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51.
Let H(B,α) be the JBW*-algebra of elements of a continuous W*-algebra B invariant under the *-anti-automorphism α of B of order two. Then the mapping I → I ∩ H(B, α) is an order isomorphism from the complete lattice of α-invariant weak* closed inner ideals in B onto the complete lattice of weak* closed inner ideals in H(B, α), every one of which is of the form eH(B, α) α(e) for some unique projection e in B with α-invariant central support. A corollary of this result completely characterizes the weak* closed inner ideals in any continuous JBW*-triple. 相似文献
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Aleksej Mialitsin 《Journal of Physics and Chemistry of Solids》2011,72(5):568-571
Low energy Raman scattering from the ab-plane of the 2H polytype single crystal NbSe2 has been investigated in the normal (N), incommensurate charge density wave (ICDW) and superconducting (SC) phases. The temperature dependence of the polarization resolved Raman response has been obtained for the excitation wavelength of 647 nm and fitted to phenomenological models for the E2g and A1g symmetry channels. The A1g response can be fitted by a simple damped oscillator peak superimposed on continuous background. The E2g response displays an anti-resonance interference pattern between the inter-layer phonon and the CDW-induced mode such that a hybridized configuration (Fano line shape [1]) is required for modelling. The polarization specific peak maxima positions and line widths as a function of temperature, deduced in this manner, are presented. Partial suppression of the electronic continuum scattering in the Raman shift range up to 110 cm−1 in the A1g symmetry channel and beyond 300 cm−1 in the E2g symmetry channel is indicative of high energy electronic states far away from the Fermi surface participating in the ICDW formation. 相似文献
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Dr. Esteban Mejía Dr. Shu‐Ping Luo Dr. Michael Karnahl Aleksej Friedrich Dr. Stefanie Tschierlei Dr. Annette‐Enrica Surkus Dr. Henrik Junge Prof. Dr. Serafino Gladiali Prof. Dr. Stefan Lochbrunner Prof. Dr. Matthias Beller 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(47):15972-15978
A series of heteroleptic copper(I) complexes with bidentate $\widehat{PP}$ and $\widehat{NN}$ chelate ligands was prepared and successfully applied as photosensitizers in the light‐driven production of hydrogen, by using [Fe3(CO)12] as a water‐reduction catalyst (WRC). These systems efficiently reduces protons from water/THF/triethylamine mixtures, in which the amine serves as a sacrificial electron donor (SR). Turnover numbers (for H) up to 1330 were obtained with these fully noble‐metal‐free systems. The new complexes were electrochemically and photophysically characterized. They exhibited a correlation between the lifetimes of the MLCT excited state and their efficiency as photosensitizers in proton‐reduction systems. Within these experiments, considerably long excited‐state lifetimes of up to 54 μs were observed. Quenching studies with the SR, in the presence and absence of the WRC, showed that intramolecular deactivation was more efficient in the former case, thus suggesting the predominance of an oxidative quenching pathway. 相似文献
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Sanctolide A (1), a 14-membered polyketide-nonribosomal peptide (PK-NRP) hybrid macrolide, was isolated from the cultured cyanobacterium Oscillatoria sancta (SAG 74.79). The planar structure was determined using various spectroscopic techniques including HRESIMS, and 1D and 2D NMR analyses. The relative configuration was assigned by J-based configurational analysis in combination with NOE correlations. The absolute configuration was determined by Mosher ester and enantioselective HPLC analyses. The structure of sanctolide A (1) features a rare N-methyl enamide and a 2-hydroxyisovaleric acid, which are incorporated to form a 14-membered macrolide ring structure, comprising a new type of cyanobacterial macrolides derived from a PKS-NRPS hybrid biosynthetic pathway. 相似文献