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41.
Walter N. L. dos Santos Dannuza D. Cavalcante Hadla S. Ferreira Cesário F. das Virgens Aline R. Borges Marcia M. Silva 《International journal of environmental analytical chemistry》2013,93(15):1447-1452
A cloud point extraction procedure for pre-concentration and determination of cadmium and lead in drinking water using sequential multi-element flame atomic absorption spectrometry is described. 4-(2-thiazolylazo)-orcinol (TAO) has been used as complexing agent and the micellar phase was obtained using the non-ionic surfactant octylphenoxypolyethoxyethanol (Triton X-114) and centrifugation. The conditions for reaction and extraction (surfactant concentration, reagent concentration, effect of incubation time, etc) were studied and the analytical characteristics of the method were determined. The method allows the determination of cadmium and lead with quantification limits of 0.30?µg?L?1 and 2.6?µg?L?1, respectively. A precision expressed as relative standard deviation (RSD, n?=?10) of 2.3% and 2.6% has been obtained for cadmium concentrations of 10?µg?L?1 and 30?µg?L?1, respectively, and RSD of 1.3% and 1.7% for lead concentrations of 10?µg?L?1 and 30?µg?L?1, respectively. The accuracy was confirmed by analysis of a natural water certified reference material. The method has been applied for the determination of cadmium and lead in drinking water samples collected in the cities of Ilhéus and Itabuna, Brazil. Recovery tests have also been performed for some samples, and results varied from 96 to 105% for cadmium and 97 to 106% for lead. The cadmium and lead concentrations found in these samples were always lower than the permissible maximum levels stipulated by World Health Organization and the Brazilian Government. 相似文献
42.
Oliver Bleher Aline Schindler Meng-Xin Yin Andrew B. Holmes Peter B. Luppa Günter Gauglitz Günther Proll 《Analytical and bioanalytical chemistry》2014,406(14):3305-3314
Autoimmune diseases are characterized by the presence of autoantibodies in serum of affected patients. The heterogeneity of autoimmune relevant antigens creates a variety of different antibodies, which requires a simultaneous detection mode. For this reason, we developed a tool for parallelized, label-free, optical detection that accomplishes the characterization of multiple antigen–antibody interactions within a single measurement on a timescale of minutes. Using 11-aminoundecyltrimethoxysilane, we were able to immobilize proteinogenic antigens as well as an amino-functionalized cardiolipin on a glass surface. Assay conditions were optimized for serum measurements with a single spot antigen chip on a single spot 1-λ detection system. Minimized background signal allows a differentiation between patients and healthy controls with a good sensitivity and specificity. Applying polarized imaging reflectometric interference spectroscopy, we evaluated samples from three APS patients and three control subjects for this proof-of-principle and already obtained good results for β2-glycoprotein I and cardiolipin. 相似文献
43.
do Nascimento Ticiano Gomes Borges Arthur Luy Tavares Ferreira de Almeida Lara Mendes Ribeiro Êurica Adélia Nogueira Silva Fernanda Geny Calheiros da Costa Silva Valdemir do Nascimento Prata Ana Paula Basílio-Júnior Irinaldo Diniz Goulart Marília Oliveira Fonseca Morilla Demetrius Peireira de Freitas Johnnatan Duarte Aragão Cícero Flávio Soares 《Journal of Thermal Analysis and Calorimetry》2022,147(21):11949-11963
Journal of Thermal Analysis and Calorimetry - This work prepared and characterized microcapsule of Uncaria tomentosa (UT) in order to standardize a spray-dryer Uncaria tomentosa extract. The UT... 相似文献
44.
Novák V. Kostura B. Raška P. Dědková K. Peterek Mendes R.G. Gemming T. Leško J. 《Journal of Solid State Electrochemistry》2021,25(1):365-372
Journal of Solid State Electrochemistry - Knowledge of the properties of metallurgical waste is essential for the assessment of their recycling. In this work, the formation of iron oxide nanolayers... 相似文献
45.
Vasudevan Lakshminarayanan Cindhuja Chockalingam Dr. Eduardo Mendes Dr. Prof. Jan H. van Esch 《Chemphyschem》2021,22(21):2256-2261
Properties such as shear modulus, gelation time, structure of supramolecular hydrogels are strongly dependent on self-assembly, gelation triggering mechanism and processes used to form the gel. In our work we extend reported rheology analysis methodologies to pH-triggered supramolecular gels to understand structural insight using a model system based on N−N’ Dibenzoyl-L-Cystine pH-triggered hydrogelator and Glucono-δ-Lactone as the trigger. We observed that Avrami growth model when applied to time-sweep rheological data of gels formed at lower trigger concentrations provide estimates of fractal dimension which agree well compared with visualization of the microstructure as seen via Confocal Laser Scanning Microscopy, for a range of gelator concentrations. 相似文献
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48.
Paiva GS Pavão AC Alpes de Vasconcelos E Mendes O da Silva EF 《Physical review letters》2007,98(4):048501
We performed electric arc discharges in pure Si to generate luminous balls with lifetime in the order of seconds and several properties usually reported for natural ball lightning. This simple experiment does not rely on energy sources and excitation mechanisms that are improbable in the natural phenomenon and clearly demonstrates the role of vaporization and oxidation of Si, as proposed by the Abrahamson-Dinniss theory for ball-lightning formation. 相似文献
49.
Paola Aline Amarante Borba Debora Dalla Vecchia Manoela Klüppel Riekes Rafael Nicolay Pereira Monika Piazzon Tagliari Marcos Antonio Segatto Silva Silvia Lucia Cuffini Carlos Eduardo Maduro de Campos Hellen Karine Stulzer 《Journal of Thermal Analysis and Calorimetry》2014,115(3):2507-2515
This study was performed to investigate the physical–chemical characteristics of carvedilol (CRV), complemented by compatibility studies with a great variety of pharmaceutical excipients. Thermogravimetry and differential scanning calorimetry, supported by diffuse reflectance infrared fourier transform spectroscopy (DRIFT), X-ray powder diffraction, and scanning electron microscopy (SEM) were selected as the solid-state techniques for the intended analyses. In addition, non-isothermal methods were employed to investigate kinetic data of CRV decomposition process under nitrogen and air atmospheres. CRV is characterized by an endothermic sharp event (T peak = 389.81 K and ΔH fusion of ?176.28 J g?1) and a thermal decomposition behavior in two stages, totalizing 98 % of mass loss. The CRV pattern diffraction presents prominent peaks at 2θ: 5.92°, 14.90°, 18.62°, 24.47°, and 26.30°, and the DRIFT spectrum showed the main characteristics bands for CRV chemical functional groups. The SEM photomicrographs demonstrate that CRV is characterized by irregular blocky shaped crystals. Zero order kinetics was determined by Ozawa method in both nitrogen and air atmospheres. The compatibility results showed no evidence of any incompatibility among CRV and all the excipients analyzed. 相似文献
50.
Michelle P. van der Helm Chang-Lin Wang Bowen Fan Mariano Macchione Eduardo Mendes Rienk Eelkema 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(46):20785-20792
Signal transduction in living systems is the conversion of information into a chemical change, and is the principal process by which cells communicate. In nature, these functions are encoded in non-equilibrium (bio)chemical reaction networks (CRNs) controlled by enzymes. However, man-made catalytically controlled networks are rare. We incorporated catalysis into an artificial fuel-driven out-of-equilibrium CRN, where the forward (ester formation) and backward (ester hydrolysis) reactions are controlled by varying the ratio of two organocatalysts: pyridine and imidazole. This catalytic regulation enables full control over ester yield and lifetime. This fuel-driven strategy was expanded to a responsive polymer system, where transient polymer conformation and aggregation are controlled through fuel and catalyst levels. Altogether, we show that organocatalysis can be used to control a man-made fuel-driven system and induce a change in a macromolecular superstructure, as in natural non-equilibrium systems. 相似文献