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21.
(R)-2-羟基-4-苯基丁酸乙酯的合成   总被引:4,自引:0,他引:4  
林文清  张晓梅  宓爱巧 《合成化学》2002,10(5):385-390,456
综述了血管紧张素转化酶抑制剂类治疗高血压和充血性心力衰竭药物的关键中间体(R)-2-羟基-4-苯基丁酸乙酯的合成方法。参考文献25篇。  相似文献   
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In our laboratories we have been studying the synthesis and reactivity of binary actinide and lanthanide intermetallic compounds. In this work, the air-oxidation of ThCu2 and AnNi2 (An = Th, U) was followed by thermogravimetry (TG) and the products were characterized by X-ray powder diffraction (XRD). The heterobimetallic oxides obtained are described by the formulas 2MO·ThO2 (M = Cu, Ni) and 2NiO·UO3. The thermogravimetric analysis under hydrogen of these heterobimetallic oxides show one mass loss for 2MO·ThO2 and two mass losses for 2NiO·UO3 over a wide range of temperature (293–1273 K). The characterization by XRD shows that the reduction products are 2M·ThO2 (M = Cu, Ni) and 2Ni·UO2, with all the actinides in the 4+ oxidation state. The actinide heterobimetallic oxides were described as copper or nickel supported catalysts.  相似文献   
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In this work, chitosan beads were synthesized in acidic medium and cross-linked in 1% glutaraldehyde solution. The characterization of the materials using TG/DTG, XRD, and BET surface areas showed that the beads did not modify their characteristics after the cross-linking reaction. The cross-linked beads were utilized as adsorbents for the removal of the yellow-, blue-, and red-anionic reactive dyes from aqueous solutions at pH 2.0. Adsorption of the yellow-dye increased from 25 to 50 degrees C. However, adsorption of the blue-dye decreased from 25 to 50 degrees C. Interestingly, the adsorption of the red-dye decreased from 25 to 35 degrees C and increased from 45 to 50 degrees C. The kinetic data were evaluated using an Avrami kinetic model, where the parameter n was related to the determination of changes in the adsorption mechanisms. Adsorption data of the dyes in relation to the contact time, the chemical structures of the dyes, and temperature were presented and were discussed.  相似文献   
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Hydrophobic films of polystyrene synthesized in bulk (PS) and by emulsion polymerization in the presence of the cationic surfactant cetyltrimethylammonium bromide (PS-CTAB) or the anionic surfactant sodium dodecyl sulfate (PS-SDS) were characterized by means of ellipsometry, contact angle measurements, and atomic force microscopy. Thin (approximately 65 nm) and thick (approximately 300 nm) films were spin-coated on hydrophilic silicon wafers. PS films presented scarcely tiny holes, while PS-CTAB and PS-SDS films presented holes and protuberances. The former were attributed to dewetting effects and the latter to surfactant clusters. The films were exposed to water or to a 0.1 mol/L NaCl solution for 24 h. Ex situ measurements evidenced strong topographic alterations after the exposure to the fluid. A model based on the diffusion of water (or electrolyte) molecules to the polymer/silcon dioxide interface through holes or defects on the film edges was proposed to explain the appearance of wrinkles and protuberances. In situ ellipsometric measurements were performed and compared with simulations, which considered either a water layer between a polymer and a silcon dioxide layer or an air layer between a polymer and water (medium). In the case of thin PS films, the ellipsometric angles evidenced a very thin (0.5-1.0 nm) air layer between water and the PS films. Upon increasing the PS film thickness, no air layer could be observed by ellipsometry. Regardless of the thickness, the ellipsometric data obtained for PS-CTAB and PS-SDS films did not indicate the presence of an air layer between them and the aqueous media. The dramatic changes in the topography of PS, PS-CTAB, and PS-SDS after immersion in salt solution were explained with proposed models. From a practical point of view, this study is particularly relevant because many hydrophobic polymers are used as substrates for biomedical purposes, where the physiological ionic strength is 0.15 mol/L NaCl.  相似文献   
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Annals of Operations Research - The aim of this paper is to solve an agricultural technology packages selection problem by considering multiple dimensions which influence a maize producer’s...  相似文献   
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The forward-backward asymmetries for the processes and at theZ resonance are measured using identifiedD mesons. In 905,000 selected hadronic events, taken in 1991 and 1992 with the DEL-PHI detector at LEP, 4757D *+D 0+ decays are reconstructed. Thec andb quark forward-backward asymmetries are determined to be:
  相似文献   
28.
The average lifetime ofB hadrons was measured using data collected with the DELPHI detector at the LEP collider during 1991 and 1992. The measurement was performed using two different anayses. The first method was an improvement on a previous technique, which used charged particle impact parameter distributions. This analysis measured an average lifetime forB hadrons of
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