全文获取类型
收费全文 | 25507篇 |
免费 | 5篇 |
国内免费 | 218篇 |
专业分类
化学 | 7679篇 |
晶体学 | 217篇 |
力学 | 1849篇 |
数学 | 8078篇 |
物理学 | 7907篇 |
出版年
2022年 | 9篇 |
2020年 | 7篇 |
2018年 | 1976篇 |
2017年 | 2236篇 |
2016年 | 970篇 |
2015年 | 632篇 |
2014年 | 520篇 |
2013年 | 798篇 |
2012年 | 1803篇 |
2011年 | 1057篇 |
2010年 | 39篇 |
2009年 | 140篇 |
2008年 | 119篇 |
2007年 | 112篇 |
2006年 | 121篇 |
2005年 | 5821篇 |
2004年 | 5628篇 |
2003年 | 3087篇 |
2002年 | 269篇 |
2001年 | 23篇 |
2000年 | 15篇 |
1999年 | 19篇 |
1998年 | 32篇 |
1997年 | 15篇 |
1996年 | 11篇 |
1995年 | 11篇 |
1994年 | 8篇 |
1993年 | 12篇 |
1992年 | 17篇 |
1991年 | 10篇 |
1990年 | 8篇 |
1989年 | 23篇 |
1988年 | 16篇 |
1987年 | 14篇 |
1986年 | 14篇 |
1985年 | 5篇 |
1984年 | 5篇 |
1983年 | 8篇 |
1982年 | 5篇 |
1981年 | 9篇 |
1979年 | 6篇 |
1978年 | 10篇 |
1977年 | 10篇 |
1976年 | 8篇 |
1975年 | 11篇 |
1973年 | 8篇 |
1972年 | 7篇 |
1971年 | 6篇 |
1970年 | 5篇 |
1960年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
21.
O.?V.?OshurkovaEmail author V.?P.?Nesterov 《Russian Journal of Electrochemistry》2005,41(12):1325-1329
The separation of a mixture containing anions of nine organic acids is investigated on an instrument for capillary isotachophoresis with an optical detector for the registration of boundaries. The separation is conducted in concentrated solutions of sodium salts. A counterflow is used during the separation. 相似文献
22.
P.M.?Kosaka Y.?Kawano M.C.?Salvadori D.F.S.?PetriEmail author 《Cellulose (London, England)》2005,12(4):351-359
The adsorption of cellulose acetate (CA), cellulose acetate propionate (CAP) and cellulose acetate butyrate (CAB) from solutions
prepared in acetone onto silicon wafers led to ultrathin films, which were characterized by ellipsometry, atomic force microscopy
(AFM) and contact angle measurements. The polysaccharides films were characterized in the air just after their formation and
after annealing at temperatures higher than their glass transition temperature or melt temperature. The films thickness close
to 2 nm and surface roughness did not vary significantly upon annealing. AFM images revealed the presence of small clumps
dispersed on a homogeneous layer, which covered completely the Si wafers. Such topographic details were also observed after
annealing. However, upon annealing the films surfaces changed from hydrophilic to hydrophobic, evidencing molecular re-orientation
at the solid–air interface. The adhesion of bovine serum albumin (BSA) and lipase onto the cellulose esters films was quantified
in order to evaluate the possibility of applying such films as selective support for biomolecules. 相似文献
23.
LC-MS/MS method for the confirmatory determination of aromatic amines and its application in textile analysis 总被引:1,自引:0,他引:1
Sutthivaiyakit P Achatz S Lintelmann J Aungpradit T Chanwirat R Chumanee S Kettrup A 《Analytical and bioanalytical chemistry》2005,381(1):268-276
A confirmation method for the determination of 18 aromatic amines originating from azo dyes after reductive cleavage was developed. The method is based on the use of high-performance liquid chromatography/tandem mass spectrometry with atmospheric-pressure chemical ionization. For the identification of the analytes one precursor ion and two daughter ions (multi-reaction monitoring, MRM) were selected and the LC-MS/MS parameters optimized to obtain high sensitivity and selectivity. The linear ranges varied from 0.1–1 to 30–50 g mL–1 with correlation coefficients of 0.99 or better. The applicability of the method to determine o-tolidine (3,3-dimethylbenzidine) and 3,3-dimethoxybenzidine in textiles following reductive cleavage of acid red 114, trypan blue, and Chicago sky blue 6B was demonstrated. 相似文献
24.
Mycotoxins are secondary metabolites, formed by the action of fungi on agricultural crops in the field or during storage. These metabolites are highly toxic to animals and humans and high levels have been measured in agricultural crops. In order to evaluate human risks due to ingestion of mycotoxin-contaminated food different methods have been developed for analysis of mycotoxins in cereals and maize. In this project the focus was on mycotoxins in agricultural soil and the fate of these toxins in the soil-water-plant system. Two different mycotoxins were selected in the study: zearalenone (ZON) produced by species of Fusariumor Aspergillusand ochratoxin A (OTA) produced by species of Penicillium. We developed a method for analysis of these toxins in soil. Soil samples were extracted with methanol-water (9:1) and purified by solid-phase extraction (SPE, C8-columns). The final extract was analysed using high-pressure liquid chromatography (HPLC) with fluorescence detection. A Phenyl Hexyl column was used to separate the toxins. The detection limits obtained were 0.1 and 1.0 microg kg(-1) dry weight (dw) for OTA and ZON, respectively. The developed method has been used for analysis of different soils in connection with growth chamber experiments. The soil types used in the growth chamber experiments were a sandy soil, a sandy clay soil, and a soil with high content of organic matter. The recovery was determined as 85.8 and 93.4% and the repeatability to 5.1 and 12.8% for OTA and ZON, respectively. The reproducibility obtained was 8.5 and 15.0% for soil samples, representing concentration levels from 0.2-30 microg kg(-1) dw (OTA) and from 1.0-100 microg kg(-1) dw (ZON). 相似文献
25.
The molecular complex formation reactions of uridine (Urd) with adenosine (Ado), cytidine (Cyd), thymidine (Thd), adenosine 5-monophosphate (AMP) and cytidine 5-monophosphate (CMP) have been studied at 20°C. It was found that the main positive noncovalent centers of ion–dipole and dipole–dipole type interactions are the protonated N(3) atoms of Urd, whereas the negative centers are the endocyclic atoms of the bases characterized by high electron density from the second molecule involved in the reaction. Moreover, NMR results indicate the occurrence of stacking in the complex (Urd)H(Cyd), whereas in the complex, (Urd)H2(Thd), it is the only type of interaction. Deprotonation of the latter species brings about a change in the character of the reaction and ion–dipole interactions have been detected in the adduct, (Urd)H(Thd). Interestingly, no involvement of the phosphate groups in the formation of AMP and CMP adducts has been evidenced and the main centers of the reactions were found to be the N(7)and N(1) atoms of AMP, or the N(3) atoms of CMP and Urd. Moreover, in the Urd/CMP system the NMR results suggest stacking-type interactions. 相似文献
26.
27.
28.
Bilevich K. A. Bubnov N. N. Ioffe N. T. Kalinkin M. I. Okhlobystin O. Yu. Petrovskii P. V. 《Russian Chemical Bulletin》1971,20(8):1707-1708
Russian Chemical Bulletin - 相似文献
29.
Selenomethionine contents of NIST wheat reference materials 总被引:1,自引:0,他引:1
Values of the total selenium and selenomethionine (Semet) content of four wheat-based reference materials have been obtained by gas chromatography-stable isotope dilution mass spectrometry methods. The total Se method is an established one, and the results obtained with it are consistent with previously-assigned values. The Semet method (previously reported by our laboratory) is based on reaction with CNBr. Our data indicate that the four wheat samples (wheat gluten, durum wheat, hard red spring wheat, and soft winter wheat), though having a 30-fold range in total Se content, all have about 45% of their total Se values in the form of selenomethionine. Investigation of the CNBr-based method suggests that additional experiments are needed to verify that all selenomethionine in the wheat samples is accounted for, but also indicates that the values obtained are within 15% of the true values. As the form in which Se occurs in foods and dietary supplements is important from a nutritional perspective, adding information about Se speciation to total Se values in appropriate reference materials makes these materials more valuable in relevant analytical work. 相似文献
30.
J.?R.?Tolchard J.?E.?H.?Sansom P.?R.?SlaterEmail author M.?S.?Islam 《Journal of Solid State Electrochemistry》2004,8(9):668-673
Recently, high oxide ion conduction has been observed in the apatite-type systems La9.33+x(Si/Ge)6O26+x/2, with conductivities approaching and even exceeding that of yttria-stabilized zirconia. The Ge-based phases have been reported to suffer from Ge loss and undergo irreversible structural changes on sintering at the high temperatures required to obtain dense pellets. In this paper we discuss doping studies (Ba, Bi for La) aimed at stabilizing the hexagonal apatite lattice to high temperature, and/or lowering the synthesis and sintering temperatures. The results show that doping with Ba helps to stabilize the hexagonal lattice at high temperatures, although Ge loss appears to still be a problem. Conductivity data show that, as previously reported for the Si-based systems, non-stoichiometry in the form of cation vacancies and/or oxygen excess is required to achieve high oxide ion conduction in these Ge-based systems. Neutron diffraction structural data for the fully stoichiometric phase La8Ba2Ge6O26 shows that the channel oxygen atoms show little anisotropy in their thermal displacement parameters, consistent with the low oxide ion conductivity of this phase. Bi doping is shown to lower the synthesis and sintering temperatures, although the presence of Bi means that these samples are not stable at high temperatures under reducing conditions.Presented at the OSSEP Workshop Ionic and Mixed Conductors: Methods and Processes, Aveiro, Portugal, April 10–12, 2003 相似文献