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931.
The local vibrational spectra of copper crystals containing vacancies are calculated using the pair atomic potential derived in the framework of the resonance pseudopotential theory. The calculations are performed by a recursive method with due regard for the symmetry of the defect region. The frequencies of the vacancy-induced resonance vibrations of different symmetries are determined. 相似文献
932.
L. M. Vasilyak M. N. Vasil’ev S. P. Vetchinin D. N. Polyakov V. E. Fortov 《Journal of Experimental and Theoretical Physics》2003,96(3):440-443
The action of an electron beam on ordered dust structures in glow and low-pressure RF discharges was studied experimentally. The electron beam produces destruction and dynamic displacement of the dust structure. In the center of a dust structure, an electron beam with a low electron energy (tens of eV) at currents up to 1 mA caused structural disordering and “melting” in the region of its action but did not excite external crystal regions. Local action of an electron beam with a high electron energy (25 keV) and a beam current above 10 mA caused deformation of the whole dust structure and shifted it in the horizontal direction so that it was carried away from the RF discharge zone. The effect of dust structure displacements can be used to locally remove particles from a plasma. 相似文献
933.
S. P. Savin L. M. Zelenyi E. Amata J. Buechner J. Blecki S. I. Klimov B. Nikutowski J. L. Rauch S. A. Romanov A. A. Skalsky V. N. Smirnov P. Song K. Stasiewicz 《JETP Letters》2004,79(8):368-371
The study of the interaction between collisionless plasma flow and stagnant plasma revealed the presence of an outer boundary layer at the border of a geomagnetic trap, where the super-Alfvén subsonic laminar flow changes over to the dynamic regime characterized by the formation of accelerated magnetosonic jets and decelerated Alfvén flows with characteristic relaxation times of 10–20 min. The nonlinear interaction of fluctuations in the initial flow with the waves reflected from an obstacle explains the observed flow chaotization. The Cherenkov resonance of the magnetosonic jet with the fluctuation beats between the boundary layer and the incoming flow is the possible mechanism of its formation. In the flow reference system, the incoming particles are accelerated by the electric fields at the border of boundary layer that arise self-consistently as a result of the preceding wave-particle interactions; the inertial drift of the incoming ions in a transverse electric field increasing toward the border explains quantitatively the observed ion acceleration. The magnetosonic jets may carry away downstream up to a half of the unperturbed flow momentum, and their dynamic pressure is an order of magnitude higher than the magnetic pressure at the obstacle border. The appearance of nonequilibrium jets and the boundary-layer fluctuations are synchronized by the magnetosonic oscillations of the incoming flow at frequencies of 1–2 mHz. 相似文献
934.
Determination of electronic structure of ozone related geometry is the main subject in this research. The proposed electronic structure must satisfy the experimental geometry, explain the excellent oxidizing properties of ozone, and can also explain the capability of additional reaction with unsaturated hydrocarbons. The potential energy surface of singlet and triplet state of ozone has been studied in order to check the correctness of the proposed structure. The proposed electronic structure of ozone is capable of explaining the oxidizing behavior of ozone in visible wavelength (daylight) 430–700 nm. For comparison, the other proposed structure of ozone in literature such as Pauling, Linnett and Weinhold has also been discussed. The main method used in this research is well-known density functional procedure, B3LYP, which takes the electron correlation aspect into consideration. The polarization and diffused functions are included in the basis set, 6-311++G**. The obtained geometry is a bent and cumulated double bond with inter-bond angle 118.42° (1.39%), and bond length 1.256 Å (1.72%). The obtained results revealed that frontier orbital theory is a proper tool for explaining the addition reaction. 相似文献
935.
Kukharev B. F. Stankevich V. K. Klimenko G. R. 《Russian Journal of Organic Chemistry》2003,39(5):625-629
Russian Journal of Organic Chemistry - 相似文献
936.
A hybrid heuristic method for combinatorial optimization problems is proposed that combines different classical techniques such as tree search procedures, bounding schemes and local search. The proposed method enhances the classic beam search approach by applying to each partial solution corresponding to a node selected by the beam, a further test that checks whether the current partial solution is dominated by another partial solution at the same level of the search tree. If this is the case, the latter solution becomes the new current partial solution. This step allows to partially recover from previous wrong decisions of the beam search procedure and can be seen as a local search step on the partial solution. We present here the application to two well known combinatorial optimization problems: the two-machine total completion time flow shop scheduling problem and the uncapacitated p-median location problem. In both cases the method strongly improves the performances with respect to the basic beam search approach and is competitive with the state of the art heuristics. 相似文献
937.
Alvim Adriana C.F. Ribeiro Celso C. Glover Fred Aloise Dario J. 《Journal of Heuristics》2004,10(2):205-229
We propose in this work a hybrid improvement procedure for the bin packing problem. This heuristic has several features: the use of lower bounding strategies; the generation of initial solutions by reference to the dual min-max problem; the use of load redistribution based on dominance, differencing, and unbalancing; and the inclusion of an improvement process utilizing tabu search. Encouraging results have been obtained for a very wide range of benchmark instances, illustrating the robustness of the algorithm. The hybrid improvement procedure compares favourably with all other heuristics in the literature. It improved the best known solutions for many of the benchmark instances and found the largest number of optimal solutions with respect to the other available approximate algorithms. 相似文献
938.
Using the methods of time-resolved absorption spectroscopy, we have investigated the features of quenching, by molecular oxygen, of the excited triplet states of water-soluble 5,10,15,20-tetrakis-(4-N-methylpyridyl)-porphyrin (H2TMPyP) and 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin (H2TSPP) in water–ethanol solutions. It has been revealed that for both compounds the rate constant of quenching of the triplet states increases with increasing viscosity of the medium. Quenching of the excited triplet states of the dissociated (in water) and undissociated (in ethanol) forms of water-soluble porphyrins occurs with a different efficiency, and the rate constant of quenching the triplet states by molecular oxygen k T thereby is higher for the dissociated form. It has been shown by means of mathematical modeling that the experimental results obtained can be described in terms of the change in the rate constants of intracomplex transitions in the porphyrin–oxygen collisional complex at varied solution viscosity and their difference for the dissociated and undissociated forms of water-soluble porphyrin. 相似文献
939.
940.