全文获取类型
收费全文 | 3164篇 |
免费 | 106篇 |
国内免费 | 11篇 |
专业分类
化学 | 2097篇 |
晶体学 | 22篇 |
力学 | 117篇 |
数学 | 419篇 |
物理学 | 626篇 |
出版年
2023年 | 25篇 |
2022年 | 68篇 |
2021年 | 114篇 |
2020年 | 99篇 |
2019年 | 68篇 |
2018年 | 57篇 |
2017年 | 48篇 |
2016年 | 135篇 |
2015年 | 105篇 |
2014年 | 93篇 |
2013年 | 177篇 |
2012年 | 207篇 |
2011年 | 247篇 |
2010年 | 147篇 |
2009年 | 106篇 |
2008年 | 192篇 |
2007年 | 207篇 |
2006年 | 189篇 |
2005年 | 161篇 |
2004年 | 166篇 |
2003年 | 119篇 |
2002年 | 94篇 |
2001年 | 45篇 |
2000年 | 23篇 |
1999年 | 17篇 |
1998年 | 20篇 |
1997年 | 26篇 |
1996年 | 29篇 |
1995年 | 22篇 |
1994年 | 19篇 |
1993年 | 14篇 |
1992年 | 19篇 |
1991年 | 6篇 |
1990年 | 12篇 |
1989年 | 9篇 |
1988年 | 12篇 |
1987年 | 10篇 |
1986年 | 7篇 |
1985年 | 18篇 |
1984年 | 21篇 |
1983年 | 17篇 |
1982年 | 16篇 |
1981年 | 11篇 |
1980年 | 10篇 |
1979年 | 11篇 |
1978年 | 5篇 |
1977年 | 10篇 |
1976年 | 5篇 |
1975年 | 5篇 |
1971年 | 4篇 |
排序方式: 共有3281条查询结果,搜索用时 15 毫秒
831.
[reaction: see text] Benzopyranoimidazolones could virtually exist in four tautomeric forms, namely N3-H, N1-H, coumarin O-H, and C2-H. Experimental evidence reported thus far has been unable to lead to a unique statement about the preferred tautomeric forms in solution. In this work, tautomeric equilibria for a series of 2-substituted [1]benzopyrano[3,4-d]imidazol-4(3H)-ones were investigated by DFT calculations, in both gas phase and solution. The influence of the solvent was included in the calculations by the CPCM solvent model. 13C chemical shifts of all tautomers were computed at different levels of theory and then compared with experiments to assign the preferred tautomers. Theoretical findings were then compared to dynamic 1H NMR experiments results. 相似文献
832.
833.
In the Roman wall paintings different white colours were used, named Paraetonium, Melinum, Anularia, Eretria, Argentaria, etc. FTIR, Raman spectroscopy and X-Ray diffraction were applied to study different white pigments, such as calcite, aragonite, dolomite and huntite, white carbonates present in archaeological findings from Roman walls in the Mediterranean region. This study showed that it is possible to distinguish and identify these components in white colours. About 450 samples of Roman wall paintings were analysed and it was observed that often aragonite is associated to precious coloured pigments. On the basis of the obtained results some considerations about the period in which the different kinds of white pigments were used are proposed. 相似文献
834.
Adami G Capriglia L Barbieri P Cozzi F Lo Coco F Acquavita A Reisenhofer E 《Annali di chimica》2006,96(9-10):601-612
The following metals: Al, Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn were determined by inductively coupled plasma - atomic emission spectroscopy (ICP-AES) in fluvial sediments of Rosandra Creek, using two different, strong and mild sediment decomposition methods. The purpose was to obtain information about the contamination by metals and distribution paths of pollutants in the area crossed by Rosandra Creek: this little river is the unique epigeous watercourse in the Italian Karst and very few data can be found in literature. In this area, we can find a natural park, but also agricultural activities and an industrial district that was recently defined as "polluted site of national interest". By comparing the results of the strong and mild extraction we have obtained the percentage of extraction and enrichment factors for each metal in the different sediments of the sites R2 and R3 exposed to pollution, while the site R1 was considered as a pristine one because situated in the natural park. The computed enrichment factors are generally not very high, but copper, lead and zinc have factors that require attention. The principal component analysis (PCA) shows that the typically anthropogenic metals (as Cr, Pb, Cu and Zn) constitute the first factor, while the lithogenic metals, as Fe and Ni, constitute the second one; moreover the score plots permit to classify and distinguish the 3 sites: site R3, possibly the more exposed to contamination, has high scores both for anthropogenic and lithogenic metals. 相似文献
835.
The following paper shows results of PM10 level and Cd, Cr, Cu, Fe, Mn, Ni, Pb, V and Zn concentrations present in this fraction for filters collected in the urban area of Campi Salentina (Apulia, Southern Italy) in 2004 in order to inquire into air quality. PM10 and lead concentrations did not exceed the standard values sanctioned by Italian Legislature with average values equal to 36.54 +/- 14.57 microg x m(-3) and 9.19 +/- 5.24 ng x m(-3) respectively. Significant correlations have been found between the pairs Fe-Mn, Ni-V, Cr-Ni and Cd-Cr. This suggests that these metals have a similar pollution source probably due to metallurgical activity. Multivariate statistical analysis showed that it is possible to distinguish the PM10 samples collected in sampling periods with different meteorological conditions. Indeed, metals concentration increases for samples characterized by scarce rains or by winds prevailing from North or North-West and is reduced due to different meteorological conditions, although there are some exceptions. 相似文献
836.
Sorace L Golze C Gatteschi D Bencini A Roesky HW Chai J Stückl AC 《Inorganic chemistry》2006,45(1):395-400
W-Band EPR spectra of [[HC(CMeNAr)(2)]Mn](2) (Ar = 2,6-(i)Pr(2)C(6)H(3)) have been measured at different temperatures. The spectra show a behavior which is typical for an antiferromagnetically coupled dimer with excited states populating upon increasing temperature. By following the intensity variation of the different features of the spectra with temperature, we attributed different groups of resonances to the S = 1, 2, and 3 states of the dimer. Their corresponding spin Hamiltonian parameters were derived from simulations. The zero-field-splitting parameters measured in this way were D(S=1) = 1.57 cm(-1) and E(S=1) = 0.064 cm(-1), D(S=2) = 0.266 cm(-1) and E(S=2) = 0.0045 cm(-1), and D(S=3) = 0.075 cm(-1) and E(S=3) = 0. On the basis of the molecular structure of the system, we could estimate that zero-field splitting (ZFS) is the result of anisotropic exchange and single-ion anisotropic contributions of similar magnitude (|D| approximately 0.2 cm(-1)). These results allow a deeper insight into the electronic structure of the Mn(I) centers in low-coordination environments, further supporting the electronic structure of Mn(I) to be 4s(1)3d(5), as previously indicated by DFT calculations. 相似文献
837.
Milios CJ Prescimone A Sanchez-Benitez J Parsons S Murrie M Brechin EK 《Inorganic chemistry》2006,45(18):7053-7055
The reaction of M(O2CMe)2.4H2O (M = Ni, Co) with NaN3 in pyridine/MeOH under microwave irradiation and controlled pressure/temperature leads to the formation of the trimetallic species [M3(N3)3(O2CMe)3(py)5] (M = Ni, 1; Co, 2) in 4 min and in high yields. Both complexes display dominant ferromagnetic interactions and high-spin ground states. 相似文献
838.
Mandanici A Cutroni M Triolo A Rodriguez-Mora V Ramos MA 《The Journal of chemical physics》2006,125(5):054514
The specific heat of some alkyl-cyclohexanes in their liquid, supercooled liquid, crystalline, and (for the first time) glassy states has been measured by quasiadiabatic calorimetry. Thermodynamic properties as well as the glass forming ability have been studied as a function of systematic changes of the molecular structure. Only one stable crystalline phase is observed experimentally for ethylcyclohexane, propylcyclohexane, and butylcyclohexane. In the case of methylcyclohexane, experimental evidence is provided of a crystal-to-crystal transition at temperatures just below the melting. 相似文献
839.
Raiteri P Laio A Gervasio FL Micheletti C Parrinello M 《The journal of physical chemistry. B》2006,110(8):3533-3539
Recently, we have introduced a new method, metadynamics, which is able to sample rarely occurring transitions and to reconstruct the free energy as a function of several variables with a controlled accuracy. This method has been successfully applied in many different fields, ranging from chemistry to biophysics and ligand docking and from material science to crystal structure prediction. We present an important development that speeds up metadynamics calculations by orders of magnitude and renders the algorithm much more robust. We use multiple interacting simulations, walkers, for exploring and reconstructing the same free energy surface. Each walker contributes to the history-dependent potential that, in metadynamics, is an estimate of the free energy. We show that the error on the reconstructed free energy does not depend on the number of walkers, leading to a fully linear scaling algorithm even on inexpensive loosely coupled clusters of PCs. In addition, we show that the accuracy and stability of the method are much improved by combining it with a weighted histogram analysis. We check the validity of our new method on a realistic application. 相似文献
840.
The dependence of (1)H and (13)C NMR chemical shifts of 1-butyl-3-methylimidazolium ([bmim])-based room-temperature ionic liquids on the counteranion ([BF(4)], [MeSO(4)]) is investigated experimentally and computationally. The local structure of the ionic liquids is investigated by means of DFT calculations of the structure of ion pairs and molecular dynamics simulations. Clusters extracted from the simulation runs are used to calculate (1)H and (13)C chemical shifts by means of QM/MM methods with various partition schemes. Proton H2 of the imidazolium ring is the most sensitive to the counteranion; its chemical shift is strongly dependent on subtle details of the arrangement of the two closest anions. It is shown that a correct spacing of signals can be attained by including the two anions closest to C2 and H2 in the QM layer. 相似文献