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61.
Alexander A. Zykov 《Geometriae Dedicata》1993,47(2):119-128
We criticize traditional definitions of the arc length which require semi-continuity from below. Symmetric definitions of lower and uppern-lengths (n-dimensional volumes) are introduced for a wide class of sets in Euclidean spaces, and the additivity of both functionals is proved. 相似文献
62.
Alexander Nickolaevich Kholodov 《Acta Appl Math》1990,19(1):1-54
We determine all orthogonal polynomials having Boas-Buck generating functions g(t)(xf(t)), where% MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGceaqabeaacqqHOo% qwcaGGOaGaamiDaiaacMcacqGH9aqpruqqYLwySbacfaGaa8hiamaa% BeaaleaacaaIWaaabeaakiaadAeacaqGGaWaaSbaaSqaaiaabgdaae% qaaOGaaeikaiaadggacaGGSaGaa8hiaiaadshacaqGPaGaaeilaiaa% bccacaqGGaGaaeiiaiaadggacqGHGjsUcaaIWaGaaiilaiaa-bcacq% GHsislcaaIXaGaaiilaiaa-bcacqGHsislcaaIYaGaaiilaiablAci% ljaacUdaaeaacqqHOoqwcaGGOaGaamiDaiaacMcacqGH9aqpcaWFGa% WaaSraaSqaaiaaicdaaeqaaOGaamOraiaabccadaWgaaWcbaGaaeOm% aaqabaGccaGGOaWaaSqaaSqaaiaaigdaaeaacaaIZaaaaOGaaiilai% aa-bcadaWcbaWcbaGaaGOmaaqaaiaaiodaaaGccaGGSaGaa8hiaiaa% dshacaGGPaGaa8hiamaaBeaaleaacaaIWaaabeaakiaadAeacaqGGa% WaaSbaaSqaaiaabkdaaeqaaOGaaeikamaaleaaleaacaaIYaaabaGa% aG4maaaakiaacYcacaWFGaWaaSqaaSqaaiaaisdaaeaacaaIZaaaaO% Gaaiilaiaa-bcacaWG0bGaaiykaiaacYcacaWFGaWaaSraaSqaaiaa% icdaaeqaaOGaamOraiaabccadaWgaaWcbaGaaeOmaaqabaGccaGGOa% WaaSqaaSqaaiaaisdaaeaacaaIZaaaaOGaaiilaiaa-bcadaWcbaWc% baGaaGynaaqaaiaaiodaaaGccaGGSaGaa8hiaiaadshacaGGPaGaai% 4oaaqaaiabfI6azjaacIcacaWG0bGaaiykaiabg2da9iaa-bcadaWg% baWcbaGaaGimaaqabaGccaWGgbGaaeiiamaaBaaaleaacaqGZaaabe% aakiaacIcadaWcbaWcbaGaaGymaaqaaiaaisdaaaGccaGGSaGaa8hi% amaaleaaleaacaaIYaaabaGaaGinaaaakiaacYcacaWFGaWaaSqaaS% qaaiaaiodaaeaacaaI0aaaaOGaaiilaiaa-bcacaWG0bGaaiykaiaa% -bcadaWgbaWcbaGaaGimaaqabaGccaWGgbGaaeiiamaaBaaaleaaca% qGZaaabeaakiaabIcadaWcbaWcbaGaaGOmaaqaaiaaisdaaaGccaGG% SaGaa8hiamaaleaaleaacaaIZaaabaGaaGinaaaakiaacYcacaWFGa% WaaSqaaSqaaiaaiwdaaeaacaaI0aaaaOGaaiilaiaa-bcacaWG0bGa% aiykaiaacYcaaeaadaWgbaWcbaGaaGimaaqabaGccaWGgbGaaeiiam% aaBaaaleaacaqGZaaabeaakiaacIcadaWcbaWcbaGaaG4maaqaaiaa% isdaaaGccaGGSaGaa8hiamaaleaaleaacaaI1aaabaGaaGinaaaaki% aacYcacaWFGaWaaSqaaSqaaiaaiAdaaeaacaaI0aaaaOGaaiilaiaa% -bcacaWG0bGaaiykaiaacYcacaGGUaGaa8hiamaaBeaaleaacaaIWa% aabeaakiaadAeacaqGGaWaaSbaaSqaaiaabodaaeqaaOGaaeikamaa% leaaleaacaaI1aaabaGaaGinaaaakiaacYcacaWFGaWaaSqaaSqaai% aaiAdaaeaacaaI0aaaaOGaaiilaiaa-bcadaWcbaWcbaGaaG4naaqa% aiaaisdaaaGccaGGSaGaa8hiaiaadshacaGGPaGaaiOlaaaaaa!C1F3!\[\begin{gathered}\Psi (t) = {}_0F{\text{ }}_{\text{1}} {\text{(}}a, t{\text{), }}a \ne 0, - 1, - 2, \ldots ; \hfill \\\Psi (t) = {}_0F{\text{ }}_{\text{2}} (\tfrac{1}{3}, \tfrac{2}{3}, t) {}_0F{\text{ }}_{\text{2}} {\text{(}}\tfrac{2}{3}, \tfrac{4}{3}, t), {}_0F{\text{ }}_{\text{2}} (\tfrac{4}{3}, \tfrac{5}{3}, t); \hfill \\\Psi (t) = {}_0F{\text{ }}_{\text{3}} (\tfrac{1}{4}, \tfrac{2}{4}, \tfrac{3}{4}, t) {}_0F{\text{ }}_{\text{3}} {\text{(}}\tfrac{2}{4}, \tfrac{3}{4}, \tfrac{5}{4}, t), \hfill \\{}_0F{\text{ }}_{\text{3}} (\tfrac{3}{4}, \tfrac{5}{4}, \tfrac{6}{4}, t),. {}_0F{\text{ }}_{\text{3}} {\text{(}}\tfrac{5}{4}, \tfrac{6}{4}, \tfrac{7}{4}, t). \hfill \\\end{gathered}\]We also determine all Sheffer polynomials which are orthogonal on the unit circle. The formula for the product of polynomials of the Boas-Buck type is obtained. 相似文献
63.
Weir AJ Klein SR Abrams G Adolphsen CE Akerlof C Alexander JP Alvarez M Amidei D Baden AR Ballam J Barish BC Barklow T Barnett BA Bartelt J Blockus D Bonvicini G Boyarski A Boyer J Brabson B Breakstone A Brom JM Bulos F Burchat PR Burke DL Butler F Calvino F Cence RJ Chapman J Cords D Coupal DP DeStaebler HC Dorfan DE Dorfan JM Drell PS Feldman GJ Fernandez E Field RC Ford WT Fordham C Frey R Fujino D Gan KK Gidal G Gladney L Glanzman T Gold MS Goldhaber G Green A Grosse-Wiesmann P Haggerty J 《Physical review D: Particles and fields》1990,41(5):1384-1388
64.
Ammar R Ball RC Banerjee S Bhat PC Bosetti P Bromberg C Canough GE Coffin T Dershem TO Dixon RL Fenker HC Ganguli SN Gensch U Girtler P Goshaw AT Grard F Gurtu A Hamilton C Henri VP Hernandez JJ Hrubec J Iori M Jones LW Kuhn D Knauss D Leedom ID Legros P Lemonne J Leutz H Liu X Malhotra PK Marraffino JM Mendez GE Miller R Naumann T Nguyen A Nowak H Pilette P Poirier J Poppleton A Raghavan R Rasner K Reucroft S Robertson WJ Roe BP Roth A Senko M Struczinski W Subramanian A Touboul MC Vonck B 《Physical review letters》1988,61(19):2185-2188
65.
Chiral separations by host-guest complexation with cyclodextrin and crown ether in capillary zone electrophoresis 总被引:2,自引:0,他引:2
Summary Capillary zone electrophoresis using cyclodextrins and a chiral crown ether as buffer constituents was studied for the enantiomeric separation of drugs and amino acids. Based on results obtained from separation of racemic -amino acids both chiral selectors are compared with respect to resolution, efficiency and retention time. For (±)-Quinagolide effects of buffer composition and temperature are examined using -cyclodextrin as chiral agent. Optimum conditions were pH 2.5 at 30 mmol L–1 -cyclodextrin. A linear dependence of retention on -cyclodextrin concentration allowed calculation of formation constants of the host-guest complexes. Buffer concentration and temperature also influence resolution. The application of a chiral crown ether to the separation of optical isomers in capillary zone electrophoresis is described for the first time. Chiral recognition of solutes depends on the formation of protonated alkyl amines and separation is attributed to the formation of diastereomeric host-guest complexes with different interactions for each enantiomer. The effects of crown ether concentration on resolution are presented. 相似文献
66.
Zhang X Sieval AB Hummelen JC Hessen B 《Chemical communications (Cambridge, England)》2005,(12):1616-1618
Polyethene with fullerene moieties pendant on short-chain branches was prepared by the catalytic copolymerization of ethene and a fullerene-containing vinylic comonomer, yielding polyethene copolymers containing up to 25 wt% of C60. 相似文献
67.
Vora A. Riga A. Dollimore D Alexander K. 《Journal of Thermal Analysis and Calorimetry》2004,75(3):709-717
This study attempts to identify the degradative process which folic acid undergoes in the solid-state under thermal stress.
In order to facilitate the process, the various pieces of the chemical structure, namely, p-amino benzoic acid, pterin and glutamic acid as both its d- and l-isomers were investigated as separate entities. These structured solid-state pieces were then compared to the composite solid
state folic acid degradative curves in order to identify the peaks seen and provide direction for the interpolation of the
degradative mechanism. It was observed that none of the structural pieces could be superimposed as assumed earlier and hence
an attempt was made to identify the decomposition products using various analytical techniques such as infrared spectroscopy,
mass spectroscopy and X-ray diffraction which suggested that the glutamic acid fragment is lost first as evidenced by acid
loss and amide enhancement in the IR spectra. The vitamin was ultimately degrading to carbon fragments and that further identification
was not necessary.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
68.
A. Hazra K. Alexander D. Dollimore A. Riga 《Journal of Thermal Analysis and Calorimetry》2004,75(1):317-330
The present study was aimed at determining the kinetics of evaporation and establishing vapor pressure curves for both single and multi-component systems by thermogravimetry (TG) and differential scanning calorimetry (DSC). Essential oils (e.g. lavender oil, orange oil, clove oil and eucalyptus oil, etc.) are typically multi-component systems consisting of various volatile pure components (e.g. linalyl acetate, limonene, cinnamaldehyde, etc.) which resemble single component systems. In this study linalyl acetate was taken as the calibration compound for TG. The vapor pressure curves for the pure substances were plotted using TG and vapor pressure plots for clove oil and eucalyptus oil were constructed using DSC. The thermodynamic and kinetic parameters of the pure compounds were compared to that of the multi-component systems to quantitatively and qualitatively measure the influence of different compounds on each other. The k-value from the vapor pressure data for linalyl acetate was calculated as 112006 Pa kg0.5mol0.5s-1 m-2 K-0.5. The vapor pressure values were used to determine the Antoine constants using the SPSS 10.0 software.This revised version was published online in November 2005 with corrections to the Cover Date. 相似文献
69.
Suman Dhami Garry Rumbles Alexander J. MacRobert David Phillips 《Photochemistry and photobiology》1997,65(1):85-90
Abstract— The photophysical properties of cis -disulfonated aluminum phthalocyanine (AlPcS2 ) in unilamellar vesicles (liposomes) of DL-a-dipalmitoyl-phosphatidylcholine have been measured. Both the fluorescence and triplet quantum yields decreased with increasing sensitizer concentration. The time-resolved fluorescence decays, analyzed by both the sum of exponentials and decay time distribution analyses, are compared with those reported for AlPcS2 in leukemic K562 cells. Information on the pho-todynamic transport and localization mechanism has been obtained by drawing correlations between the two systems, indicating active transport of the phthalocyanine into tumor cells involving lysosomal accumulation. 相似文献
70.