A new method to study antioxidant capability: hydrogen transfer from phenols to a prefluorescent nitroxide

[reaction: see text]. Rate constants for hydrogen abstraction from phenols by a prefluorescent-TEMPO probe are reported. The nitroxide is employed as a potential model of peroxyl radicals. The probe works by nitroxide suppression of the fluorescence of the chromophore. The fluorescence is restored when the nitroxide abstracts a hydrogen atom to produce the diamagnetic hydroxylamine. The phenols studied in this project exhibited rate constants between 0.003 and 0.2 M(-1) s(-1). A deuterium isotope effect of 10 for TROLOX confirms that the mechanism is dominated by hydrogen transfer.     

Effects of H/D-isotope substitution and temperature on the volume characteristics of tetra-n-butylammonium bromide dissolved in methanol and its D-isotopomers

Densities of Buⁿ ₄NBr solutions in MeOH, MeOD, and CD₃OH were measured at salt concentrations of up to 1.5 solvomolality units (nearly 2.63·10^–2 mole fraction) at 278.15, 288.15, 298.15, 308.15, and 318.15 K. The limiting partial molar volumes of Buⁿ ₄NBr dissolved in these alcohols were calculated. The isotope effects in the volume characteristics of the stoichiometric mixture of ions, [Buⁿ ₄N⁺ + Br^–], are mainly due to the vibrational changes in the solvent structure upon deuteration of different molecular fragments. Structural transformations in infinitely dilute solution of Buⁿ ₄NBr in methanol are governed by non-specific solvation of the symmetrical Buⁿ ₄N⁺ cation.     

On the relation between the Jackson and Jung constants of the spacesL p

For any infinitely metrizable compact Abelian groupG; 1pq<,n , the following relations are proved: whereK _pq(G, n, G) is the largest Jackson constant in the approximation of the system of characters by polynomials of ordern, d _pq(G, n, G) is the best Jackson constant,J(L _p(G), L_q(G)) is the Jung constant of the pair of real spaces (L _p(G), L_q(G)), and.Translated fromMatematicheskie Zametki, Vol. 58, No. 6, pp. 828–836, December, 1995.This work was supported by the Russian Foundation for Basic Research under grant No. 95-01-00657.     

Nonreciprocal effects in light reflection by a moving medium

Nonreciprocal effects in light reflection by a medium moving along an interface are considered in a weakly relativistic approximation. It is found that nonreciprocal effects are anomalously large in the vicinity of the Brewster and the total-internal-reflection (TIR) angles when light is reflected by transparent moving media. These effects exceed considerably (by several orders of magnitude) the ratio of the velocity of the reflecting medium to the velocity of light and can be proportional to rather than to under certain conditions. We show new possibilities for the creation a method for investigation of the structure of nonuniform flows with a very small spatial scale (less than one millimeter). This method is based on measurement of amplitude and phase nonreciprocities in light reflection by these flows.Institute of Applied Physics, Russian Academy of Sciences, Nizhny Novgorod. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 38, No. 11, pp. 1146–1157, November, 1995.     

Change in structure and properties of carbon steels bombarded by a 10−5 to 10−4 second high-energy electron beam

We consider the hardening characteristics and features of the structural and phase transformations in carbon steel (0.7% C) quenched from the melt using an electron beam with electron energy 130–180 keV, pulse duration 10–200 msec and power density 10⁶ to 10⁷ W/cm². We have observed that maximum hardening is achieved for pulse duration 40 msec. The nonmonotonic character of the dependence of the degree of hardening on the pulse duration is connected with the substantial effect of the beam parameters on the phase composition and morphology of the rapidly quenched structures.Institute of Power Electronics, Siberian Branch, Russian Academy of Sciences; Tomsk State Architectural Design Academy. Institute of the Physics of Strength and Materials Science, Siberian Branch, Russian Academy of Sciences. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, p. 42–50, October, 1995.