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841.
We develop a simple Landau-Ginzburg-type continuum theory of solvent-free ionic liquids and use it to predict the structure of the electrical double layer. The model captures overscreening from short-range correlations, dominant at small voltages, and steric constraints of finite ion sizes, which prevail at large voltages. Increasing the voltage gradually suppresses overscreening in favor of the crowding of counterions in a condensed inner layer near the electrode. This prediction, the ion profiles, and the capacitance-voltage dependence are consistent with recent computer simulations and experiments on room-temperature ionic liquids, using a correlation length of order the ion size. 相似文献
842.
Alexei Sharpanskykh Sybert H. Stroeve 《Computational & Mathematical Organization Theory》2011,17(1):77-117
Safety culture is broadly recognized as important for operational safety in various fields, including air traffic management,
power plant control and health care. Previous studies addressed characterization and assessment of safety culture extensively.
Nevertheless, relations between safety culture and formal and informal organizational structures and processes are yet not
well understood. To address this gap, a new, formal, agent-based approach is proposed. This paper shows the application of
the approach to an air navigation service provider, including structured modeling, analysis and identification of improvement
strategies for the organizational safety culture. The model results have been validated using safety culture data that had
been achieved by an independent safety culture survey study. 相似文献
843.
Aleksandr Kalinko Alexey Kotlov Alexei Kuzmin Vladimir Pankratov Anatoli I. Popov Liana Shirmane 《Central European Journal of Physics》2011,9(2):432-437
The photoluminescence spectra and luminescence excitation spectra of pure microcrystalline and nano-sized ZnWO4 as well as the Zn
x
Ni1−x
WO4 solid solutions were studied using vacuum ultraviolet (VUV) synchrotron radiation. The samples were also characterized by
x-ray powder diffraction. We found that: (i) the shape of the photoluminescence band at 2.5 eV, being due to radiative electron
transitions within the [WO6]6− anions, becomes modulated by the optical absorption of Ni2+ ions in the Zn
x
Ni1−x
WO4 solid solutions; and (ii) no significant change in the excitation spectra of Zn0.9Ni0.1WO4 is observed compared to pure ZnWO4. At the same time, a shift of the excitonic bands to smaller energies and a set of peaks, attributed to the one-electron
transitions from the top of the valence band to quasi-localized states, were observed in the excitation spectrum of nano-sized
ZnWO4. 相似文献
844.
Valentina E. Bychkova Dmitry A. Dolgikh Vitalii A. Balobanov Alexei V. Finkelstein 《Molecules (Basel, Switzerland)》2022,27(14)
Quite a long time ago, Oleg B. Ptitsyn put forward a hypothesis about the possible functional significance of the molten globule (MG) state for the functioning of proteins. MG is an intermediate between the unfolded and the native state of a protein. Its experimental detection and investigation in a cell are extremely difficult. In the last decades, intensive studies have demonstrated that the MG-like state of some globular proteins arises from either their modifications or interactions with protein partners or other cell components. This review summarizes such reports. In many cases, MG was evidenced to be functionally important. Thus, the MG state is quite common for functional cellular proteins. This supports Ptitsyn’s hypothesis that some globular proteins may switch between two active states, rigid (N) and soft (MG), to work in solution or interact with partners. 相似文献
845.
We consider smooth algebraic varieties with ample either canonical or anticanonical sheaf. We prove that such a variety is uniquely determined by its derived category of coherent sheaves. We also calculate the group of exact autoequivalences for these categories. The technics of ample sequences in Abelian categories is used. 相似文献
846.
Kevin Dykstra Alexei Buevich Qi Gao Yu-Hong Lam Jeffrey T. Kuethe 《Molecules (Basel, Switzerland)》2022,27(2)
An effective strategy has been developed for the photoredox-catalyzed decarboxylative addition of cyclic amino acids to both vinylogous amides and esters leading to uniquely substituted heterocycles. The additions take place exclusively trans to the substituent present on the dihydropyridone ring affording stereochemical control about the new carbon-carbon bond. These reactions are operationally simplistic and afford the desired products in good to excellent isolated yields. 相似文献
847.
848.
Hydrogen‐Bond‐Mediated Aglycone Delivery (HAD): A Highly Stereoselective Synthesis of 1,2‐cis α‐D‐Glucosides from Common Glycosyl Donors in the Presence of Bromine 下载免费PDF全文
Dr. Jagodige P. Yasomanee Prof. Alexei V. Demchenko 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(17):6572-6581
Described herein is the expansion of the picoloyl protecting‐group assisted H‐bond mediated aglycone delivery (HAD) method recently introduced by our laboratory. At first it was noticed that high α‐stereoselectivity is only obtained with S‐ethyl glycosyl donors and only in the presence of dimethyl(methylthio)sulfonium trifluoromethanesulfonate (DMTST), in high dilution, and low temperature. Combining the mechanistic studies of the HAD reaction and bromine‐promoted glycosylations allowed a very effective method to be devised that allows for highly stereoselective α‐glycosidation of practically all common leaving groups (S‐phenyl, S‐tolyl, S/O‐imidates) at regular concentrations and ambient temperature. 相似文献
849.
850.