = 300 K is studied using a positron microprobe in conjunction with molecular dynamics simulations. The ammonium cation, encapsulated in a three-pointed hydrogen-bonding perching arrangement, undergoes unhindered facile rotation inside the crown cavity, and the ether backbone adopts itself to the dynamic cation conformation. Preferential localization of the positron in the vicinity of the encapsulated cation results in the positron sensing changes in the local electron density distribution arising from the unrestricted rotational motion of the cation as well as from the slow motion of the crown backbone and hence sensing only an average conformation of the complex. 相似文献
78.
Ferromagnetic resonance measurements were carried out on various compositions of magnesium nickel ferrites prepared by various heat treatments. Corrections were applied for polycrystalline and size effects for calculating the g factor and linewidth. The variation of these parameters has been explained on the basis of the cation distribution in these compounds as obtained from magnetization data assuming a collinear model of spin distribution. 相似文献
79.
The new molybdenum cyanonitrosyl complexes, R2[Mo(NO)(CN)5]·2H2O (R = Ph4P and Bu4N) and [Mo(NO)(CN)3(L-L)]·H2O [L-L = 相似文献
80.