首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   662篇
  免费   15篇
  国内免费   18篇
化学   305篇
晶体学   4篇
力学   4篇
数学   310篇
物理学   72篇
  2023年   3篇
  2022年   15篇
  2021年   20篇
  2020年   12篇
  2019年   16篇
  2018年   9篇
  2017年   10篇
  2016年   20篇
  2015年   21篇
  2014年   23篇
  2013年   48篇
  2012年   51篇
  2011年   48篇
  2010年   37篇
  2009年   36篇
  2008年   49篇
  2007年   41篇
  2006年   40篇
  2005年   26篇
  2004年   25篇
  2003年   25篇
  2002年   14篇
  2001年   6篇
  2000年   5篇
  1999年   3篇
  1998年   3篇
  1997年   3篇
  1996年   7篇
  1995年   9篇
  1994年   4篇
  1993年   6篇
  1992年   3篇
  1991年   3篇
  1990年   1篇
  1988年   2篇
  1987年   1篇
  1985年   9篇
  1984年   6篇
  1983年   4篇
  1982年   3篇
  1981年   3篇
  1980年   3篇
  1979年   4篇
  1978年   5篇
  1977年   2篇
  1976年   3篇
  1975年   3篇
  1974年   1篇
  1973年   3篇
  1971年   1篇
排序方式: 共有695条查询结果,搜索用时 15 毫秒
61.
We determine the rank generating function, the zeta polynomial and the M?bius function for the poset NC (B) (p, q) of annular non-crossing partitions of type B, where p and q are two positive integers. We give an alternative treatment of some of these results in the case q = 1, for which this poset is a lattice. We also consider the general case of multiannular noncrossing partitions of type B, and prove that this reduces to the cases of non-crossing partitions of type B in the annulus and the disc.  相似文献   
62.
In this note, we address the following question: Which 1-formal groups occur as fundamental groups of both quasi-K?hler manifolds and closed, connected, orientable 3-manifolds. We classify all such groups, at the level of Malcev completions, and compute their coranks. Dropping the assumption on realizability by 3-manifolds, we show that the corank equals the isotropy index of the cup-product map in degree one. Finally, we examine the formality properties of smooth affine surfaces and quasi-homogeneous isolated surface singularities. In the latter case, we describe explicitly the positive-dimensional components of the first characteristic variety for the associated singularity link.  相似文献   
63.
The task of this study is to investigate the influence of various geometric parameters and pressure ratios on the Coanda ejector performance. For numerically investigations we use an implicit formulation of the compressible Reynolds-average Navier-Stokes equations (RANS) for axisymmetric flow with a shear stress transport k − ω (SST model) turbulence model. The numerically results was obtained for a total pressure range 1-5 Bars, imposed at the reservoir inlet. The effect of various factors, such as, the pressure ratio, primary nozzle and ejector configurations on the system performance has been evaluated based on defined performance parameters. The numerical results have been compared with theoretical and experimental results for a given Coanda ejector configuration. (© 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
64.
Journal of Algebraic Combinatorics - In the present paper, we study conic-line arrangements having nodes, tacnodes, and ordinary triple points as singularities. We provide combinatorial constraints...  相似文献   
65.
Using local cohomology and algebraic -Modules, we generalize a comparison theorem between relative de Rham cohomology and Dwork cohomology due to N. Katz, P. Monsky, A. Adolphson and S. Sperber. Received June 10, 1999 / Published online July 20, 2000  相似文献   
66.
This paper presents an experimental characterization of two sources of calcium carbonate, limestone and calcium carbonate precipitate (CCP) used in wet flue gas desulphurization processes. Characterization of the two carbonate sources was carried out by chemical analysis, IR spectra, thermal behavior, particle size distribution for CCP, BET surface area and absorption capacity of SO2 in calcium carbonate suspensions. The absorption temperature, suspension concentration and carbonate grain size were found to be the most influential parameters in the absorption capacity measurements.   相似文献   
67.
The novel 1,2-di(azulen-1-yl)cyclopent-1-ene 3 was conveniently synthesized via a two-step procedure involving Vilsmeier–Haack acylation of azulene with N,N,N′,N′-tetraethylglutaramide (TEGA) and POCl3, followed by an intramolecular McMurry coupling of the resulting diketone. In contrast with the previously reported (E)-1,2-di(azulen-1-yl)ethene that shows negligible fluorescence in the solid state, alkene 3 displays fluorescence emission from the S2 excited state of the azulene moieties. This compound easily polymerizes upon electrochemical oxidation, leading to the formation of a conducting polymer film at the electrode surface.  相似文献   
68.
We are attempting to develop novel synthetic antioxidants aimed at retarding the effects of free-radical induced cell damage. In this paper we discuss the design strategy and report the synthesis of seven novel antioxidants, including six catechols and a benzylic phenol. The bond dissociation enthalpy (BDE) for the most active (weakest) OH bond in each molecule was calculated by theoretical methods, as well as the BDE for the semiquinone radical. Reaction rates with the nitrogen-centered free radical DPPH(*) were measured in ethyl acetate. The log of k(DPPH) for bimolecular reaction correlated well with the primary BDE. The correlation between rate constants and calculated BDEs shows that the BDE is a good predictor of antioxidant activity with DPPH(*), suggesting that our design criteria are useful and that these compounds should undergo further testing in cell cultures and in animal models.  相似文献   
69.
Tritopic ion-pair receptors can bind bivalent salts in solution; yet, these salts have a tendency to form ion-pairs even in the absence of receptors. The extent to which such receptors can enhance ion pairing has however remained elusive. Here, we study ion pairing of M2+ (Ba2+, Sr2+) and X (I, ClO4) in acetonitrile with and without a dichlorooxacalix[2]arene[2]triazine-related receptor containing a pentaethylene-glycol moiety. We find marked ion association already in receptor-free solutions. When present, most of the MX+ ion-pairs are bound to the receptor and the overall degree of ion association is enhanced due to coordinative, hydrogen-bonding, and anion-π interactions. The receptor shows higher selectivity for iodides but also stabilizes perchlorates, despite the latter are often considered as weakly coordinating anions. Our results show that ion-pair binding is strongly correlated to ion pairing in these solutions, thereby highlighting the importance of taking ion association in organic solvents into account.  相似文献   
70.
Lipidic cubic phases (LCPs) are used in areas ranging from membrane biology to biodevices. Because some membrane proteins are notoriously unstable at room temperature, and available LCPs undergo transformation to lamellar phases at low temperatures, development of stable low‐temperature LCPs for biophysical studies of membrane proteins is called for. Monodihydrosterculin (MDS) is a designer lipid based on monoolein (MO) with a configurationally restricted cyclopropyl ring replacing the olefin. Small‐angle X‐ray scattering (SAXS) analyses revealed a phase diagram for MDS lacking the high‐temperature, highly curved reverse hexagonal phase typical for MO, and extending the cubic phase boundary to lower temperature, thereby establishing the relationship between lipid molecular structure and mesophase behavior. The use of MDS as a new material for LCP‐based membrane protein crystallization at low temperature was demonstrated by crystallizing bacteriorhodopsin at 20 °C as well as 4 °C.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号